Beryllium carbonate

Last updated
Beryllium carbonate
Berylliumcarbonat.png
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.032.740 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 236-030-8
PubChem CID
RTECS number
  • DS2350000
UN number 1566
  • InChI=1S/CH2O3.Be/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2 Yes check.svgY
    Key: ZBUQRSWEONVBES-UHFFFAOYSA-L Yes check.svgY
  • InChI=1/CH2O3.Be/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2
    Key: ZBUQRSWEONVBES-NUQVWONBAN
  • [Be+2].[O-]C([O-])=O
Properties
BeCO3
Molar mass 69.020 g·mol−1
Melting point 54 °C (129 °F; 327 K)
Boiling point 100 °C (212 °F; 373 K)
decomposes
0.36 g/100 mL
Thermochemistry
65 J/mol·K [1]
Std molar
entropy
(S298)
52 J/mol·K [1]
-1025 kJ/mol [1]
-948 kJ/mol [1]
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Toxic (T)

Irritant (Xi)
Dangerous for the environment (N)

GHS labelling: [2]
GHS-pictogram-skull.svg GHS-pictogram-silhouette.svg GHS-pictogram-pollu.svg
Danger
H301, H315, H317, H319, H330, H335, H350i, H372, H411
NFPA 704 (fire diamond)
NFPA 704.svgHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
3
0
0
Lethal dose or concentration (LD, LC):
150 mg/kg (guinea pig)
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 0.002 mg/m3
C 0.005 mg/m3 (30 minutes), with a maximum peak of 0.025 mg/m3 (as Be) [3]
REL (Recommended)
Ca C 0.0005 mg/m3 (as Be) [3]
IDLH (Immediate danger)
Ca [4 mg/m3 (as Be)] [3]
Related compounds
Other cations
Magnesium carbonate
Calcium carbonate
Strontium carbonate
Barium carbonate
Radium carbonate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
X mark.svgN  verify  (what is  Yes check.svgYX mark.svgN ?)

Beryllium carbonate is a chemical compound with the chemical formula BeCO3.

Contents

Structures

There are three forms reported, anhydrous, tetrahydrate and basic beryllium carbonate. The anhydrous form is reported to be unstable, decomposing to BeO and carbon dioxide, and requiring storage under CO2. [4] The tetrahydrate is said to be formed when CO2 is bubbled through a solution of Be(OH)2 and is also reported to be similarly unstable. [5]

Preparation

Basic beryllium carbonate is a mixed salt, which can be prepared by the reaction of beryllium sulfate and ammonium carbonate, and contains both carbonate and hydroxide ions, with formula Be2CO3(OH)2. [6] It is believed that in the older literature this is probably what was referred to as beryllium carbonate. [6]

Safety

It may cause irritation. Toxic. It should be handled carefully since several related beryllium compounds are known carcinogens.

Natural occurrence

No formations of purely beryllium carbonate are known to occur naturally. The only Be-rich carbonate mineral currently known is niveolanite. [7]

Related Research Articles

<span class="mw-page-title-main">Hydroxide</span> Chemical compound

Hydroxide is a diatomic anion with chemical formula OH. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical. The corresponding electrically neutral compound HO is the hydroxyl radical. The corresponding covalently bound group –OH of atoms is the hydroxy group. Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry.

<span class="mw-page-title-main">Basic copper carbonate</span> Chemical compound

Basic copper carbonate is a chemical compound, more properly called copper(II) carbonate hydroxide. It can be classified as a coordination polymer or a salt. It consists of copper(II) bonded to carbonate and hydroxide with formula Cu2(CO3)(OH)2. It is a green solid that occurs in nature as the mineral malachite. It has been used since antiquity as a pigment, and it is still used as such in artist paints, sometimes called verditer, green bice, or mountain green.

<span class="mw-page-title-main">Magnesium carbonate</span> Chemical compound

Magnesium carbonate, MgCO3, is an inorganic salt that is a colourless or white solid. Several hydrated and basic forms of magnesium carbonate also exist as minerals.

<span class="mw-page-title-main">Manganese(II) chloride</span> Chemical compound

Manganese(II) chloride is the dichloride salt of manganese, MnCl2. This inorganic chemical exists in the anhydrous form, as well as the dihydrate (MnCl2·2H2O) and tetrahydrate (MnCl2·4H2O), with the tetrahydrate being the most common form. Like many Mn(II) species, these salts are pink, with the paleness of the color being characteristic of transition metal complexes with high spin d5 configurations.

<span class="mw-page-title-main">Cadmium chloride</span> Chemical compound

Cadmium chloride is a white crystalline compound of cadmium and chloride, with the formula CdCl2. This salt is a hygroscopic solid that is highly soluble in water and slightly soluble in alcohol. The crystal structure of cadmium chloride (described below), is a reference for describing other crystal structures. Also known are CdCl2•H2O and the hemipentahydrate CdCl2•2.5H2O.

<span class="mw-page-title-main">Beryllium oxide</span> Chemical compound

Beryllium oxide (BeO), also known as beryllia, is an inorganic compound with the formula BeO. This colourless solid is an electrical insulator with a higher thermal conductivity than any other non-metal except diamond, and exceeds that of most metals. As an amorphous solid, beryllium oxide is white. Its high melting point leads to its use as a refractory material. It occurs in nature as the mineral bromellite. Historically and in materials science, beryllium oxide was called glucina or glucinium oxide, owing to its sweet taste.

A solubility chart is a chart describing whether the ionic compounds formed from different combinations of cations and anions dissolve in or precipitate from solution.

<span class="mw-page-title-main">Lead carbonate</span> Chemical compound

Lead(II) carbonate is the chemical compound with the chemical formula PbCO3. It is a white, toxic solid. It occurs naturally as the mineral cerussite.

<span class="mw-page-title-main">Copper(II) bromide</span> Chemical compound

Copper(II) bromide (CuBr2) is a chemical compound that forms an unstable tetrahydrate CuBr2·4H2O. It is used in photographic processing as an intensifier and as a brominating agent in organic synthesis.

<span class="mw-page-title-main">Nickel(II) carbonate</span> Chemical compound

Nickel(II) carbonate describes one or a mixture of inorganic compounds containing nickel and carbonate. From the industrial perspective, an important nickel carbonate is basic nickel carbonate with the formula Ni4CO3(OH)6(H2O)4. Simpler carbonates, ones more likely encountered in the laboratory, are NiCO3 and its hexahydrate. All are paramagnetic green solids containing Ni2+ cations. The basic carbonate is an intermediate in the hydrometallurgical purification of nickel from its ores and is used in electroplating of nickel.

<span class="mw-page-title-main">Zirconium tetrafluoride</span> Chemical compound

Zirconium(IV) fluoride describes members of a family inorganic compounds with the formula ZrF4(H2O)x. All are colorless, diamagnetic solids. Anhydrous Zirconium(IV) fluoride is a component of ZBLAN fluoride glass.

<span class="mw-page-title-main">Cadmium iodide</span> Chemical compound

Cadmium iodide is an inorganic compound with the formula CdI2. It is a white hygroscopic solid. It also can be obtained as a mono- and tetrahydrate. It has few applications. It is notable for its crystal structure, which is typical for compounds of the form MX2 with strong polarization effects.

<span class="mw-page-title-main">Cadmium nitrate</span> Chemical compound

Cadmium nitrate describes any of the related members of a family of inorganic compounds with the general formula Cd(NO3)2·xH2O. The most commonly encountered form being the tetrahydrate.The anhydrous form is volatile, but the others are colourless crystalline solids that are deliquescent, tending to absorb enough moisture from the air to form an aqueous solution. Like other cadmium compounds, cadmium nitrate is known to be carcinogenic. According to X-ray crystallography, the tetrahydrate features octahedral Cd2+ centers bound to six oxygen ligands.

<span class="mw-page-title-main">Basic beryllium acetate</span> Chemical compound

Basic beryllium acetate is the chemical compound with the formula Be4O(O2CCH3)6. This compound adopts a distinctive structure, but it has no applications and has been only lightly studied. It is a colourless solid that is soluble in organic solvents.

<span class="mw-page-title-main">Beryllium bromide</span> Chemical compound

Beryllium bromide is the chemical compound with the formula BeBr2. It is very hygroscopic and dissolves well in water. The Be2+ cation, which is relevant to BeBr2, is characterized by the highest known charge density (Z/r = 6.45), making it one of the hardest cations and a very strong Lewis acid.

<span class="mw-page-title-main">Beryllium sulfate</span> Chemical compound

Beryllium sulfate normally encountered as the tetrahydrate, [Be(H2O)4]SO4 is a white crystalline solid. It was first isolated in 1815 by Jons Jakob Berzelius. Beryllium sulfate may be prepared by treating an aqueous solution of many beryllium salts with sulfuric acid, followed by evaporation of the solution and crystallization. The hydrated product may be converted to anhydrous salt by heating at 400 °C.

Aluminium carbonate (Al2(CO3)3), is a carbonate of aluminium. It is not well characterized; one authority says that simple carbonates of aluminium are not known. However related compounds are known, such as the basic sodium aluminium carbonate mineral dawsonite (NaAlCO3(OH)2) and hydrated basic aluminium carbonate minerals scarbroite (Al5(CO3)(OH)13•5(H2O)) and hydroscarbroite (Al14(CO3)3(OH)36•nH2O).

<span class="mw-page-title-main">Beryllium nitrate</span> Chemical compound

Beryllium nitrate is an inorganic compound with the idealized chemical formula Be(NO3)2. The formula suggests a salt, but, as for many beryllium compounds, the compound is highly covalent. Little of its chemistry is well known. "When added to water, brown fumes are evolved; when hydrolyzed in sodium hydroxide solution, both nitrate and nitrite ions are produced."

<span class="mw-page-title-main">Thorium(IV) nitrate</span> Chemical compound

Thorium(IV) nitrate is a chemical compound, a salt of thorium and nitric acid with the formula Th(NO3)4. A white solid in its anhydrous form, it can form tetra- and pentahydrates. As a salt of thorium it is weakly radioactive.

<span class="mw-page-title-main">Europium(III) acetate</span> Chemical compound

Europium(III) acetate is an inorganic salt of europium and acetic acid with the chemical formula of Eu(CH3COO)3. In this compound, europium exhibits the +3 oxidation state. It can exist in the anhydrous form, sesquihydrate and tetrahydrate. Its hydrate molecule is a dimer.

References

  1. 1 2 3 4 "Beryllium carbonate".
  2. GHS: GESTIS 082790
  3. 1 2 3 NIOSH Pocket Guide to Chemical Hazards. "#0054". National Institute for Occupational Safety and Health (NIOSH).
  4. Egon Wiberg, Arnold Frederick Holleman (2001) Inorganic Chemistry, Elsevier ISBN   0-12-352651-5
  5. David Anthony Everest, 1964, The Chemistry of Beryllium, Elsevier Pub. Co.
  6. 1 2 J.E. Macintyre, Dictionary of Inorganic Compounds 1992 CRC Press ISBN   0-412-30120-2
  7. "Niveolanite".