Sodium nitride

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Sodium nitride
Rhenium-trioxide-unit-cell-3D-balls-A.png
Names
IUPAC name
Sodium nitride
Identifiers
3D model (JSmol)
ECHA InfoCard 100.032.017 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 235-232-3
  • InChI=1/3Na.N
    Key: ZOULLXMSYSKRPG-UHFFFAOYNA-N
  • [Na]N([Na])[Na]
  • [Na+].[Na+].[Na+].[N-3]
  • [Na+].[Na][N-][Na]
Properties
Na3N
Molar mass 82.976 g/mol
Appearancereddish brown or dark blue solid
Melting point 87 °C (189 °F; 360 K) [1] (decomposes)
reacts
Structure
Cubic, cP4 [2]
Pm3m [2]
Thermochemistry
-151 J/mol [2]
Related compounds
Other anions
Sodium amide
Sodium imide
Other cations
Lithium nitride
Potassium nitride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Sodium nitride is the inorganic compound with the chemical formula Na3N. In contrast to lithium nitride and some other nitrides, sodium nitride is an extremely unstable alkali metal nitride. It can be generated by combining atomic beams of sodium and nitrogen deposited onto a low-temperature sapphire substrate. [1] It readily decomposes into its elements:

Contents

Synthesis

Sodium nitride can be synthesized in two different ways: by the thermal decomposition of NaNH2 or by the direct reaction of the elements. [2] The most common way to successfully synthesize sodium nitride has been done by Dieter Fischer & Martin Jansen and Grigori Vajenine using the latter method. The first way is to introduce desired ratios of Na and N2 in gas phase separately and depositing them in a vacuum chamber on a cooled substrate, which is then heated to room temperate (298 K) to crystallize. [1] The second method is to react elemental sodium with plasma activated nitrogen on a metal surface. This synthesis can be further facilitated by introducing liquid Na-K alloy to the compound with the excess liquid removed and washed with fresh alloy. The solid is then separated from the liquid using a centrifuge. However Vajenine’s method is very air-sensitive and can decompose and combust rapidly, unless exposed to a pure oxygen (O2) environment. [3]

Characteristics

Sodium nitride can be of reddish brown or dark blue color depending on the synthesis of the compound due to intrinsic properties. [1] [3] It shows no signs of decomposition after several weeks when at room temperature. [3] The compound does not have a melting point as it decomposes back into its elemental forms as demonstrated using mass spectrometry around 360 K. [1] [2] The estimated enthalpy of formation for the compound is +64 kJ/mol. [3]

Structure

Sodium nitride seems to be about 90% ionic at room temperature, but has the band gap typical for a semiconductor. [2] [3] It adopts the anti-ReO3 structure with a simple lattice made up of NNa6 octahedra. [1] [2] [3] [4] The compound has N­−Na bond lengths of 236.6 pm. [1] [3] This structure has been confirmed through X-ray diffraction and more recently neutron diffraction on powder and single crystals. [1] [2] [3] [4]

Related Research Articles

<span class="mw-page-title-main">Nitrogen</span> Chemical element, symbol N and atomic number 7

Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at seventh in total abundance in the Milky Way and the Solar System. At standard temperature and pressure, two atoms of the element bind to form N2, a colorless and odorless diatomic gas. N2 forms about 78% of Earth's atmosphere, making it the most abundant uncombined element. Nitrogen occurs in all organisms, primarily in amino acids (and thus proteins), in the nucleic acids (DNA and RNA) and in the energy transfer molecule adenosine triphosphate. The human body contains about 3% nitrogen by mass, the fourth most abundant element in the body after oxygen, carbon, and hydrogen. The nitrogen cycle describes the movement of the element from the air, into the biosphere and organic compounds, then back into the atmosphere.

In chemistry, azide is a linear, polyatomic anion with the formula N−3 and structure N=N+=N. It is the conjugate base of hydrazoic acid HN3. Organic azides are organic compounds with the formula RN3, containing the azide functional group. The dominant application of azides is as a propellant in air bags.

<span class="mw-page-title-main">Manganese(III) fluoride</span> Chemical compound

Manganese(III) fluoride (also known as Manganese trifluoride) is the inorganic compound with the formula MnF3. This red/purplish solid is useful for converting hydrocarbons into fluorocarbons, i.e., it is a fluorination agent. It forms a hydrate and many derivatives.

<span class="mw-page-title-main">Ozonide</span> Polyatomic ion (O3, charge –1), or cyclic compounds made from ozone and alkenes

Ozonide is the polyatomic anion O−3. Cyclic organic compounds formed by the addition of ozone to an alkene are also called ozonides.

<span class="mw-page-title-main">Tetrasulfur tetranitride</span> Chemical compound

Tetrasulfur tetranitride is an inorganic compound with the formula S4N4. This gold-poppy coloured solid is the most important binary sulfur nitride, which are compounds that contain only the elements sulfur and nitrogen. It is a precursor to many S-N compounds and has attracted wide interest for its unusual structure and bonding.

<span class="mw-page-title-main">Sodium thioantimoniate</span> Chemical compound

Sodium thioantimoniate is an inorganic compound with the formula Na3SbS4. The nonahydrate of this material is known as Schlippe's salt, named after K. F. Schlippe (1799–1867), These compounds are examples of sulfosalts. They were once of interest as species generated in qualitative inorganic analysis.

<span class="mw-page-title-main">Ammonia borane</span> Chemical compound

Ammonia borane (also systematically named amminetrihydridoboron), also called borazane, is the chemical compound with the formula H3NBH3. The colourless or white solid is the simplest molecular boron-nitrogen-hydride compound. It has attracted attention as a source of hydrogen fuel, but is otherwise primarily of academic interest.

<span class="mw-page-title-main">Silver carbonate</span> Chemical compound

Silver carbonate is the chemical compound with the formula Ag2CO3. This salt is yellow but typical samples are grayish due to the presence of elemental silver. It is poorly soluble in water, like most transition metal carbonates.

<span class="mw-page-title-main">Polythiazyl</span> Chemical compound

Polythiazyl, (SN)x, is an electrically conductive, gold- or bronze-colored polymer with metallic luster. It was the first conductive inorganic polymer discovered and was also found to be a superconductor at very low temperatures. It is a fibrous solid, described as "lustrous golden on the faces and dark blue-black", depending on the orientation of the sample. It is air stable and insoluble in all solvents.

<span class="mw-page-title-main">Sodium perrhenate</span> Chemical compound

Sodium perrhenate (also known as sodium rhenate(VII)) is the inorganic compound with the formula NaReO4. It is a white salt that is soluble in water. It is a common precursor to other rhenium compounds. Its structure resembles that of sodium perchlorate and sodium permanganate.

<span class="mw-page-title-main">Potassium azide</span> Chemical compound

Potassium azide is the inorganic compound having the formula KN3. It is a white, water-soluble salt. It is used as a reagent in the laboratory.

<span class="mw-page-title-main">Cyanuric triazide</span> Chemical compound

Cyanuric triazide (C3N12 or (NCN3)3) is described as an environmentally friendly, low toxicity, and organic primary explosive with a detonation velocity of about 7,300 m s−1, and ignition temperature at 205 °C. Primary research on this compound focuses on its use as a high energy density compound.

<span class="mw-page-title-main">Triphosphorus pentanitride</span> Chemical compound

Triphosphorus pentanitride is an inorganic compound with the chemical formula P3N5. Containing only phosphorus and nitrogen, this material is classified as a binary nitride. While it has been investigated for various applications this has not led to any significant industrial uses. It is a white solid, although samples often appear colored owing to impurities.

<span class="mw-page-title-main">Hydromelonic acid</span> Chemical compound

Hydromelonic acid, is an elusive chemical compound with formula C
9
H
3
N
13
or (HNCN)
3
(C
6
N
7
)
, whose molecule would consist of a heptazine H3(C
6
N
7
)
molecule, with three cyanamido groups H–N=C=N– or N≡C–NH– substituted for the hydrogen atoms.

In chemistry, a hydridonitride is a chemical compound that contains hydride and nitride ions in a single phase. These inorganic compounds are distinct from inorganic amides and imides as the hydrogen does not share a bond with nitrogen, and contain a larger proportion of metals.

The inorganic imides are compounds containing an ion composed of nitrogen bonded to hydrogen with formula HN2−. Organic imides have the NH group, and two single or one double covalent bond to other atoms. The imides are related to the inorganic amides (H2N), the nitrides (N3−) and the nitridohydrides (N3−•H).

Nitride fluorides containing nitride and fluoride ions with the formula NF4-. They can be electronically equivalent to a pair of oxide ions O24-. Nitride fluorides were discovered in 1996 by Lavalle et al. They heated diammonium technetium hexafluoride to 300 °C to yield TcNF. Another preparation is to heat a fluoride compound with a nitride compound in a solid state reaction. The fluorimido ion is F-N2- and is found in a rhenium compound.

Potassium nitride is an unstable chemical compound. Several syntheses were erroneously claimed in the 19th century, and by 1894 it was assumed that it did not exist.

The nitridogermanates are chemical compounds containing germanium atoms bound to nitrogen. The simplest anion is GeN48−, but these are often condensed, with the elimination of nitrogen.

A chloride nitride is a mixed anion compound containing both chloride (Cl) and nitride ions (N3−). Another name is metallochloronitrides. They are a subclass of halide nitrides or pnictide halides.

References

  1. 1 2 3 4 5 6 7 8 Fischer, D., Jansen, M. (2002). "Synthesis and structure of Na3N". Angew Chem. 41 (10): 1755–1756. doi:10.1002/1521-3773(20020517)41:10<1755::AID-ANIE1755>3.0.CO;2-C. PMID   19750706.{{cite journal}}: CS1 maint: multiple names: authors list (link)Fischer, D.; Cancarevic, Z.; Schön, J. C.; Jansen, M. Z. (2004). "Synthesis and structure of K3N". Z. Anorg. Allg. Chem. 630 (1): 156. doi:10.1002/zaac.200300280.. 'Elusive Binary Compound Prepared' Chemical & Engineering News80 No. 20 (20 May 2002)
  2. 1 2 3 4 5 6 7 8 Sangster, J. (2004). "N-Na(Nitrogen-Sodium) System". Journal of Phase Equilibria and Diffusion. 25 (6): 560–563. doi:10.1007/s11669-004-0082-0. S2CID   97905377.
  3. 1 2 3 4 5 6 7 8 Vajenine, G.V. (2007). "Plasma-Assisted Synthesis and Properties of Na3N". Inorganic Chemistry. 46 (13): 5146–5148. doi:10.1021/ic700406q. PMID   17530752.
  4. 1 2 Vajenine, G. V., Hoch, C., Dinnebier, R. E., Senyshyn, A., Niewa, R. (2009). "A Temperature-dependent Structural Study of anti-ReO3-type Na3N: to Distort or not to Distort?". Zeitschrift für Anorganische und Allgemeine Chemie. 636 (1): 94–99. doi:10.1002/zaac.200900488.{{cite journal}}: CS1 maint: multiple names: authors list (link)