Sodium dihydrogen arsenate

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Sodium dihydrogen arsenate
Structural formula of sodium dihydrogen arsenate.svg
Names
IUPAC name
Sodium dihydrogen arsenate
Other names
sodium arsenate monobasic, sodium dihydroarsenate
Identifiers
3D model (JSmol)
PubChem CID
  • InChI=1S/AsH3O4.Na/c2-1(3,4)5;/h(H3,2,3,4,5);/q;+1/p-1
    Key: XCVRTGQHVBWRJB-UHFFFAOYSA-M
  • O[As](=O)(O)[O-].[Na+]
Properties
NaH4AsO5 (monohydrate)
Molar mass 181.9 g/mol
Appearancecolourless solid
Density 2.53 g/cm3
slightly soluble
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
toxic
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Sodium dihydrogen arsenate is the inorganic compound with the formula NaH2AsO4. Related salts are also called sodium arsenate, including Na2HAsO4 (disodium hydrogen arsenate) and NaH2AsO4 (sodium dihydrogen arsenate). Sodium dihydrogen arsenate is a colorless solid that is highly toxic.

The salt is the conjugate base of arsenic acid:

H3AsO4 H2AsO
4
+ H+ (K1 = 10−2.19)

In the laboratory, it is prepared in this way, crystallizing from a hot saturated aqueous solution, where it is highly soluble when hot (75.3 g in 100 mL at 100 °C). It is obtained as the monohydrate.

Upon heating, solid NaH2AsO4H2O, loses water of crystallization and converts to the pyroarsenate salt Na2H2As2O7. [1]

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Sodium peroxide Chemical compound

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Sodium superoxide Chemical compound

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The arsenate ion is AsO3−
4
. An arsenate (compound) is any compound that contains this ion. Arsenates are salts or esters of arsenic acid. The arsenic atom in arsenate has a valency of 5 and is also known as pentavalent arsenic or As(V). Arsenate resembles phosphate in many respects, since arsenic and phosphorus occur in the same group (column) of the periodic table. Arsenates are moderate oxidizers, with an electrode potential of +0.56 V for reduction to arsenites.

Arsenic acid Chemical compound

Arsenic acid is the chemical compound with the formula H3AsO4. More descriptively written as AsO(OH)3, this colorless acid is the arsenic analogue of phosphoric acid. Arsenate and phosphate salts behave very similarly. Arsenic acid as such has not been isolated, but is only found in solution, where it is largely ionized. Its hemihydrate form (2H3AsO4·H2O) does form stable crystals. Crystalline samples dehydrate with condensation at 100 °C.

Arsenic pentoxide Chemical compound

Arsenic pentoxide is the inorganic compound with the formula As2O5. This glassy, white, deliquescent solid is relatively unstable, consistent with the rarity of the As(V) oxidation state. More common, and far more important commercially, is arsenic(III) oxide (As2O3). All inorganic arsenic compounds are highly toxic and thus find only limited commercial applications.

Sodium dichromate Inorganic compound

Sodium dichromate is the inorganic compound with the formula Na2Cr2O7. However, the salt is usually handled as its dihydrate Na2Cr2O7·2H2O. Virtually all chromium ore is processed via conversion to sodium dichromate and virtually all compounds and materials based on chromium are prepared from this salt. In terms of reactivity and appearance, sodium dichromate and potassium dichromate are very similar. The sodium salt is, however, around twenty times more soluble in water than the potassium salt (49 g/L at 0 °C) and its equivalent weight is also lower, which is often desirable.

Sodium phosphide Chemical compound

Sodium phosphide is the inorganic compound with the formula Na3P. It is a black solid. It is often described as Na+ salt of the P3− anion. Na3P is a source of the highly reactive phosphide anion. It should not be confused with sodium phosphate, Na3PO4.

Hexafluorosilicic acid Octahedric silicon compound

Hexafluorosilicic acid is an inorganic compound with the chemical formula H
2
SiF
6
. Although no evidence has been presented for the existence of this species in solution or as a solid, aqueous solutions of hexafluorosilicic acid are well-defined, consisting of salts derived from various protonated forms of water as the cation and hexafluorosilicate as the anion. These salts and their aqueous solutions are colorless.

Calcium arsenate Chemical compound

Calcium arsenate is the inorganic compound with the formula Ca3(AsO4)2. A colourless salt, it was originally used as a pesticide and as a germicide. It is highly soluble in water, as compared with lead arsenate, which makes it more toxic. The minerals rauenthalite Ca3(AsO4)2·10H2O and phaunouxite Ca3(AsO4)2·11H2O are hydrates of calcium arsenate.

Zinc pyrophosphate Chemical compound

Zinc pyrophosphate (Zn2P2O7) is an ionic inorganic chemical compound composed of Zn2+ cations and pyrophosphate anions.

Monosodium phosphate Chemical compound

Monosodium phosphate (MSP), also known as monobasic sodium phosphate and sodium dihydrogen phosphate, is an inorganic compound of sodium with a dihydrogen phosphate (H2PO4) anion. One of many sodium phosphates, it is a common industrial chemical. The salt exists in an anhydrous form, as well as mono- and dihydrates.

Sodium arsenate Chemical compound

Sodium arsenate is the inorganic compound with the formula Na3AsO4. Related salts are also called sodium arsenate, including Na2HAsO4 (disodium hydrogen arsenate) and NaH2AsO4 (sodium dihydrogen arsenate). The trisodium salt is a white or colourless solid that is highly toxic. It is usually handled as the dodecahydrate Na3AsO4.12H2O.

Sodium tetraphenylborate Chemical compound

Sodium tetraphenylborate is the organic compound with the formula NaB(C6H5)4. It is a salt, wherein the anion consists of four phenyl rings bonded to boron. This white crystalline solid is used to prepare other tetraphenylborate salts, which are often highly soluble in organic solvents. The compound is used in inorganic and organometallic chemistry as a precipitating agent for potassium, ammonium, rubidium, and cesium ions, and some organic nitrogen compounds.

Ammonium arsenate Chemical compound

Ammonium arsenate is the inorganic compound with the formula (NH4)3AsO4. It is prepared by treating a concentrated solution of arsenic acid with ammonia, resulting in precipitation of colorless crystals of the trihydrate. Upon heating, it releases ammonia.

Aluminium arsenate is an inorganic compound with the formula AlAsO4. It is most commonly found as an octahydrate. It is a colourless solid that is produced by the reaction between sodium arsenate and a soluble aluminium salt. Aluminium arsenate occurs naturally as the mineral mansfieldite. Anhydrous form is known as an extremely rare, fumarolic mineral alarsite A synthetic hydrate of aluminium arsenate is produced by hydrothermal method. with the formulation Al2O3·3As2O5·10H2O.

Disodium hydrogen arsenate Chemical compound

Disodium hydrogen arsenate is the inorganic compound with the formula Na2HAsO4.7H2O. The compound consists of a salt and seven molecules of water of crystallization although for simplicity the formula usually omits the water component. The other sodium arsenates are NaH2AsO4 and Na3AsO4, the latter being called sodium arsenate. Disodium hydrogen arsenate is highly toxic. The salt is the conjugate base of arsenic acid. It is a white, water-soluble solid.

Monopotassium arsenate Chemical compound

Monopotassium arsenate is the inorganic compound with the formula KH2AsO4. A white solid, this salt is used to prepared other arsenic-containing compounds, mainly pesticides. It is prepared by calcining arsenic oxide and potassium nitrate, followed by extraction with water.

References

  1. Schenk, P. W. (1963). Brauer, G. (ed.). Arsenic, Antimony, Bismuth" in Handbook of Preparative Inorganic Chemistry. Vol. 1 (2nd ed.). New York: Academic Press. p. 602.