This article needs additional citations for verification .(January 2017) |
Hot isostatic pressing (HIP) is a manufacturing process, used to reduce the porosity of metals and increase the density of many ceramic materials. This improves the material's mechanical properties and workability.
The process can be used to produce waste form classes. Calcined radioactive waste (waste with additives) is packed into a thin walled metal canister. The adsorbed gases are removed with high heat and the remaining material compressed to full density using argon gas during the heat cycle. This process can shrink steel canisters to minimize space in disposal containers and during transport. It was invented in the 1950s at the Battelle Memorial Institute [1] and has been used to prepare nuclear fuel for submarines since the 1960s. It is used to prepare inactive ceramics as well, and the Idaho National Laboratory has validated it for the consolidation of radioactive ceramic waste forms. ANSTO (Australian Nuclear Science and Technology Organisation) is using HIP as part of a process to immobilize waste radionuclides from molybdenum-99 production. [2]
The HIP process subjects a component to both elevated temperature and isostatic gas pressure within a high-pressure containment vessel, unlike the cold isostatic pressing(CIP), where the component is maintained at room temperature. [3] The pressurizing gas most widely used is argon. An inert gas is used so that the material does not chemically react. The choice of metal can minimize negative effects of chemical reactions. Nickel, stainless or mild steel, or other metals can be chosen depending on the desired redox conditions. The chamber is heated, causing the pressure inside the vessel to increase. Many systems use associated gas pumping to achieve the necessary pressure level. Pressure is applied to the material from all directions (hence the term "isostatic").
For processing castings, metal powders can also be turned to compact solids by this method, the inert gas is applied between 7,350 psi (50.7 MPa) and 45,000 psi (310 MPa), with 15,000 psi (100 MPa) being most common. Process soak temperatures range from 900 °F (482 °C) for aluminium castings to 2,400 °F (1,320 °C) for nickel-based superalloys. When castings are treated with HIP, the simultaneous application of heat and pressure eliminates internal voids and microporosity through a combination of plastic deformation, creep, and diffusion bonding; this process improves fatigue resistance of the component. Primary applications are the reduction of microshrinkage, the consolidation of powder metals, ceramic composites and metal cladding. Hot isostatic pressing is thus also used as part of a sintering (powder metallurgy) process and for fabrication of metal matrix composites, [4] often being used for postprocessing in additive manufacturing. [5]
Sintering or frittage is the process of compacting and forming a solid mass of material by pressure or heat without melting it to the point of liquefaction. Sintering happens as part of a manufacturing process used with metals, ceramics, plastics, and other materials. The nanoparticles in the sintered material diffuse across the boundaries of the particles, fusing the particles together and creating a solid piece.
Powder metallurgy (PM) is a term covering a wide range of ways in which materials or components are made from metal powders. PM processes are sometimes used to reduce or eliminate the need for subtractive processes in manufacturing, lowering material losses and reducing the cost of the final product. This occurs especially often with small metal parts, like gears for small machines. Some porous products, allowing liquid or gas to permeate them, are produced in this way. They are also used when melting a material is impractical, due to it having a high melting point, or an alloy of two mutually insoluble materials, such as a mixture of copper and graphite.
Synroc, a portmanteau of "synthetic rock", is a means of safely storing radioactive waste. It was pioneered in 1978 by a team led by Professor Ted Ringwood at the Australian National University, with further research undertaken in collaboration with ANSTO at research laboratories in Lucas Heights.
A cermet is a composite material composed of ceramic and metal materials.
Plasma arc welding (PAW) is an arc welding process similar to gas tungsten arc welding (GTAW). The electric arc is formed between an electrode and the workpiece. The key difference from GTAW is that in PAW, the electrode is positioned within the body of the torch, so the plasma arc is separated from the shielding gas envelope. The plasma is then forced through a fine-bore copper nozzle which constricts the arc and the plasma exits the orifice at high velocities and a temperature approaching 28,000 °C (50,000 °F) or higher.
Microstructure is the very small scale structure of a material, defined as the structure of a prepared surface of material as revealed by an optical microscope above 25× magnification. The microstructure of a material can strongly influence physical properties such as strength, toughness, ductility, hardness, corrosion resistance, high/low temperature behaviour or wear resistance. These properties in turn govern the application of these materials in industrial practice.
Ceramic forming techniques are ways of forming ceramics, which are used to make everything from tableware such as teapots to engineering ceramics such as computer parts. Pottery techniques include the potter's wheel, slip casting and many others.
Near-net-shape is an industrial manufacturing technique. As the name implies, the initial production of the item is very close to the final, or net, shape. This reduces the need for surface finishing. By minimizing the use of finishing methods like machining or grinding, near-net-shape production eliminates more than two-thirds of the production costs in some industries.
Metal injection molding (MIM) is a metalworking process in which finely-powdered metal is mixed with binder material to create a "feedstock" that is then shaped and solidified using injection molding. Metal injection molding combines the most useful characteristics of powder metallurgy and plastic injection molding to facilitate the production of small, complex-shaped metal components with outstanding mechanical properties. The molding process allows high volume, complex parts to be shaped in a single step. After molding, the part undergoes conditioning operations to remove the binder (debinding) and densify the powders. Finished products are small components used in many industries and applications.
Chromium(II) carbide is a ceramic compound that exists in several chemical compositions: Cr3C2, Cr7C3, and Cr23C6. At standard conditions it exists as a gray solid. It is extremely hard and corrosion resistant. It is also a refractory compound, which means that it retains its strength at high temperatures as well. These properties make it useful as an additive to metal alloys. When chromium carbide crystals are integrated into the surface of a metal it improves the wear resistance and corrosion resistance of the metal, and maintains these properties at elevated temperatures. The hardest and most commonly used composition for this purpose is Cr3C2.
Ceramic engineering is the science and technology of creating objects from inorganic, non-metallic materials. This is done either by the action of heat, or at lower temperatures using precipitation reactions from high-purity chemical solutions. The term includes the purification of raw materials, the study and production of the chemical compounds concerned, their formation into components and the study of their structure, composition and properties.
Titanium powder metallurgy (P/M) offers the possibility of creating net shape or near net shape parts without the material loss and cost associated with having to machine intricate components from wrought billet. Powders can be produced by the blended elemental technique or by pre-alloying and then consolidated by metal injection moulding, hot isostatic pressing, direct powder rolling or laser engineered net shaping.
Spray forming, also known as spray casting, spray deposition and in-situ compaction, is a method of casting near net shape metal components with homogeneous microstructures via the deposition of semi-solid sprayed droplets onto a shaped substrate. In spray forming an alloy is melted, normally in an induction furnace, then the molten metal is slowly poured through a conical tundish into a small-bore ceramic nozzle. The molten metal exits the furnace as a thin free-falling stream and is broken up into droplets by an annular array of gas jets, and these droplets then proceed downwards, accelerated by the gas jets to impact onto a substrate. The process is arranged such that the droplets strike the substrate whilst in the semi-solid condition, this provides sufficient liquid fraction to 'stick' the solid fraction together. Deposition continues, gradually building up a spray formed billet of metal on the substrate.
Gas dynamic cold spraying or cold spraying (CS) is a coating deposition method. Solid powders are accelerated in a supersonic gas jet to velocities up to ca. 1200 m/s. During impact with the substrate, particles undergo plastic deformation and adhere to the surface. To achieve a uniform thickness the spraying nozzle is scanned along the substrate. Metals, polymers, ceramics, composite materials and nanocrystalline powders can be deposited using cold spraying. The kinetic energy of the particles, supplied by the expansion of the gas, is converted to plastic deformation energy during bonding. Unlike thermal spraying techniques, e.g., plasma spraying, arc spraying, flame spraying, or high velocity oxygen fuel (HVOF), the powders are not melted during the spraying process.
Induction plasma, also called inductively coupled plasma, is a type of high temperature plasma generated by electromagnetic induction, usually coupled with argon gas. The magnetic field induces an electric current within the gas which creates the plasma. The plasma can reach temperatures up to 10,000 Kelvin. Inductive plasma technology is used in fields such as powder spheroidization and nano-material synthesis. The technology is applied via an Induction plasma torch, which consists of three basic elements: the induction coil, a confinement chamber, and a torch head, or gas distributor. The main benefit of this technology is the elimination of electrodes, which can deteriorate and introduce contamination.
Hot pressing is a high-pressure, low-strain-rate powder metallurgy process for forming of a powder or powder compact at a temperature high enough to induce sintering and creep processes. This is achieved by the simultaneous application of heat and pressure.
Selective laser melting (SLM) is one of many proprietary names for a metal additive manufacturing (AM) technology that uses a bed of powder with a source of heat to create metal parts. Also known as direct metal laser sintering (DMLS), the ASTM standard term is powder bed fusion (PBF). PBF is a rapid prototyping, 3D printing, or additive manufacturing technique designed to use a high power-density laser to melt and fuse metallic powders together.
Uddeholms AB is a multinational producer of high alloyed tool steel with production in Hagfors, Sweden. Since 1991, the company is part of the Austrian Böhler-Uddeholm group which in turn is part of the voestalpine AG group since 2007. Uddeholms AB has 800 Swedish and 3,000 total employees.
Ultra-high-temperature ceramics (UHTCs) are a type of refractory ceramics that can withstand extremely high temperatures without degrading, often above 2,000 °C. They also often have high thermal conductivities and are highly resistant to thermal shock, meaning they can withstand sudden and extreme changes in temperature without cracking or breaking. Chemically, they are usually borides, carbides, nitrides, and oxides of early transition metals.