Beryllium carbide

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Beryllium carbide
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Names
IUPAC name
Beryllium carbide
Other names
Beryllium methanide
Identifiers
3D model (JSmol)
ChemSpider
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EC Number
  • 208-050-7
PubChem CID
UNII
  • InChI=1S/C.2Be Yes check.svgY
    Key: UQVOJETYKFAIRZ-UHFFFAOYSA-N Yes check.svgY
  • [Be]=C=[Be]
Properties
Be2C
Molar mass 30.035 g·mol−1
AppearanceYellow to red crystals
Odor odorless
Density 1.90 g/cm3 (at 15 °C)
Melting point 2,100 °C (3,810 °F; 2,370 K) (decomposes)
decomposes
Structure
cubic
Hazards
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 0.002 mg/m3
C 0.005 mg/m3 (30 minutes), with a maximum peak of 0.025 mg/m3 (as Be) [1]
REL (Recommended)
Ca C 0.0005 mg/m3 (as Be) [1]
IDLH (Immediate danger)
Ca [4 mg/m3 (as Be)] [1]
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Beryllium carbide is a chemical compound with the chemical formula Be 2 C . It is a metal carbide. [2] Similar to diamond, it is a very hard compound. It is used in nuclear reactors as a core material.

Contents

Preparation

Beryllium carbide is prepared by heating the elements beryllium and carbon at elevated temperatures (above 950°C). It also may be prepared by reduction of beryllium oxide with carbon at a temperature above 1,500°C:

2 BeO + 3 C → Be2C + 2 CO

Beryllium carbide decomposes very slowly in water and forms methane gas:

Be2C + 2 H2O → 2 BeO + CH4

The rate of decomposition is faster in mineral acids with evolution of methane.

Be2C + 4 H+ → 2 Be2+ + CH4

In hot concentrated alkali the reaction is very rapid, forming alkali metal beryllates and methane:

Be2C + 4 OH → 2 BeO2−2 + CH4

See also

References

  1. 1 2 3 NIOSH Pocket Guide to Chemical Hazards. "#0054". National Institute for Occupational Safety and Health (NIOSH).
  2. "Beryllium Carbide". American Elements. Retrieved 25 June 2023.