Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical. The corresponding electrically neutral compound HO• is the hydroxyl radical. The corresponding covalently bound group –OH of atoms is the hydroxy group. Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry.
Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations Na+ and hydroxide anions OH−.
Sodium silicate is a generic name for chemical compounds with the formula Na
2xSi
yO
2y+x or (Na
2O)
x·(SiO
2)
y, such as sodium metasilicate, sodium orthosilicate, and sodium pyrosilicate. The anions are often polymeric. These compounds are generally colorless transparent solids or white powders, and soluble in water in various amounts.
Potassium ferrate is an inorganic compound with the formula K2FeO4. It is the potassium salt of ferric acid. Potassium ferrate is a powerful oxidizing agent with applications in green chemistry, organic synthesis, and cathode technology.
Iron(III) oxide-hydroxide or ferric oxyhydroxide is the chemical compound of iron, oxygen, and hydrogen with formula FeO(OH).
Sodium metasilicate is the chemical substance with formula Na
2SiO
3, which is the main component of commercial sodium silicate solutions. It is an ionic compound consisting of sodium cations Na+
and the polymeric metasilicate anions [–SiO2−
3–]n. It is a colorless crystalline hygroscopic and deliquescent solid, soluble in water but not in alcohols.
Sodium formate, HCOONa, is the sodium salt of formic acid, HCOOH. It usually appears as a white deliquescent powder.
Lithium aluminate, also called lithium aluminium oxide, is an inorganic chemical compound, an aluminate of lithium. In microelectronics, lithium aluminate is considered as a lattice matching substrate for gallium nitride. In nuclear technology, lithium aluminate is of interest as a solid tritium breeder material, for preparing tritium fuel for nuclear fusion. Lithium aluminate is a layered double hydroxide (LDH) with a crystal structure resembling that of hydrotalcite. Lithium aluminate solubility at high pH is much lower than that of aluminium oxides. In the conditioning of low- and intermediate level radioactive waste (LILW), lithium nitrate is sometimes used as additive to cement to minimise aluminium corrosion at high pH and subsequent hydrogen production. Indeed, upon addition of lithium nitrate to cement, a passive layer of LiH(AlO
2)
2 · 5 H
2O is formed onto the surface of metallic aluminium waste immobilised in mortar. The lithium aluminate layer is insoluble in cement pore water and protects the underlying aluminium oxide covering the metallic aluminium from dissolution at high pH. It is also a pore filler. This hinders the aluminium oxidation by the protons of water and reduces the hydrogen evolution rate by a factor of 10.
Iron(III) nitrate, or ferric nitrate, is the name used for a series of inorganic compounds with the formula Fe(NO3)3.(H2O)n. Most common is the nonahydrate Fe(NO3)3.(H2O)9. The hydrates are all pale colored, water-soluble paramagnetic salts.
The alkali–silica reaction (ASR), also commonly known as concrete cancer, is a deleterious internal swelling reaction that occurs over time in concrete between the highly alkaline cement paste and the reactive amorphous silica found in many common aggregates, given sufficient moisture.
Barium ferrate is the chemical compound of formula BaFeO4. This is a rare compound containing iron in the +6 oxidation state. The ferrate(VI) ion has two unpaired electrons, making it paramagnetic. It is isostructural with BaSO4, and contains the tetrahedral [FeO4]2− anion.
Eudialyte group is a group of complex trigonal zircono- and, more rarely, titanosilicate minerals with general formula [N(1)N(2)N(3)N(4)N(5)]3[M(1a)M(1b)]3M(2)3M(4)Z3[Si24O72]O'4X2, where N(1) and N(2) and N(3) and N(5) = Na+ and more rarely H3O+ or H2O, N(4) = Na+, Sr2+, Mn2+ and more rarely H3O+ or H2O or K+ or Ca2+ or REE3+ (rare earth elements), M(1) and M(1b) = Ca2+, M(1a) = Ca2+ or Mn2+ or Fe2+, M(2) = Fe (both II and III), Mn and rarely Na+, K+ or Zr4+, M(3) = Si, Nb and rarely W, Ti and [] (vacancy), M(4) = Si and or rarely [], Z Zr4+ and or rarely Ti4+, and X = OH−, Cl− and more rarely CO32− or F−. Some of the eudialyte-like structures can even be more complex, however, in general, its typical feature is the presence of [Si3O9]6− and [Si9O27]18− ring silicate groups. Space group is usually R3m or R-3m but may be reduced to R3 due to cation ordering. Like other zirconosilicates, the eudialyte group minerals possess alkaline ion-exchange properties, as microporous materials.
Green rust is a generic name for various green crystalline chemical compounds containing iron(II) and iron(III) cations, the hydroxide (OH−
) anion, and another anion such as carbonate (CO2−
3), chloride (Cl−
), or sulfate (SO2−
4), in a layered double hydroxide (LDH) structure. The most studied varieties are the following:
Eveslogite is a complex inosilicate mineral with a chemical formula (Ca,K,Na,Sr,Ba)
48[(Ti,Nb,Fe,Mn)
12(OH)
12Si
48O
144](F,OH,Cl)
14 found on Mt. Eveslogchorr in Khibiny Mountains, on the Kola peninsula, Russia. It was named after the place it was found. This silicate mineral occurs as an anchimonomineral veinlet that cross-cuts poikilitic nepheline syenite. This mineral appears to resemble yuksporite, as it forms similar placated fine fibrous of approximately 0.05 to 0.005mm that aggregates outwardly. The color of eveslogite is yellow or rather light brown. In addition, it is a semitransparent mineral that has a white streak and a vitreous luster. Its crystal system is monoclinic and possesses a hardness (Mohs) of 5. This newly discovered mineral belongs to the astrophyllite group of minerals and contains structures that are composed of titanosilicate layers. Limited information about this mineral exists due to the few research studies carried out since its recent discovery.
Dualite is a very rare and complex mineral of the eudialyte group, its complexity being expressed in its formula Na
30(Ca,Na,Ce,Sr)
12(Na,Mn,Fe,Ti)
6Zr
3Ti
3MnSi
51O
144(OH,H
2O,Cl)
9. The formula is simplified as it does not show the presence of cyclic silicate groups. The name of the mineral comes from its dual nature: zircono- and titanosilicate at once. Dualite has two modules in its structure: alluaivite one and eudialyte one. After alluaivite and labyrinthite it stands for third representative of the eudialyte group with essential titanium.
Aluminium triacetate, formally named aluminium acetate, is a chemical compound with composition Al(CH
3CO
2)
3. Under standard conditions it appears as a white, water-soluble solid that decomposes on heating at around 200 °C. The triacetate hydrolyses to a mixture of basic hydroxide / acetate salts, and multiple species co-exist in chemical equilibrium, particularly in aqueous solutions of the acetate ion; the name aluminium acetate is commonly used for this mixed system.
Sodium pyrosilicate is the chemical compound Na
6Si
2O
7. It is one of the sodium silicates, specifically a pyrosilicate, formally a salt of the unstable pyrosilicic acid H
6Si
2O
7.
A pyrosilicate is a type of chemical compound; either an ionic compound that contains the pyrosilicate anionSi
2O6−
7, or an organic compound with the hexavalent ≡O
3Si-O-SiO
3≡ group. The anion is also called disilicate or diorthosilicate.
Lamprophyllite is a rare, but widespread mineral Ti-silicate mineral usually found in intrusive agpasitic igneous rocks. Yellow, reddish brown, Vitreous, Pearly.
Yegorovite, ([Na4[Si4O8(OH)4]·7H2O]) is a silicate mineral found in a hyperalkaline pegmatite in the Lovozero Pluton at Mt. Kedykverpakhk in the Kola Peninsula of Russia. It was named in memory of Russian crystallographer Yurii Kavdievich Yegorov-Tismenko, and approved by the Commission on New Minerals and Mineral Names, International Mineralogical Association in 2008.
