Mechanical alloying

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Mechanical alloying (MA) is a solid-state and powder processing technique involving repeated cold welding, fracturing, and re-welding of blended powder particles in a high-energy ball mill to produce a homogeneous material. Originally developed to produce oxide-dispersion strengthened (ODS) nickel- and iron-base superalloys for applications in the aerospace industry, [1] MA has now been shown to be capable of synthesizing a variety of equilibrium and non-equilibrium alloy phases starting from blended elemental or pre-alloyed powders. [2] The non-equilibrium phases synthesized include supersaturated solid solutions, metastable crystalline and quasicrystalline phases, nanostructures, and amorphous alloys.The method is sometimes is classified as a surface severe platic deformation method to achieve nanomaterials. [3]

Contents

Alloying during high-energy milling. MA Scheme.jpg
Alloying during high-energy milling.

Metal mixes

Mechanical alloying is akin to metal powder processing, where metals may be mixed to produce superalloys. Mechanical alloying occurs in three steps. First, the alloy materials are combined in a ball mill and ground to a fine powder. A hot isostatic pressing (HIP) process is then applied to simultaneously compress and sinter the powder. A final heat treatment stage helps remove existing internal stresses produced during any cold compaction [ broken anchor ] which may have been used. This produces an alloy suitable for high heat turbine blades and aerospace components. In combination with powder spheroidization this technology can be used to develop rapidly new alloy powders for additive manufacturing [5]

Design

Design parameters include type of mill, milling container, milling speed, milling time, type, size, and size distribution of the grinding medium, ball-to-powder weight ratio, extent of filling the vial, milling atmosphere, process control agent, temperature of milling, and the reactivity of the species.

Process

The process of mechanical alloying involves the production of a composite powder particles by:

  1. Using a high energy mill to favor plastic deformation required for cold welding and reduce the process times
  2. Using a mixture of elemental and master alloy powders (the latter to reduce the activity of the element, since it is known that the activity in an alloy or a compound could be orders of magnitude less than in a pure metal)
  3. Eliminating the use of surface-active agents which would produce fine pyrophoric powder as well as contaminate the powder
  4. Relying on a constant interplay between welding and fracturing to yield a powder with a refined internal structure, typical of very fine powders normally produced, but having an overall particle size which was relatively coarse, and therefore stable.
Narrow particle size distribution. MA Size Distribution.jpg
Narrow particle size distribution.

Milling

During high-energy milling the powder particles are repeatedly flattened, cold welded, fractured and rewelded. Whenever two steel balls collide, some powder is trapped between them. Typically, around 1000 particles with an aggregate weight of about 0.2 mg are trapped during each collision. The force of the impact plastically deforms the powder particles, leading to work hardening and fracture. The new surfaces thus created enable the particles to weld together; this leads to an increase in particle size. Since in the early stages of milling, the particles are soft (if using either ductile-ductile or ductile-brittle material combination), their tendency to weld together and form large particles is high. A broad range of particle sizes develops, with some as large as three times larger than the starting particles. The composite particles at this stage have a characteristic layered structure consisting of various combinations of the starting constituents. With continued deformation particles become work hardened, and fracture by a fatigue failure mechanism and/or by the fragmentation of fragile flakes.

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<span class="mw-page-title-main">Ductility</span> Degree to which a material under stress irreversibly deforms before failure

Ductility refers to the ability of a material to sustain significant plastic deformation before fracture. Plastic deformation is the permanent distortion of a material under applied stress, as opposed to elastic deformation, which is reversible upon removing the stress. Ductility is a critical mechanical performance indicator, particularly in applications that require materials to bend, stretch, or deform in other ways without breaking. The extent of ductility can be quantitatively assessed using the percent elongation at break, given by the equation:

In materials science, a metal matrix composite (MMC) is a composite material with fibers or particles dispersed in a metallic matrix, such as copper, aluminum, or steel. The secondary phase is typically a ceramic or another metal. They are typically classified according to the type of reinforcement: short discontinuous fibers (whiskers), continuous fibers, or particulates. There is some overlap between MMCs and cermets, with the latter typically consisting of less than 20% metal by volume. When at least three materials are present, it is called a hybrid composite. MMCs can have much higher strength-to-weight ratios, stiffness, and ductility than traditional materials, so they are often used in demanding applications. MMCs typically have lower thermal and electrical conductivity and poor resistance to radiation, limiting their use in the very harshest environments.

<span class="mw-page-title-main">Powder metallurgy</span> Process of sintering metal powders

Powder metallurgy (PM) is a term covering a wide range of ways in which materials or components are made from metal powders. PM processes are sometimes used to reduce or eliminate the need for subtractive processes in manufacturing, lowering material losses and reducing the cost of the final product. This occurs especially often with small metal parts, like gears for small machines. Some porous products, allowing liquid or gas to permeate them, are produced in this way. They are also used when melting a material is impractical, due to it having a high melting point, or an alloy of two mutually insoluble materials, such as a mixture of copper and graphite.

<span class="mw-page-title-main">Maraging steel</span> Steel known for strength and toughness

Maraging steels are steels that are known for possessing superior strength and toughness without losing ductility. Aging refers to the extended heat-treatment process. These steels are a special class of very-low-carbon ultra-high-strength steels that derive their strength not from carbon, but from precipitation of intermetallic compounds. The principal alloying element is 15 to 25 wt% nickel. Secondary alloying elements, which include cobalt, molybdenum and titanium, are added to produce intermetallic precipitates. Original development was carried out on 20 and 25 wt% Ni steels to which small additions of aluminium, titanium, and niobium were made; a rise in the price of cobalt in the late 1970s led to the development of cobalt-free maraging steels.

<span class="mw-page-title-main">Galling</span> Form of wear caused by adhesion between sliding surfaces

Galling is a form of wear caused by adhesion between sliding surfaces. When a material galls, some of it is pulled with the contacting surface, especially if there is a large amount of force compressing the surfaces together. Galling is caused by a combination of friction and adhesion between the surfaces, followed by slipping and tearing of crystal structure beneath the surface. This will generally leave some material stuck or even friction welded to the adjacent surface, whereas the galled material may appear gouged with balled-up or torn lumps of material stuck to its surface.

<span class="mw-page-title-main">Inconel</span> Austenitic nickel-chromium superalloys

Inconel is a nickel-chromium-based superalloy often utilized in extreme environments where components are subjected to high temperature, pressure or mechanical loads. Inconel alloys are oxidation- and corrosion-resistant. When heated, Inconel forms a thick, stable, passivating oxide layer protecting the surface from further attack. Inconel retains strength over a wide temperature range, attractive for high-temperature applications where aluminum and steel would succumb to creep as a result of thermally-induced crystal vacancies. Inconel's high-temperature strength is developed by solid solution strengthening or precipitation hardening, depending on the alloy.

<span class="mw-page-title-main">Work hardening</span> Strengthening a material through plastic deformation

Work hardening, also known as strain hardening, is the process by which a material's load-bearing capacity (strength) increases during plastic (permanent) deformation. This characteristic is what sets ductile materials apart from brittle materials. Work hardening may be desirable, undesirable, or inconsequential, depending on the application.

<span class="mw-page-title-main">Superalloy</span> Alloy with higher durability than normal metals

A superalloy, or high-performance alloy, is an alloy with the ability to operate at a high fraction of its melting point. Key characteristics of a superalloy include mechanical strength, thermal creep deformation resistance, surface stability, and corrosion and oxidation resistance.

<span class="mw-page-title-main">Microstructure</span> Very small scale structure of material

Microstructure is the very small scale structure of a material, defined as the structure of a prepared surface of material as revealed by an optical microscope above 25× magnification. The microstructure of a material can strongly influence physical properties such as strength, toughness, ductility, hardness, corrosion resistance, high/low temperature behaviour or wear resistance. These properties in turn govern the application of these materials in industrial practice.

Titanium powder metallurgy (P/M) offers the possibility of creating net shape or near net shape parts without the material loss and cost associated with having to machine intricate components from wrought billet. Powders can be produced by the blended elemental technique or by pre-alloying and then consolidated by metal injection moulding, hot isostatic pressing, direct powder rolling or laser engineered net shaping.

<span class="mw-page-title-main">Magnesium alloy</span> Mixture of magnesium with other metals

Magnesium alloys are mixtures of magnesium with other metals, often aluminium, zinc, manganese, silicon, copper, rare earths and zirconium. Magnesium alloys have a hexagonal lattice structure, which affects the fundamental properties of these alloys. Plastic deformation of the hexagonal lattice is more complicated than in cubic latticed metals like aluminium, copper and steel; therefore, magnesium alloys are typically used as cast alloys, but research of wrought alloys has been more extensive since 2003. Cast magnesium alloys are used for many components of modern cars and have been used in some high-performance vehicles; die-cast magnesium is also used for camera bodies and components in lenses.

<span class="mw-page-title-main">Thermal spraying</span> Coating process for applying heated materials to a surface

Thermal spraying techniques are coating processes in which melted materials are sprayed onto a surface. The "feedstock" is heated by electrical or chemical means.

<span class="mw-page-title-main">Cold spraying</span> Coating deposition method

Gas dynamic cold spraying or cold spraying (CS) is a coating deposition method. Solid powders are accelerated in a supersonic gas jet to velocities up to ca. 1200 m/s. During impact with the substrate, particles undergo plastic deformation and adhere to the surface. To achieve a uniform thickness the spraying nozzle is scanned along the substrate. Metals, polymers, ceramics, composite materials and nanocrystalline powders can be deposited using cold spraying. The kinetic energy of the particles, supplied by the expansion of the gas, is converted to plastic deformation energy during bonding. Unlike thermal spraying techniques, e.g., plasma spraying, arc spraying, flame spraying, or high velocity oxygen fuel (HVOF), the powders are not melted during the spraying process.

A cryogenic treatment is the process of treating workpieces to cryogenic temperatures in order to remove residual stresses and improve wear resistance in steels and other metal alloys, such as aluminum. In addition to seeking enhanced stress relief and stabilization, or wear resistance, cryogenic treatment is also sought for its ability to improve corrosion resistance by precipitating micro-fine eta carbides, which can be measured before and after in a part using a quantimet.

Electron-beam additive manufacturing, or electron-beam melting (EBM) is a type of additive manufacturing, or 3D printing, for metal parts. The raw material is placed under a vacuum and fused together from heating by an electron beam. This technique is distinct from selective laser sintering as the raw material fuses have completely melted. Selective Electron Beam Melting (SEBM) emerged as a powder bed-based additive manufacturing (AM) technology and was brought to market in 1997 by Arcam AB Corporation headquartered in Sweden.

Oxide dispersion strengthened alloys (ODS) are alloys that consist of a metal matrix with small oxide particles dispersed within it. They have high heat resistance, strength, and ductility. Alloys of nickel are the most common but includes iron aluminum alloys.

Severe plastic deformation (SPD) is a generic term describing a group of metalworking techniques involving very large strains typically involving a complex stress state or high shear, resulting in a high defect density and equiaxed "ultrafine" grain (UFG) size or nanocrystalline (NC) structure.

<span class="mw-page-title-main">Friction stir processing</span>

Friction stir processing (FSP) is a method of changing the properties of a metal through intense, localized plastic deformation. This deformation is produced by forcibly inserting a non-consumable tool into the workpiece, and revolving the tool in a stirring motion as it is pushed laterally through the workpiece. The precursor of this technique, friction stir welding, is used to join multiple pieces of metal without creating the heat affected zone typical of fusion welding.

<span class="mw-page-title-main">Selective laser melting</span> 3D printing technique

Selective laser melting (SLM) is one of many proprietary names for a metal additive manufacturing (AM) technology that uses a bed of powder with a source of heat to create metal parts. Also known as direct metal laser sintering (DMLS), the ASTM standard term is powder bed fusion (PBF). PBF is a rapid prototyping, 3D printing, or additive manufacturing technique designed to use a high power-density laser to melt and fuse metallic powders together.

Cold spray additive manufacturing (CSAM) is a particular application of cold spraying, able to fabricate freestanding parts or to build features on existing components. During the process, fine powder particles are accelerated in a high-velocity compressed gas stream, and upon the impact on a substrate or backing plate, deform and bond together creating a layer. Moving the nozzle over a substrate repeatedly, a deposit is building up layer-by-layer, to form a part or component. If an industrial robot or computer controlled manipulator controls the spray gun movements, complex shapes can be created. To achieve a 3D shape, there are two different approaches. First, to fix the substrate and move the cold spray gun/nozzle using a robotic arm; the second one is to move the substrate with a robotic arm, and keep the spray-gun nozzle fixed. There is also a possibility to combine these two approaches either using two robotic arms or other manipulators. The process always requires a substrate and uses only powder as raw material.

References

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  2. Suryanarayana C. Mechanical alloying and milling, Progress in Materials Science 46 (2001) 1-184
  3. Edalati, Kaveh; et al. (2024). "Severe plastic deformation for producing superfunctional ultrafine-grainedand heterostructured materials: An interdisciplinary review". Journal of Alloys and Compounds. 1002: 174667. doi: 10.1016/j.jallcom.2024.174667 .
  4. Suryanarayana, C (January 2001). "Mechanical alloying and milling". Progress in Materials Science. 46 (1–2): 1–184. doi:10.1016/S0079-6425(99)00010-9.
  5. Goncharov, I.S.; Razumov, N.G.; Silin, A.O.; Ozerskoi, N.E.; Shamshurin, A.I.; Kim, A.; Wang, Q.S.; Popovich, A.A. (June 2019). "Synthesis of Nb-based powder alloy by mechanical alloying and plasma spheroidization processes for additive manufacturing". Materials Letters. 245: 188–191. doi:10.1016/j.matlet.2019.03.014.
  6. Demetrio, Ketner (2011). Cryomilling and Spark Plasma Sintering of 2024 Aluminum Alloy. University of Trento.