Beryllium carbonate

Last updated
Beryllium carbonate
Berylliumcarbonat.png
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.032.740 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 236-030-8
PubChem CID
RTECS number
  • DS2350000
UN number 1566
  • InChI=1S/CH2O3.Be/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2 Yes check.svgY
    Key: ZBUQRSWEONVBES-UHFFFAOYSA-L Yes check.svgY
  • InChI=1/CH2O3.Be/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2
    Key: ZBUQRSWEONVBES-NUQVWONBAN
  • [Be+2].[O-]C([O-])=O
Properties
BeCO3
Molar mass 69.020 g·mol−1
Melting point 54 °C (129 °F; 327 K)
Boiling point 100 °C (212 °F; 373 K)
decomposes
0.36 g/100 mL
Thermochemistry
65 J/mol·K [1]
52 J/mol·K [1]
-1025 kJ/mol [1]
-948 kJ/mol [1]
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Toxic (T)

Irritant (Xi)
Dangerous for the environment (N)

GHS labelling: [2]
GHS-pictogram-skull.svg GHS-pictogram-silhouette.svg GHS-pictogram-pollu.svg
Danger
H301, H315, H317, H319, H330, H335, H350i, H372, H411
NFPA 704 (fire diamond)
3
0
0
Lethal dose or concentration (LD, LC):
150 mg/kg (guinea pig)
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 0.002 mg/m3
C 0.005 mg/m3 (30 minutes), with a maximum peak of 0.025 mg/m3 (as Be) [3]
REL (Recommended)
Ca C 0.0005 mg/m3 (as Be) [3]
IDLH (Immediate danger)
Ca [4 mg/m3 (as Be)] [3]
Related compounds
Other cations
Magnesium carbonate
Calcium carbonate
Strontium carbonate
Barium carbonate
Radium carbonate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
X mark.svgN  verify  (what is  Yes check.svgYX mark.svgN ?)

Beryllium carbonate is a chemical compound with the chemical formula BeCO3.

Contents

Structures

There are three forms reported, anhydrous, a tetrahydrate and basic beryllium carbonate. The anhydrous form is reported to be unstable, decomposing to BeO and carbon dioxide, and requiring storage under CO2. [4] The tetrahydrate is said to be formed when CO2 is bubbled through a solution of Be(OH)2 and is also reported to be similarly unstable. [5]

Preparation

Basic beryllium carbonate is a mixed salt, which can be prepared by the reaction of beryllium sulfate and ammonium carbonate, and contains both carbonate and hydroxide ions, with formula Be2CO3(OH)2. [6] It is believed that in the older literature this is probably what was referred to as beryllium carbonate. [6]

Safety

It may cause irritation. Toxic. It should be handled carefully since several related beryllium compounds are known carcinogens.

Natural occurrence

No purely beryllium carbonate is known to occur naturally. The only Be-rich carbonate mineral currently known is niveolanite. [7]

Related Research Articles

Hydroxide Chemical compound

Hydroxide is a diatomic anion with chemical formula OH. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical. The corresponding electrically neutral compound HO is the hydroxyl radical. The corresponding covalently bound group –OH of atoms is the hydroxy group. Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry.

Potassium hydroxide Inorganic compound with the formula KOH

Potassium hydroxide is an inorganic compound with the formula KOH, and is commonly called caustic potash.

Basic copper carbonate Chemical compound

Basic copper carbonate is a chemical compound, more properly called copper(II) carbonate hydroxide. It is an ionic compound consisting of the ions copper(II) Cu2+
, carbonate CO2−
3
, and hydroxide OH
.

Magnesium carbonate Chemical compound

Magnesium carbonate, MgCO3, is an inorganic salt that is a colourless or white solid. Several hydrated and basic forms of magnesium carbonate also exist as minerals.

Zinc chloride Chemical compound

Zinc chloride is the name of chemical compounds with the formula ZnCl2 and its hydrates. Zinc chlorides, of which nine crystalline forms are known, are colorless or white, and are highly soluble in water. This white salt is hygroscopic and even deliquescent. Samples should therefore be protected from sources of moisture, including the water vapor present in ambient air. Zinc chloride finds wide application in textile processing, metallurgical fluxes, and chemical synthesis. No mineral with this chemical composition is known aside from the very rare mineral simonkolleite, Zn5(OH)8Cl2·H2O.

Manganese(II) chloride Chemical compound

Manganese(II) chloride is the dichloride salt of manganese, MnCl2. This inorganic chemical exists in the anhydrous form, as well as the dihydrate (MnCl2·2H2O) and tetrahydrate (MnCl2·4H2O), with the tetrahydrate being the most common form. Like many Mn(II) species, these salts are pink, with the paleness of the color being characteristic of transition metal complexes with high spin d5 configurations. It is a paramagnetic salt.

Beryllium fluoride Chemical compound

Beryllium fluoride is the inorganic compound with the formula BeF2. This white solid is the principal precursor for the manufacture of beryllium metal. Its structure resembles that of quartz, but BeF2 is highly soluble in water.

Beryllium oxide Chemical compound

Beryllium oxide (BeO), also known as beryllia, is an inorganic compound with the formula BeO. This colourless solid is a notable electrical insulator with a higher thermal conductivity than any other non-metal except diamond, and exceeds that of most metals. As an amorphous solid, beryllium oxide is white. Its high melting point leads to its use as a refractory material. It occurs in nature as the mineral bromellite. Historically and in materials science, beryllium oxide was called glucina or glucinium oxide, owing to its sweet taste.

Cadmium iodide Chemical compound

Cadmium iodide is the inorganic compound with the formula CdI2. It is a white hygroscopic solid. It also can be obtained as a mono- and tetrahydrate. It has few applications. It is notable for its crystal structure, which is typical for compounds of the form MX2 with strong polarization effects.

Indium(III) sulfate (In2(SO4)3) is a sulfate salt of the metal indium. It is a sesquisulfate, meaning that the sulfate group occurs 11/2 times as much as the metal. It may be formed by the reaction of indium, its oxide, or its carbonate with sulfuric acid. An excess of strong acid is required, otherwise insoluble basic salts are formed. As a solid indium sulfate can be anhydrous, or take the form of a pentahydrate with five water molecules or a nonahydrate with nine molecules of water. Indium sulfate is used in the production of indium or indium containing substances. Indium sulfate also can be found in basic salts, acidic salts or double salts including indium alum.

Cadmium nitrate Chemical compound

Cadmium nitrate describes any of the related members of a family of inorganic compounds with the general formula , the most commonly encountered form being the tetrahydrate. The anhydrous form is volatile, but the others are colourless crystalline solids that are deliquescent, tending to absorb enough moisture from the air to form an aqueous solution. Like other cadmium compounds, cadmium nitrate is known to be carcinogenic.

Basic beryllium acetate Chemical compound

Basic beryllium acetate is the chemical compound with the formula Be4O(O2CCH3)6. This compound adopts a distinctive structure, but it has no applications and has been only lightly studied. It is a colourless solid that is soluble in organic solvents.

Cobalt(II) nitrate Chemical compound

Cobalt nitrate is the inorganic compound with the formula Co(NO3)2.xH2O. It is cobalt(II)'s salt. The most common form is the hexahydrate Co(NO3)2·6H2O, which is a red-brown deliquescent salt that is soluble in water and other polar solvents.

Beryllium chloride Chemical compound

Beryllium chloride is an inorganic compound with the formula BeCl2. It is a colourless, hygroscopic solid that dissolves well in many polar solvents. Its properties are similar to those of aluminium chloride, due to beryllium's diagonal relationship with aluminium.

Chromium(III) sulfate Chemical compound

Chromium(III) sulfate usually refers to the inorganic compounds with the formula Cr2(SO4)3.x(H2O), where x can range from 0 to 18. Additionally, ill-defined but commercially important "basic chromium sulfates" are known. These salts are usually either violet or green solids that are soluble in water. It is commonly used in tanning leather.

Beryllium hydride Chemical compound

Beryllium hydride is an inorganic compound with the chemical formula n. This alkaline earth hydride is a colourless solid that is insoluble in solvents that do not decompose it. Unlike the ionically bonded hydrides of the heavier Group 2 elements, beryllium hydride is covalently bonded.

Beryllium sulfate Chemical compound

Beryllium sulfate normally encountered as the tetrahydrate, [Be(H2O)4]SO4 is a white crystalline solid. It was first isolated in 1815 by Jons Jakob Berzelius. Beryllium sulfate may be prepared by treating an aqueous solution of many beryllium salts with sulfuric acid, followed by evaporation of the solution and crystallization. The hydrated product may be converted to anhydrous salt by heating at 400 °C.

Aluminium carbonate (Al2(CO3)3), is a carbonate of aluminium. It is not well characterized; one authority says that simple carbonates of aluminium are not known. However related compounds are known, such as the basic sodium aluminium carbonate mineral dawsonite (NaAlCO3(OH)2) and hydrated basic aluminium carbonate minerals scarbroite (Al5(CO3)(OH)13•5(H2O)) and hydroscarbroite (Al14(CO3)3(OH)36•nH2O).

Beryllium nitrate Chemical compound

Beryllium nitrate is an inorganic compound with the idealized chemical formula Be(NO3)2. The formula suggests a salt, but, as for many beryllium compounds, the compound is highly covalent. Little of its chemistry is well known. "When added to water, brown fumes are evolved; when hydrolyzed in sodium hydroxide solution, both nitrate and nitrite ions are produced. "

Thorium(IV) nitrate Chemical compound

Thorium(IV) nitrate is a chemical compound with the formula Th(NO3)4. A white solid in its anhydrous form, it can form tetra- and pentahydrates. As a salt of thorium it is weakly radioactive.

References

  1. 1 2 3 4 "Beryllium carbonate".
  2. GHS: GESTIS 082790
  3. 1 2 3 NIOSH Pocket Guide to Chemical Hazards. "#0054". National Institute for Occupational Safety and Health (NIOSH).
  4. Egon Wiberg, Arnold Frederick Holleman (2001) Inorganic Chemistry, Elsevier ISBN   0-12-352651-5
  5. David Anthony Everest, 1964, The Chemistry of Beryllium, Elsevier Pub. Co.
  6. 1 2 J.E. Macintyre, Dictionary of Inorganic Compounds 1992 CRC Press ISBN   0-412-30120-2
  7. "Niveolanite".