Sodium orthosilicate

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Sodium orthosilicate
Sodium orthosilicate.svg
Chemical structure of sodium orthosilicate
Names
IUPAC name
Tetrasodium silicate
Other names
Sodium orthosilicate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.387 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 236-741-3
PubChem CID
UNII
UN number 1759
  • InChI=1S/4Na.O4Si/c;;;;1-5(2,3)4/q4*+1;-4 Yes check.svgY
    Key: POWFTOSLLWLEBN-UHFFFAOYSA-N Yes check.svgY
  • InChI=1S/4Na.O4Si/c;;;;1-5(2,3)4/q4*+1;-4
    Key: POWFTOSLLWLEBN-UHFFFAOYSA-N
  • [O-][Si]([O-])([O-])[O-].[Na+].[Na+].[Na+].[Na+]
Properties
Na4O4Si
Molar mass 184.040 g·mol−1
AppearanceWhite powder
Melting point 1,018 °C (1,864 °F; 1,291 K)
Hazards
GHS labelling: [1]
GHS-pictogram-acid.svg GHS-pictogram-exclam.svg
Danger
H302, H314, H335
P260, P301+P330+P331, P303+P361+P353, P305+P351+P338, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
X mark.svgN (what is  Yes check.svgYX mark.svgN ?)

Sodium orthosilicate is the chemical compound with the molecular formula Na
4
SiO
4
. It is one of the sodium silicates, specifically an orthosilicate, formally a salt of the unstable orthosilicic acid H
4
SiO
4
. [2] [3] [4]

Contents

Uses

Sodium orthosilicate has been considered as an interfacial tension reducing additive in the waterflooding of oil fields for enhanced oil extraction. In laboratory settings, it was found to be more effective than sodium hydroxide for some types of oil. [5]

Sodium orthosilicate has been found to stabilize ferrate films as an anticorrosion treatment of iron and steel surfaces. [6]

Natural occurrence

Sodium orthosilicate has not been found in nature. However, the mineral chesnokovite, chemically the related salt disodium dihydrogen orthosilicate [Na+
]2[SiO
2
(OH)2−
2
] · 8H
2
O
, was recently identified in the Kola Peninsula. [7]

See also

Related Research Articles

<span class="mw-page-title-main">Hydroxide</span> Chemical compound

Hydroxide is a diatomic anion with chemical formula OH. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical. The corresponding electrically neutral compound HO is the hydroxyl radical. The corresponding covalently bound group –OH of atoms is the hydroxy group. Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry.

<span class="mw-page-title-main">Silicate</span> Any polyatomic anion containing silicon and oxygen

In chemistry, a silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula [SiO(4-2x)−
4−x
]
n
, where 0 ≤ x < 2. The family includes orthosilicate SiO4−4, metasilicate SiO2−3, and pyrosilicate Si2O6−7. The name is also used for any salt of such anions, such as sodium metasilicate; or any ester containing the corresponding chemical group, such as tetramethyl orthosilicate. The name "silicate" is sometimes extended to any anions containing silicon, even if they do not fit the general formula or contain other atoms besides oxygen; such as hexafluorosilicate [SiF6]2−.Most commonly, silicates are encountered as silicate minerals.

<span class="mw-page-title-main">Sodium hydroxide</span> Chemical compound with formula NaOH

Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations Na+ and hydroxide anions OH.

<span class="mw-page-title-main">Natron</span> Carbonate mineral

Natron is a naturally occurring mixture of sodium carbonate decahydrate (Na2CO3·10H2O, a kind of soda ash) and around 17% sodium bicarbonate (also called baking soda, NaHCO3) along with small quantities of sodium chloride and sodium sulfate. Natron is white to colourless when pure, varying to gray or yellow with impurities. Natron deposits are sometimes found in saline lake beds which arose in arid environments. Throughout history natron has had many practical applications that continue today in the wide range of modern uses of its constituent mineral components.

<span class="mw-page-title-main">Sodium carbonate</span> Chemical compound

Sodium carbonate is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield alkaline solutions in water. Historically, it was extracted from the ashes of plants grown in sodium-rich soils. Because the ashes of these sodium-rich plants were noticeably different from ashes of wood, sodium carbonate became known as "soda ash". It is produced in large quantities from sodium chloride and limestone by the Solvay process, as well as by carbonating sodium hydroxide which is made using the Chlor-alkali process.

<span class="mw-page-title-main">Ferrate(VI)</span> Ion

Ferrate(VI) is the inorganic anion with the chemical formula [FeO4]2−. It is photosensitive, contributes a pale violet colour to compounds and solutions containing it and is one of the strongest water-stable oxidizing species known. Although it is classified as a weak base, concentrated solutions containing ferrate(VI) are corrosive and attack the skin and are only stable at high pH.

<span class="mw-page-title-main">Sodium metasilicate</span> Chemical compound

Sodium metasilicate is the chemical substance with formula Na
2
SiO
3
, which is the main component of commercial sodium silicate solutions. It is an ionic compound consisting of sodium cations Na+
and the polymeric metasilicate anions [–SiO2−
3
–]n. It is a colorless crystalline hygroscopic and deliquescent solid, soluble in water but not in alcohols.

<span class="mw-page-title-main">Sodium formate</span> Chemical compound

Sodium formate, HCOONa, is the sodium salt of formic acid, HCOOH. It usually appears as a white deliquescent powder.

<span class="mw-page-title-main">Barium ferrate</span> Chemical compound

Barium ferrate is the chemical compound of formula BaFeO4. This is a rare compound containing iron in the +6 oxidation state. The ferrate(VI) ion has two unpaired electrons, making it paramagnetic. It is isostructural with BaSO4, and contains the tetrahedral [FeO4]2− anion.

Alsakharovite-Zn (IMA symbol: Ask-Zn) is an extremely rare alkaline strontium zinc titanium silicate mineral from the cyclosilicates class, with the chemical formula NaSrKZn(Ti,Nb)4(Si4O12)2(O,OH)4·7H2O, from alkaline pegmatites. It belongs to the labuntsovite group.

Coyoteite is a hydrated sodium iron sulfide mineral. The mineral was named coyoteite after Coyote Peak near Orick, California where it was discovered.

Banalsite is a rare barium, sodium aluminium silicate mineral with formula: BaNa2Al4Si4O16. Banalsite is a tectosilicate of the feldspar group.

Nabalamprophyllite has a general formula of Ba(Na,Ba){Na3Ti[Ti2O2Si4O14](OH,F)2}. The name is given for its composition and relation to other lamprophyllite-group minerals. Lamprophyllite is a rare Ti-bearing silicate mineral usually found in intrusive igneous rocks.

The purpose of a mineralizer is to facilitate the transport of insoluble “nutrient” to a seed crystal by means of a reversible chemical reaction. Over time, the seed crystal accumulates the material that was once in the nutrient and grows. Mineralizers are additives that aid the solubilization of the nutrient solid. When used in small quantities, mineralizers function as catalysts. Typically, a more stable solid is crystallized from a solution that consists of a less stable solid and a solvent. The process is done by dissolution-precipitation or crystallization process.

Eveslogite is a complex inosilicate mineral with a chemical formula (Ca,K,Na,Sr,Ba)
48
[(Ti,Nb,Fe,Mn)
12
(OH)
12
Si
48
O
144
](F,OH,Cl)
14
found on Mt. Eveslogchorr in Khibiny Mountains, on the Kola peninsula, Russia. It was named after the place it was found. This silicate mineral occurs as an anchimonomineral veinlet that cross-cuts poikilitic nepheline syenite. This mineral appears to resemble yuksporite, as it forms similar placated fine fibrous of approximately 0.05 to 0.005mm that aggregates outwardly. The color of eveslogite is yellow or rather light brown. In addition, it is a semitransparent mineral that has a white streak and a vitreous luster. Its crystal system is monoclinic and possesses a hardness (Mohs) of 5. This newly discovered mineral belongs to the astrophyllite group of minerals and contains structures that are composed of titanosilicate layers. Limited information about this mineral exists due to the few research studies carried out since its recent discovery.

<span class="mw-page-title-main">Gyrolite</span> Rare phyllosilicate mineral crystallizing in spherules

Gyrolite, NaCa16(Si23Al)O60(OH)8·14H2O, is a rare silicate mineral (basic sodium calcium silicate hydrate: N-C-S-H, in cement chemist notation) belonging to the class of phyllosilicates. Gyrolite is also often associated with zeolites. It is most commonly found as spherical or radial formations in hydrothermally altered basalt and basaltic tuffs. These formations can be glassy, dull or fibrous in appearance.

Labyrinthite is a very rare mineral of the eudialyte group. When compared to other species in the group, its structure is extremely complex - with over 100 sites and about 800 cations and anions - hence its name, with its complexity expressed in its chemical formula (Na,K,Sr)35Ca12Fe3Zr6TiSi51O144(O,OH,H2O)9Cl3. The formula is simplified as it does not show the presence of cyclic silicate groups. Complexity of the structure results in symmetry lowering from the typical centrosymmetrical group to R3 space group. Other eudialyte-group representatives with such symmetry lowering include aqualite, oneillite, raslakite, voronkovite. Labyrinthite is the second dual-nature representative of the group after dualite and third with essential titanium after dualite and alluaivite.

Voronkovite is a very rare mineral of the eudialyte group with the chemical formula Na15(Na,Ca,Ce)3(Mn,Ca)3Fe3Zr3Si2Si24O72(OH,O)4Cl·H2O. The formula is based on the simplified original one; it does not show the presence of cyclic silicate groups, but two M3- and M4-site silicon atoms are shown separately (basing on the nomenclature of the eudialyte group). Voronkovite has lowered symmetry (space group R3, instead of more specific for the group R3m one), similarly to some other eudialyte-group members: aqualite, labyrinthite, oneillite and raslakite. The specific feature of voronkovite is, among others, strong enrichment in sodium.

<span class="mw-page-title-main">Rastsvetaevite</span> Mineral of the eudialyte group

Rastsveatevite is a rare mineral of the eudialyte group with the chemical formula Na27K8Ca12Fe3Zr6Si4[Si3O9]4[Si9O27]4(O,OH,H2O)6Cl2. Its structure is modular. It is only the third member of the group after andrianovite and davinciite with essential (site-dominating) potassium. Potassium and sodium enter both N4 and M2 sites. The mineral is named after Russian crystallographer Ramiza K. Rastsvetaeva.

Sodium pyrosilicate is the chemical compound Na
6
Si
2
O
7
. It is one of the sodium silicates, specifically a pyrosilicate, formally a salt of the unstable pyrosilicic acid H
6
Si
2
O
7
.

References

  1. "Sodium Orthosilicate". American Elements . Retrieved September 18, 2018.
  2. Baur, Werner H.; Halwax, Erich; Völlenkle, Horst (1986). "Comparison of the crystal structures of sodium orthosilicate, Na
    4
    SiO
    4
    , and sodium orthogermanate, Na
    4
    GeO
    4
    ". Monatshefte für Chemie Chemical Monthly. 117 (6–7): 793–797. doi:10.1007/BF00810070. S2CID   92420380.
  3. M,. G. Barker, P. G.Gadd (1981): "The preparation and crystal structure of sodium orthosilicate, Na
    4
    SiO
    4
    ." Journal of Chemical Research, London] Chemical Society, volume 9, pages S:274 (synopse), M:3446-3466 (main).
  4. Schairer, J. F.; Bowen, N. L. (1956). "The system Na
    2
    O
    Al
    2
    O
    3
    SiO
    2
    ". American Journal of Science. 254 (3): 129–195. Bibcode:1956AmJS..254..129S. doi:10.2475/ajs.254.3.129.
  5. Campbell, Thomas C. (1977). "A Comparison of Sodium Orthosilicate and Sodium Hydroxide for Alkaline Waterflooding". All Days. Society of Petroleum engineers, SPE California Regional Meeting 13–15 April 1977, Bakersfield. doi:10.2118/6514-MS.
  6. John R. Harrison (1954): "Process for treating metals with ferrate solution". US Patent US2850415A, assigned to E. I. du Pont de Nemours
  7. Pekov, I. V.; Chukanov, N. V.; Zadov, A. E.; Zubkova, N. V.; Pushcharovsky, D. Yu. (2007). "Chesnokovite, Na2[SiO2(OH)2] · 8H2O, the first natural sodium orthosilicate from the Lovozero alkaline pluton, Kola Peninsula: Description and crystal structure of a new mineral species". Geology of Ore Deposits. 49 (8): 727–738. Bibcode:2007GeoOD..49..727P. doi:10.1134/S1075701507080077. S2CID   94817330.