Chromium(II) carbide

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Contents

Chromium carbide [1]
Cr3C2structure.jpg
Chromium carbide Cr3C2.JPG
Names
IUPAC name
Chromium(II) carbide
Other names
Chromium carbide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.420 OOjs UI icon edit-ltr-progressive.svg
PubChem CID
  • InChI=1S/2C.3Cr Yes check.svgY
    Key: UFGZSIPAQKLCGR-UHFFFAOYSA-N Yes check.svgY
  • InChI=1/2C.3Cr/rC2Cr3/c3-1-5-2-4
    Key: UFGZSIPAQKLCGR-HMFAXLTNAU
  • [Cr]#C[Cr]C#[Cr]
Properties
Cr3C2
Molar mass 180.009 g/mol
Appearancegray orthorhombic crystals
Density 6.68 g/cm3
Melting point 1,895 °C (3,443 °F; 2,168 K)
Boiling point 3,800 °C (6,870 °F; 4,070 K)
reacts
Structure
Orthorhombic, oP20
Pnma, No. 62
Hazards
NFPA 704 (fire diamond)
NFPA 704.svgHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 2: Must be moderately heated or exposed to relatively high ambient temperature before ignition can occur. Flash point between 38 and 93 °C (100 and 200 °F). E.g. diesel fuelInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no code
1
2
1
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1 mg/m3 [2]
REL (Recommended)
TWA 0.5 mg/m3 [2]
IDLH (Immediate danger)
250 mg/m3 [2]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Yes check.svgY  verify  (what is  Yes check.svgYX mark.svgN ?)

Chromium(II) carbide is a ceramic compound that exists in several chemical compositions: Cr3C2, Cr7C3, and Cr23C6. At standard conditions it exists as a gray solid. It is extremely hard and corrosion resistant. It is also a refractory compound, which means that it retains its strength at high temperatures as well. These properties make it useful as an additive to metal alloys. When chromium carbide crystals are integrated into the surface of a metal it improves the wear resistance and corrosion resistance of the metal, and maintains these properties at elevated temperatures. The hardest and most commonly used composition for this purpose is Cr3C2.

The mineral form of the Cr3C2 compound is tongbaite. [3] Isovite, (Cr,Fe)
23
C
6
, is a related mineral. Both are extremely rare. [4] Yet another chromium-rich carbide mineral is yarlongite, Cr4Fe4NiC4. [5]

Properties

There are three different crystal structures for chromium carbide corresponding to the three different chemical compositions. Cr23C6 has a cubic crystal structure and a Vickers hardness of 976 kg/mm2. [6] Cr7C3 has a hexagonal crystal structure and a microhardness of 1336 kg/mm2. [6] Cr3C2 is the most durable of the three compositions, and has an orthorhombic crystal structure with a microhardness of 2280 kg/mm2. [6] For this reason Cr3C2 is the primary form of chromium carbide used in surface treatment.

Synthesis

Synthesis of chromium carbide can be achieved through mechanical alloying. In this type of process metallic chromium and pure carbon in the form of graphite are loaded into a ball mill and ground into a fine powder. After the components have been ground they are pressed into a pellet and subjected to hot isostatic pressing. Hot isostatic pressing utilizes an inert gas, primarily argon, in a sealed oven. This pressurized gas applies pressure to the sample from all directions while the oven is heated. The heat and pressure cause the graphite and metallic chromium to react and form chromium carbide. Decreasing the percentage of carbon content in the initial mixture results in an increase in the yield of the Cr7C3, and Cr23C6 forms of chromium carbide. [7]

Another method for the synthesis of chromium carbide utilizes chromium oxide, pure aluminum, and graphite in a self-propagating exothermic reaction that proceeds as follows: [7]

3Cr2O3 + 6Al + 4C → 2Cr3C2 + 3Al2O3

In this method the reactants are ground and blended in a ball mill. The blended powder is then pressed into a pellet and placed under an inert atmosphere of argon. The sample is then heated. A heated wire, a spark, a laser, or an oven may provide the heat. The exothermic reaction is initiated, and the resulting heat propagates the reaction throughout the rest of the sample.

Uses

Chromium carbide is useful in the surface treatment of metal components. Chromium carbide is used to coat the surface of another metal in a technique known as thermal spraying. Cr3C2 powder is mixed with solid nickel-chromium. This mixture is then heated to very high temperatures and sprayed onto the object being coated where it forms a protective layer. This layer is essentially its own metal matrix composite, consisting of hard ceramic Cr3C2 particles embedded in a nickel-chromium matrix. The matrix itself contributes to the corrosion resistance of the coating because both nickel and chromium are corrosion resistant in their metallic form. After over spraying the coating, the coated part must run through a diffusion heat treatment to reach the best results in matter of coupling strength to the base metal and also in matter of hardness.

Another technique utilizes chromium carbide in the form of overlay plates. These are prefabricated chromium carbide-coated steel plates, which are meant to be welded onto existing structures or machinery in order to improve performance.

Chromium carbide is used as an additive in cutting tools made of cemented carbides, in order to improve hardness by preventing the growth of large grains. [8] The primary constituent in most extremely hard cutting tools is tungsten carbide. The tungsten carbide is combined with other carbides such as titanium carbide, niobium carbide, and chromium carbide and sintered together with a cobalt matrix. Cr3C2 prevents large grains from forming in the composite, which results in a fine-grained structure of superior hardness.

Undesired formation of chromium carbides in stainless steel and other alloys can lead to intergranular corrosion.

Related Research Articles

<span class="mw-page-title-main">Alloy</span> Mixture or metallic solid solution composed of two or more elements

An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, opacity, and luster, but may have properties that differ from those of the pure metals, such as increased strength or hardness. In some cases, an alloy may reduce the overall cost of the material while preserving important properties. In other cases, the mixture imparts synergistic properties to the constituent metal elements such as corrosion resistance or mechanical strength.

<span class="mw-page-title-main">Metal</span> Type of material

A metal is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typically ductile and malleable. These properties are the result of the metallic bond between the atoms or molecules of the metal.

<span class="mw-page-title-main">Metallurgy</span> Field of science that studies the physical and chemical behavior of metals

Metallurgy is a domain of materials science and engineering that studies the physical and chemical behavior of metallic elements, their inter-metallic compounds, and their mixtures, which are known as alloys. Metallurgy encompasses both the science and the technology of metals; that is, the way in which science is applied to the production of metals, and the engineering of metal components used in products for both consumers and manufacturers. Metallurgy is distinct from the craft of metalworking. Metalworking relies on metallurgy in a similar manner to how medicine relies on medical science for technical advancement. A specialist practitioner of metallurgy is known as a metallurgist.

In materials science, a metal matrix composite (MMC) is a composite material with fibers or particles dispersed in a metallic matrix, such as copper, aluminum, or steel. The secondary phase is typically a ceramic or another metal. They are typically classified according to the type of reinforcement: short discontinuous fibers (whiskers), continuous fibers, or particulates. There is some overlap between MMCs and cermets, with the latter typically consisting of less than 20% metal by volume. When at least three materials are present, it is called a hybrid composite. MMCs can have much higher strength-to-weight ratios, stiffness, and ductility than traditional materials, so they are often used in demanding applications. MMCs typically have lower thermal and electrical conductivity and poor resistance to radiation, limiting their use in the very harshest environments.

<span class="mw-page-title-main">Brazing</span> Metal-joining technique

Brazing is a metal-joining process in which two or more metal items are joined together by melting and flowing a filler metal into the joint, with the filler metal having a lower melting point than the adjoining metal.

<span class="mw-page-title-main">Carbon steel</span> Steel in which the main interstitial alloying constituent is carbon

Carbon steel is a steel with carbon content from about 0.05 up to 2.1 percent by weight. The definition of carbon steel from the American Iron and Steel Institute (AISI) states:

Plating is a finishing process in which a metal is deposited on a surface. Plating has been done for hundreds of years; it is also critical for modern technology. Plating is used to decorate objects, for corrosion inhibition, to improve solderability, to harden, to improve wearability, to reduce friction, to improve paint adhesion, to alter conductivity, to improve IR reflectivity, for radiation shielding, and for other purposes. Jewelry typically uses plating to give a silver or gold finish.

<span class="mw-page-title-main">Carburizing</span> Heat treatment process in which a metal or alloy is infused with carbon to increase hardness

Carburizing, or carburising, is a heat treatment process in which iron or steel absorbs carbon while the metal is heated in the presence of a carbon-bearing material, such as charcoal or carbon monoxide. The intent is to make the metal harder and more wear resistant. Depending on the amount of time and temperature, the affected area can vary in carbon content. Longer carburizing times and higher temperatures typically increase the depth of carbon diffusion. When the iron or steel is cooled rapidly by quenching, the higher carbon content on the outer surface becomes hard due to the transformation from austenite to martensite, while the core remains soft and tough as a ferritic and/or pearlite microstructure.

<span class="mw-page-title-main">Tantalum carbide</span> Chemical compound

Tantalum carbides (TaC) form a family of binary chemical compounds of tantalum and carbon with the empirical formula TaCx, where x usually varies between 0.4 and 1. They are extremely hard, brittle, refractory ceramic materials with metallic electrical conductivity. They appear as brown-gray powders, which are usually processed by sintering.

<span class="mw-page-title-main">Titanium carbide</span> Chemical compound

Titanium carbide, TiC, is an extremely hard refractory ceramic material, similar to tungsten carbide. It has the appearance of black powder with the sodium chloride crystal structure.

<span class="mw-page-title-main">Tempering (metallurgy)</span> Process of heat treating used to increase the toughness of iron-based alloys

Tempering is a process of heat treating, which is used to increase the toughness of iron-based alloys. Tempering is usually performed after hardening, to reduce some of the excess hardness, and is done by heating the metal to some temperature below the critical point for a certain period of time, then allowing it to cool in still air. The exact temperature determines the amount of hardness removed, and depends on both the specific composition of the alloy and on the desired properties in the finished product. For instance, very hard tools are often tempered at low temperatures, while springs are tempered at much higher temperatures.

<span class="mw-page-title-main">Titanium nitride</span> Ceramic material

Titanium nitride is an extremely hard ceramic material, often used as a physical vapor deposition (PVD) coating on titanium alloys, steel, carbide, and aluminium components to improve the substrate's surface properties.

<span class="mw-page-title-main">Superalloy</span> Alloy with higher durability than normal metals

A superalloy, or high-performance alloy, is an alloy with the ability to operate at a high fraction of its melting point. Key characteristics of a superalloy include mechanical strength, thermal creep deformation resistance, surface stability, and corrosion and oxidation resistance.

<span class="mw-page-title-main">Intergranular corrosion</span> When crystallite boundaries are more corrosive than their interiors

In materials science, intergranular corrosion (IGC), also known as intergranular attack (IGA), is a form of corrosion where the boundaries of crystallites of the material are more susceptible to corrosion than their insides.

<span class="mw-page-title-main">Electroless nickel-phosphorus plating</span>

Electroless nickel-phosphorus plating, also referred to as E-nickel, is a chemical process that deposits an even layer of nickel-phosphorus alloy on the surface of a solid substrate, like metal or plastic. The process involves dipping the substrate in a water solution containing nickel salt and a phosphorus-containing reducing agent, usually a hypophosphite salt. It is the most common version of electroless nickel plating and is often referred by that name. A similar process uses a borohydride reducing agent, yielding a nickel-boron coating instead.

Aluminium carbide, chemical formula Al4C3, is a carbide of aluminium. It has the appearance of pale yellow to brown crystals. It is stable up to 1400 °C. It decomposes in water with the production of methane.

Alloy steel is steel that is alloyed with a variety of elements in total amounts between 1.0% and 50% by weight to improve its mechanical properties.

<span class="mw-page-title-main">Native element mineral</span> Elements that occur in nature as minerals in uncombined form

Native element minerals are those elements that occur in nature in uncombined form with a distinct mineral structure. The elemental class includes metals, intermetallic compounds, alloys, metalloids, and nonmetals. The Nickel–Strunz classification system also includes the naturally occurring phosphides, silicides, nitrides, carbides, and arsenides.

<span class="mw-page-title-main">Detonation spraying</span> Method of thermal spraying

Detonation spraying is one of the many forms of thermal spraying techniques that are used to apply a protective coating at supersonic velocities to a material in order to change its surface characteristics. This is primarily to improve the durability of a component. It was first invented in 1955 by H.B. Sargent, R.M. Poorman and H. Lamprey and is applied to a component using a specifically designed detonation gun (D-gun). The component being sprayed must be prepared correctly by removing all surface oils, greases, debris and roughing up the surface in order to achieve a strongly bonded detonation spray coating. This process involves the highest velocities and temperatures (≈4000 °C) of coating materials compared to all other forms of thermal spraying techniques. Which means detonation spraying is able to apply low porous and low oxygen content protective coatings that protect against corrosion, abrasion and adhesion under low load.

References

  1. Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, Florida: CRC Press, pp. 4–52, ISBN   0-8493-0594-2
  2. 1 2 3 NIOSH Pocket Guide to Chemical Hazards. "#0141". National Institute for Occupational Safety and Health (NIOSH).
  3. Tongbaite: Mineral information, data and localities, Mindat.org
  4. Generalov ME, Naumov VA, Mokhov AV, Trubkin NV, "Isovite (Cr,Fe)23C6 - a new mineral from the gold-platinum bearing placers of the Urals", Zapiski Vserossiyskogo mineralogicheskogo obshchestva, vol. 127, pp.26-37, 1998.
  5. Mindat, http://www.mindat.org/min-35899.html
  6. 1 2 3 Chattopadhyay, R. (2001). Surface Wear: Analysis, Treatment, and Prevention. Materials Park, OH: ASM International. pp. 228–229. ISBN   978-0-87170-702-4.
  7. 1 2 Cintho, Osvaldo; Favilla, Eliane; Capocchi, Jose (1 July 2007). "Mechanical–thermal synthesis of chromium carbides". Journal of Alloys and Compounds. 439 (1–2): 189–195. doi:10.1016/j.jallcom.2006.03.102.
  8. Ellis, Jonathan; Haw, Michael (November 1997). "Chromium Carbides". Materials World. 5 (11).