Silicate carbonate

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The silicate carbonates are double salts that contain both silicate and carbonate in their formula. Most compounds are natural minerals containing calcium or rare earth elements. However, some have been made experimentally. Silicate carbonate minerals can be formed in limestone metamorphosed by heating from igneous intrusions. [1] Scawtite forms where the activity of calcium is high compared to H+. Spurrite forms in a limited range of calcium activity and high silica activity. [2] In magma, a carbonate rich melt is imiscible with a silicate melt. [3]

Contents

Structures

Silicate carbonates contain carbonate triangles, and silicate tetrahedrons, SiO4. Tillyite contains disilicate Si2O7 units. [1]

Properties

List

Thaumasite prisms Thaumasite-251460.jpg
Thaumasite prisms
formulanamestructuredensitycommentref
Ca4Si2O6(OH)2(CO3) fukalite [4]
Ca5(SiO4)2(CO3) spurrite [5]
Ca5(Si2O7)(CO3)2 tilleyite monoclinic  =7.582 Å, b=10.265 Å, c =15.030 Å β=103.99° [1]
Ca5(Si2O7)(CO3)2post-Tilleyite [1]
Ca6(CO3)1.58(Si2O7)0.21(OH)7Cl0.5(OH)0.08 (H2O)0.42 deferenite [6]
Ca7(SiO4)3(CO3) galuskinite [1]
Ca7(Si6O18)(CO3)·2H2O scawtite [1]
Ca3Si(OH)6(CO3)(SO4)•12H2O thaumasite Hexagonal a = 11.03, c = 10.4 [7]
Na7Ca[Al6Si6O24](CO3)1.5•2H2O cancrinite hexagonal a = 12.67 c = 5.15 [8]
(Ca4Al6Si6O24CO3) meionite tetragonal I4/m a = 12.179, c = 7.571, Z = 2 [9]
(Ca,Na)4Al6Si6O24(SO4,CO3) silvialite
scapolite [10]
K2Ca[Si2O5](CO3)P6322 a = 5.0479 c = 17.8668artificial [6]
KNa4Ca4[Si8O18](CO3)4F·H2O carletonite [6]
Y2(SiO4)(CO3) iimoriite-(Y) triclinic P1_ a=6.549 b=6.629 c=6.4395 α=116.36° β=92.56° γ=195.507° [11]
Ca2Y2[SiO3]4(CO3)·H2O kainosite [6]
Ca4Y4[Si2O5]4(CO3)6·7H2O caysichite [6]
K5Na5Y12[Si2O5]14(CO3)8(OH)2·8H2O ashcroftine [6]
Na2Ba2FeTi[Si2O7](CO3) (OH)3F bussenite [6]
Ba6Fe3[Si8O23](CO3)2Cl3·H2O fencooperite [6]
La2Mn(CO3)(Si2O7) alexkuznetsovite-(La) P21/cZ = 4 a = 6.5642 b = 6.7689 c = 18.721 Å, β = 108.684° V = 788.00 Å3 [12]
La2Fe2+(CO3)(Si2O7) biraite-(La) P21/c Z = 4 a = 6.566 b = 6.767 c = 18.698 Å, β = 108.95° V = 785.7 Å3 [12]
Ce2Mn(CO3)(Si2O7) alexkuznetsovite-(Ce) P21/cZ = 4 a = 6.5764 b = 6.7685 c = 18.749 Å, β = 108.672° V =790.7 Å3 [12]
Ce2Fe2+[Si2O7](CO3) biraite monoclinic P21/c, a 6.505 b 6.744 c 18.561 β=108.75° [6] [13]
Na2Ce2TiO2[SiO4](CO3)2 tundrite [6]
(Y1.44Er0.56)[SiO4](CO3) iimorite [6]
Pb19.4Na1.9[Si10O25](CO3)9(OH)12.7artificial [14]
Cu4Pb4[SiO3](HCO3)4)OH)4Cl ashburtonite [6]

Related Research Articles

<span class="mw-page-title-main">Mineral</span> Crystalline chemical element or compound formed by geologic processes

In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.

<span class="mw-page-title-main">Wollastonite</span> Single chain calcium inosilicate (CaSiO3)

Wollastonite is a calcium inosilicate mineral (CaSiO3) that may contain small amounts of iron, magnesium, and manganese substituting for calcium. It is usually white. It forms when impure limestone or dolomite is subjected to high temperature and pressure, which sometimes occurs in the presence of silica-bearing fluids as in skarns or in contact with metamorphic rocks. Associated minerals include garnets, vesuvianite, diopside, tremolite, epidote, plagioclase feldspar, pyroxene and calcite. It is named after the English chemist and mineralogist William Hyde Wollaston (1766–1828).

<span class="mw-page-title-main">Silicate mineral</span> Rock-forming minerals with predominantly silicate anions

Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust.

<span class="mw-page-title-main">Abenakiite-(Ce)</span> Cyclosilicate mineral

Abenakiite-(Ce) is a mineral of sodium, cerium, neodymium, lanthanum, praseodymium, thorium, samarium, oxygen, sulfur, carbon, phosphorus, and silicon with a chemical formula Na26Ce6(SiO3)6(PO4)6(CO3)6(S4+O2)O. The silicate groups may be given as the cyclic Si6O18 grouping. The mineral is named after the Abenaki, an Algonquian Indian tribe of New England. Its Mohs scale rating is 4 to 5.

<span class="mw-page-title-main">Clinozoisite</span>

Clinozoisite is a complex calcium aluminium sorosilicate mineral with formula: Ca2Al3(Si2O7)(SiO4)O(OH). It forms a continuous solid solution series with epidote by substitution of iron(III) in the aluminium (m3 site) and is also called aluminium epidote.

In inorganic chemistry, mineral hydration is a reaction which adds water to the crystal structure of a mineral, usually creating a new mineral, commonly called a hydrate.

<span class="mw-page-title-main">Spurrite</span> Nesosilicate mineral

Spurrite is a white, yellow or light blue mineral with monoclinic crystals. Its chemical formula is Ca5(SiO4)2CO3.

<span class="mw-page-title-main">Zorite</span> Silicate mineral

Zorite is a silicate mineral with the chemical formula of Na2Ti(Si,Al)3O9·nH2O. It is named because of its pink color, after the Russian word "zoria" which refers to the rosy hue of the sky at dawn. It is primarily found in Mount Karnasurta, Lovozero Massif, Kola Peninsula, Russia. The Lovozero Massif is an area with an igneous mountain range, home to various types of minerals such as eudialyte, loparite, and natrosilitite.

This list gives an overview of the classification of minerals (silicates) and includes mostly International Mineralogical Association (IMA) recognized minerals and its groupings. This list complements the List of minerals recognized by the International Mineralogical Association series of articles and List of minerals. Rocks, ores, mineral mixtures, non-IMA approved minerals and non-named minerals are mostly excluded.

Larnite is a calcium silicate mineral with the formula Ca2SiO4. It is the calcium member of the olivine group of minerals.

Eveslogite is a complex inosilicate mineral with a chemical formula (Ca,K,Na,Sr,Ba)
48
[(Ti,Nb,Fe,Mn)
12
(OH)
12
Si
48
O
144
](F,OH,Cl)
14
found on Mt. Eveslogchorr in Khibiny Mountains, on the Kola peninsula, Russia. It was named after the place it was found. This silicate mineral occurs as an anchimonomineral veinlet that cross-cuts poikilitic nepheline syenite. This mineral appears to resemble yuksporite, as it forms similar placated fine fibrous of approximately 0.05 to 0.005mm that aggregates outwardly. The color of eveslogite is yellow or rather light brown. In addition, it is a semitransparent mineral that has a white streak and a vitreous luster. Its crystal system is monoclinic and possesses a hardness (Mohs) of 5. This newly discovered mineral belongs to the astrophyllite group of minerals and contains structures that are composed of titanosilicate layers. Limited information about this mineral exists due to the few research studies carried out since its recent discovery.

<span class="mw-page-title-main">Gyrolite</span> Rare phyllosilicate mineral crystallizing in spherules

Gyrolite, NaCa16(Si23Al)O60(OH)8·14H2O, is a rare silicate mineral (basic sodium calcium silicate hydrate: N-C-S-H, in cement chemist notation) belonging to the class of phyllosilicates. Gyrolite is also often associated with zeolites. It is most commonly found as spherical or radial formations in hydrothermally altered basalt and basaltic tuffs. These formations can be glassy, dull or fibrous in appearance.

Mogovidite is a very rare mineral of the eudialyte group, with formula Na9(Ca,Na)6Ca6(Fe3+,Fe2+)2Zr3[]Si(Si9O27)2(Si3O9)2(CO3)(OH,H2O)4. The formula given is based on the original one but extended to show the presence of cyclic silicate groups. It is similar to feklichevite, differing from it in the presence of essential vacancies and carbonate group. Another specific feature is the dominance of ferric iron – a feature shared with other eudialyte-group members, including feklichevite, fengchengite, golyshevite and ikranite. Similarly to golyshevite, it is calcium-dominant, however on three sites: M(1), N(3) and N(4). It has a molecular mass of 3,066.24 gm.

<span class="mw-page-title-main">Jinshajiangite</span>

Jinshajiangite is a rare silicate mineral named after the Jinshajiang river in China. Its currently accepted formula is BaNaFe4Ti2(Si2O7)2O2(OH)2F. It gives a name of the jinshajiangite group. The mineral is associated with alkaline rocks. In jinshajiangite, there is a potassium-to-barium, calcium-to-sodium, manganese-to-iron and iron-to-titanium diadochy substitution. Jinshajiangite is the iron-analogue of surkhobite and perraultite. It is chemically related to bafertisite, cámaraite and emmerichite. Its structure is related to that of bafertisite. Jinshajiangite is a titanosilicate with heteropolyhedral HOH layers, where the H-layer is a mixed tetrahedral-octahedral layer, and the O-layer is simply octahedral.

<span class="mw-page-title-main">Abellaite</span> Hydrous carbonate mineral

Abellaite is a hydrous carbonate mineral discovered in the abandoned Eureka uranium mine in the village of Torre de Capdella (Lleida province), Catalonia, Spain. The ideal chemical formula of abellaite is NaPb2(CO3)2(OH). It is named in honor of Joan Abella i Creus, a Catalan gemmologist who has long studied minerals from the Eureka mine and first found abellaite in the mine. A team composed, among others, by Jordi Ibáñez-Insa from the Institute of Earth Sciences Jaume Almera (CSIC) and by Joan Viñals and Xavier Llovet from the University of Barcelona, identified and characterized the mineral’s structure and chemical composition.

<span class="mw-page-title-main">Lamprophyllite</span> Ti-silicate mineral

Lamprophyllite is a rare, but widespread mineral Ti-silicate mineral usually found in intrusive agpasitic igneous rocks. Yellow, reddish brown, Vitreous, Pearly.

The carbonate chlorides are double salts containing both carbonate and chloride anions. Quite a few minerals are known. Several artificial compounds have been made. Some complexes have both carbonate and chloride ligands. They are part of the family of halocarbonates. In turn these halocarbonates are a part of mixed anion materials.

<span class="mw-page-title-main">Fumarole mineral</span> Minerals which are deposited by fumarole exhalations

Fumarole minerals are minerals which are deposited by fumarole exhalations. They form when gases and compounds desublimate or precipitate out of condensates, forming mineral deposits. They are mostly associated with volcanoes following deposition from volcanic gas during an eruption or discharge from a volcanic vent or fumarole, but have been encountered on burning coal deposits as well. They can be black or multicoloured and are often unstable upon exposure to the atmosphere.

<span class="mw-page-title-main">Tilleyite</span> Calcium sorosilicate mineral

Tilleyite is a rarely occurring calcium sorosilicate mineral with formula Ca3[Si2O7]·2CaCO3. It is chemically a calcium silicate with additional carbonate ions. Tilleyite crystallizes in the monoclinic crystal system and forms only poorly developed, irregularly defined, tabular crystals and spherical grains. In its pure form it is colorless and transparent, however due to multiple refractions of light from lattice defects or polycrystalline formation, it can also appear white, with the transparency decreasing accordingly.

References

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