Mechanical alloying

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Mechanical alloying (MA) is a solid-state and powder processing technique involving repeated cold welding, fracturing, and re-welding of blended powder particles in a high-energy ball mill to produce a homogeneous material. Originally developed to produce oxide-dispersion strengthened (ODS) nickel- and iron-base superalloys for applications in the aerospace industry, [1] MA has now been shown to be capable of synthesizing a variety of equilibrium and non-equilibrium alloy phases starting from blended elemental or pre-alloyed powders. [2] The non-equilibrium phases synthesized include supersaturated solid solutions, metastable crystalline and quasicrystalline phases, nanostructures, and amorphous alloys.

Contents

Alloying during high-energy milling. MA Scheme.jpg
Alloying during high-energy milling.

Metal mixes

Mechanical alloying is akin to metal powder processing, where metals may be mixed to produce superalloys. Mechanical alloying occurs in three steps. First, the alloy materials are combined in a ball mill and ground to a fine powder. A hot isostatic pressing (HIP) process is then applied to simultaneously compress and sinter the powder. A final heat treatment stage helps remove existing internal stresses produced during any cold compaction [ broken anchor ] which may have been used. This produces an alloy suitable for high heat turbine blades and aerospace components.

Design

Design parameters include type of mill, milling container, milling speed, milling time, type, size, and size distribution of the grinding medium, ball-to-powder weight ratio, extent of filling the vial, milling atmosphere, process control agent, temperature of milling, and the reactivity of the species.

Process

The process of mechanical alloying involves the production of a composite powder particles by:

  1. Using a high energy mill to favor plastic deformation required for cold welding and reduce the process times
  2. Using a mixture of elemental and master alloy powders (the latter to reduce the activity of the element, since it is known that the activity in an alloy or a compound could be orders of magnitude less than in a pure metal)
  3. Eliminating the use of surface-active agents which would produce fine pyrophoric powder as well as contaminate the powder
  4. Relying on a constant interplay between welding and fracturing to yield a powder with a refined internal structure, typical of very fine powders normally produced, but having an overall particle size which was relatively coarse, and therefore stable.
Narrow particle size distribution. MA Size Distribution.jpg
Narrow particle size distribution.

Milling

During high-energy milling the powder particles are repeatedly flattened, cold welded, fractured and rewelded. Whenever two steel balls collide, some powder is trapped between them. Typically, around 1000 particles with an aggregate weight of about 0.2 mg are trapped during each collision. The force of the impact plastically deforms the powder particles, leading to work hardening and fracture. The new surfaces thus created enable the particles to weld together; this leads to an increase in particle size. Since in the early stages of milling, the particles are soft (if using either ductile-ductile or ductile-brittle material combination), their tendency to weld together and form large particles is high. A broad range of particle sizes develops, with some as large as three times larger than the starting particles. The composite particles at this stage have a characteristic layered structure consisting of various combinations of the starting constituents. With continued deformation particles become work hardened, and fracture by a fatigue failure mechanism and/or by the fragmentation of fragile flakes.

Related Research Articles

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<span class="mw-page-title-main">Brazing</span> Metal-joining technique

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<span class="mw-page-title-main">High-strength low-alloy steel</span> Type of alloy steel

High-strength low-alloy steel (HSLA) is a type of alloy steel that provides better mechanical properties or greater resistance to corrosion than carbon steel. HSLA steels vary from other steels in that they are not made to meet a specific chemical composition but rather specific mechanical properties. They have a carbon content between 0.05 and 0.25% to retain formability and weldability. Other alloying elements include up to 2.0% manganese and small quantities of copper, nickel, niobium, nitrogen, vanadium, chromium, molybdenum, titanium, calcium, rare-earth elements, or zirconium. Copper, titanium, vanadium, and niobium are added for strengthening purposes. These elements are intended to alter the microstructure of carbon steels, which is usually a ferrite-pearlite aggregate, to produce a very fine dispersion of alloy carbides in an almost pure ferrite matrix. This eliminates the toughness-reducing effect of a pearlitic volume fraction yet maintains and increases the material's strength by refining the grain size, which in the case of ferrite increases yield strength by 50% for every halving of the mean grain diameter. Precipitation strengthening plays a minor role, too. Their yield strengths can be anywhere between 250–590 megapascals (36,000–86,000 psi). Because of their higher strength and toughness HSLA steels usually require 25 to 30% more power to form, as compared to carbon steels.

<span class="mw-page-title-main">Powder metallurgy</span> Process of sintering metal powders

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<span class="mw-page-title-main">Creep (deformation)</span> Tendency of a solid material to move slowly or deform permanently under mechanical stress

In materials science, creep is the tendency of a solid material to undergo slow deformation while subject to persistent mechanical stresses. It can occur as a result of long-term exposure to high levels of stress that are still below the yield strength of the material. Creep is more severe in materials that are subjected to heat for long periods and generally increase as they near their melting point.

<span class="mw-page-title-main">Ball mill</span> Machine used to grind or blend materials

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<span class="mw-page-title-main">Intermetallic</span> Type of metallic alloy

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<span class="mw-page-title-main">Inconel</span> Austenitic nickel-chromium superalloys

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<span class="mw-page-title-main">Work hardening</span> Strengthening a material through plastic deformation

In materials science, work hardening, also known as strain hardening, is the strengthening of a metal or polymer by plastic deformation. Work hardening may be desirable, undesirable, or inconsequential, depending on the context.

<span class="mw-page-title-main">Superalloy</span> Alloy with higher durability than normal metals

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<span class="mw-page-title-main">Microstructure</span> Very small scale structure of material

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<span class="mw-page-title-main">Cold spraying</span> Coating deposition method

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<span class="mw-page-title-main">Friction stir processing</span>

Friction stir processing (FSP) is a method of changing the properties of a metal through intense, localized plastic deformation. This deformation is produced by forcibly inserting a non-consumable tool into the workpiece, and revolving the tool in a stirring motion as it is pushed laterally through the workpiece. The precursor of this technique, friction stir welding, is used to join multiple pieces of metal without creating the heat affected zone typical of fusion welding.

<span class="mw-page-title-main">Selective laser melting</span> 3D printing technique

Selective laser melting (SLM) is one of many proprietary names for a metal additive manufacturing (AM) technology that uses a bed of powder with a source of heat to create metal parts. Also known as direct metal laser sintering (DMLS), the ASTM standard term is powder bed fusion (PBF). PBF is a rapid prototyping, 3D printing, or additive manufacturing technique designed to use a high power-density laser to melt and fuse metallic powders together.

In materials science, toughening refers to the process of making a material more resistant to the propagation of cracks. When a crack propagates, the associated irreversible work in different materials classes is different. Thus, the most effective toughening mechanisms differ among different materials classes. The crack tip plasticity is important in toughening of metals and long-chain polymers. Ceramics have limited crack tip plasticity and primarily rely on different toughening mechanisms.

References

  1. H. K. D. H. Bhadeshia, Practical ODS Alloys, Materials Science and Engineering A, 223 (1997)64-77
  2. Suryanarayana C. Mechanical alloying and milling, Progress in Materials Science 46 (2001) 1-184
  3. Suryanarayana, C (January 2001). "Mechanical alloying and milling". Progress in Materials Science. 46 (1–2): 1–184. doi:10.1016/S0079-6425(99)00010-9.
  4. Demetrio, Ketner (2011). Cryomilling and Spark Plasma Sintering of 2024 Aluminum Alloy. University of Trento.