Names | |
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IUPAC name Chromium nitride | |
Other names Chromium(III) nitride | |
Identifiers | |
3D model (JSmol) | |
ChemSpider | |
ECHA InfoCard | 100.041.819 |
EC Number |
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PubChem CID | |
UNII | |
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Properties | |
CrN | |
Molar mass | 66.003 g/mol |
Appearance | Black powder |
Density | 5.9 g/cm3 [1] |
Melting point | 1770 ˚C (decomp.) [2] |
Insoluble [3] | |
Thermochemistry | |
Std molar entropy (S | 37.75 J K−1 mol−1 [4] |
Std enthalpy of formation (ΔfH⦵298) | −117.15 kJ/mol [4] |
Hazards | |
Flash point | Non-flammable |
NIOSH (US health exposure limits): | |
PEL (Permissible) | TWA 1 mg/m3 [5] |
REL (Recommended) | TWA 0.5 mg/m3 [5] |
IDLH (Immediate danger) | 250 mg/m3 [5] |
Related compounds | |
Related compounds | Dichromium nitride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Chromium nitride is a chemical compound of chromium and nitrogen with the formula CrN. It is very hard, and is extremely resistant to corrosion. It is an interstitial compound, with nitrogen atoms occupying the octahedral holes in the chromium lattice: [2] as such, it is not strictly a chromium(III) compound nor does it contain nitride ions (N3−). Chromium forms a second interstitial nitride, dichromium nitride, Cr2N.
Chromium(III) nitride can be prepared by direct combination of chromium and nitrogen at 800 °C:
It can also synthesize by Physical Vapour Deposition technique such as Cathodic arc deposition.
CrN is used as a coating material for corrosion resistance and in metal forming and plastic moulding applications. [6] CrN is often used on medical implants and tools. CrN is also a valuable component in advanced multicomponent coating systems, such as CrAlN, for hard, wear-resistant applications on cutting tools. [7]
The fundamental materials physics of CrN, giving rise to its favorable properties, has been debated recently in high-profile scientific journals such as Nature Materials. [8] [9] In particular, the importance of magnetism in both the low temperature and the high temperature phases has been demonstrated by means of quantum mechanical calculations of the electronic structure of the compound. [10] [11] [12]
Though rare, carlsbergite - the natural form of chromium nitride - occurs in some meteorites. [13]
The Wannier functions are a complete set of orthogonal functions used in solid-state physics. They were introduced by Gregory Wannier in 1937. Wannier functions are the localized molecular orbitals of crystalline systems.
A superhard material is a material with a hardness value exceeding 40 gigapascals (GPa) when measured by the Vickers hardness test. They are virtually incompressible solids with high electron density and high bond covalency. As a result of their unique properties, these materials are of great interest in many industrial areas including, but not limited to, abrasives, polishing and cutting tools, disc brakes, and wear-resistant and protective coatings.
Magnetic semiconductors are semiconductor materials that exhibit both ferromagnetism and useful semiconductor properties. If implemented in devices, these materials could provide a new type of control of conduction. Whereas traditional electronics are based on control of charge carriers, practical magnetic semiconductors would also allow control of quantum spin state. This would theoretically provide near-total spin polarization, which is an important property for spintronics applications, e.g. spin transistors.
Titanium nitride is an extremely hard ceramic material, often used as a physical vapor deposition (PVD) coating on titanium alloys, steel, carbide, and aluminium components to improve the substrate's surface properties.
The λ (lambda) universality class is a group in condensed matter physics. It regroups several systems possessing strong analogies, namely, superfluids, superconductors and smectics. All these systems are expected to belong to the same universality class for the thermodynamic critical properties of the phase transition. While these systems are quite different at the first glance, they all are described by similar formalisms and their typical phase diagrams are identical.
Mott insulators are a class of materials that are expected to conduct electricity according to conventional band theories, but turn out to be insulators. These insulators fail to be correctly described by band theories of solids due to their strong electron–electron interactions, which are not considered in conventional band theory. A Mott transition is a transition from a metal to an insulator, driven by the strong interactions between electrons. One of the simplest models that can capture Mott transition is the Hubbard model.
Spin-density wave (SDW) and charge-density wave (CDW) are names for two similar low-energy ordered states of solids. Both these states occur at low temperature in anisotropic, low-dimensional materials or in metals that have high densities of states at the Fermi level . Other low-temperature ground states that occur in such materials are superconductivity, ferromagnetism and antiferromagnetism. The transition to the ordered states is driven by the condensation energy which is approximately where is the magnitude of the energy gap opened by the transition.
Nitriding is a heat treating process that diffuses nitrogen into the surface of a metal to create a case-hardened surface. These processes are most commonly used on low-alloy steels. They are also used on titanium, aluminium and molybdenum.
Helimagnetism is a form of magnetic ordering where spins of neighbouring magnetic moments arrange themselves in a spiral or helical pattern, with a characteristic turn angle of somewhere between 0 and 180 degrees. It results from the competition between ferromagnetic and antiferromagnetic exchange interactions. It is possible to view ferromagnetism and antiferromagnetism as helimagnetic structures with characteristic turn angles of 0 and 180 degrees respectively. Helimagnetic order breaks spatial inversion symmetry, as it can be either left-handed or right-handed in nature.
High-power impulse magnetron sputtering is a method for physical vapor deposition of thin films which is based on magnetron sputter deposition. HIPIMS utilises extremely high power densities of the order of kW⋅cm−2 in short pulses (impulses) of tens of microseconds at low duty cycle of < 10%. Distinguishing features of HIPIMS are a high degree of ionisation of the sputtered metal and a high rate of molecular gas dissociation which result in high density of deposited films. The ionization and dissociation degree increase according to the peak cathode power. The limit is determined by the transition of the discharge from glow to arc phase. The peak power and the duty cycle are selected so as to maintain an average cathode power similar to conventional sputtering (1–10 W⋅cm−2).
Interfacial thermal resistance, also known as thermal boundary resistance, or Kapitza resistance, is a measure of an interface's resistance to thermal flow. This thermal resistance differs from contact resistance because it exists even at atomically perfect interfaces. Owing to differences in electronic and vibrational properties in different materials, when an energy carrier attempts to traverse the interface, it will scatter at the interface. The probability of transmission after scattering will depend on the available energy states on side 1 and side 2 of the interface.
David R. Nelson is an American physicist, and Arthur K. Solomon Professor of Biophysics, at Harvard University.
Titanium aluminium nitride (TiAlN) or aluminium titanium nitride is a group of metastable hard coatings consisting of nitrogen and the metallic elements aluminium and titanium. Four important compositions are deposited in industrial scale by physical vapor deposition methods:
In quantum many-body physics, topological degeneracy is a phenomenon in which the ground state of a gapped many-body Hamiltonian becomes degenerate in the limit of large system size such that the degeneracy cannot be lifted by any local perturbations.
Symmetry-protected topological (SPT) order is a kind of order in zero-temperature quantum-mechanical states of matter that have a symmetry and a finite energy gap.
Scissors Modes are collective excitations in which two particle systems move with respect to each other conserving their shape. For the first time they were predicted to occur in deformed atomic nuclei by N. LoIudice and F. Palumbo, who used a semiclassical Two Rotor Model, whose solution required a realization of the O(4) algebra that was not known in mathematics. In this model protons and neutrons were assumed to form two interacting rotors to be identified with the blades of scissors. Their relative motion (Fig.1) generates a magnetic dipole moment whose coupling with the electromagnetic field provides the signature of the mode.
High-entropy alloys (HEAs) are alloys that are formed by mixing equal or relatively large proportions of (usually) five or more elements. Prior to the synthesis of these substances, typical metal alloys comprised one or two major components with smaller amounts of other elements. For example, additional elements can be added to iron to improve its properties, thereby creating an iron-based alloy, but typically in fairly low proportions, such as the proportions of carbon, manganese, and others in various steels. Hence, high-entropy alloys are a novel class of materials. The term "high-entropy alloys" was coined because the entropy increase of mixing is substantially higher when there is a larger number of elements in the mix, and their proportions are more nearly equal.
Vladimir G. Dubrovskii is the head of Laboratory of physics of nanostructures at St. Petersburg Academic University, a leading research scientist at Ioffe Institute, and a professor at St. Petersburg State University and ITMO University.
Caesium sesquioxide is a chemical compound with the formula Cs2O3 or Cs4O6. In terms of oxidation states, Caesium in this compound has a nominal charge of +1, and the oxygen is a mixed peroxide (O22-) and superoxide (O2−) for a structural formula of (Cs+)4(O2−)2(O22-). Compared to the other caesium oxides, this phase is less well studied, but has been long present in the literature. It can be created by thermal decomposition of caesium superoxide at 290 °C.
Europium(II) oxide (EuO) is a chemical compound which is one of the oxides of europium. In addition to europium(II) oxide, there is also europium(III) oxide and the mixed valence europium(II,III) oxide.