Beryllium nitrate

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Beryllium nitrate
Names
Systematic IUPAC name
Beryllium nitrate
Other names
Beryllium dinitrate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.678 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 237-062-5
PubChem CID
UNII
UN number 2464
  • InChI=1S/Be.2NO3/c;2*2-1(3)4/q+2;2*-1 Yes check.svgY
    Key: RFVVBBUVWAIIBT-UHFFFAOYSA-N Yes check.svgY
  • [Be+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O
Properties
Be(NO3)2
Molar mass 133.021982 g/mol
Appearancewhite solid
Odor odorless
Density 1.56 g/cm3
Melting point 60.5 °C (140.9 °F; 333.6 K)
Boiling point 142 °C (288 °F; 415 K) (decomposes)
166 g/100 mL
Thermochemistry
-700.4 kJ/mol
Hazards
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 0.002 mg/m3
C 0.005 mg/m3 (30 minutes), with a maximum peak of 0.025 mg/m3 (as Be) [1]
REL (Recommended)
Ca C 0.0005 mg/m3 (as Be) [1]
IDLH (Immediate danger)
Ca [4 mg/m3 (as Be)] [1]
Related compounds
Other cations
Magnesium nitrate
Calcium nitrate
Strontium nitrate
Barium nitrate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Beryllium nitrate is an inorganic compound with the idealized chemical formula Be(NO3)2. The formula suggests a salt, but, as for many beryllium compounds, the compound is highly covalent. Little of its chemistry is well known. "When added to water, brown fumes are evolved; when hydrolyzed in sodium hydroxide solution, both nitrate and nitrite ions are produced." [2]

Structure of basic berylliium nitrate. Color scheme: red = O, blue = N, turquoise = Be. Be4O(NO3)6 ICD Code59272.png
Structure of basic berylliium nitrate. Color scheme: red = O, blue = N, turquoise = Be.

Synthesis and reactions

The straw-colored adduct Be(NO3)2(N2O4) forms upon treatment of beryllium chloride with dinitrogen tetroxide:

BeCl2 + 3 N2O4 → Be(NO3)2(N2O4) + 2 NOCl

Upon heating, this adduct loses N2O4 and produces colorless Be(NO3)2. Further heating of Be(NO3)2 induces conversion to basic beryllium nitrate, which adopts a structure akin to that for basic beryllium acetate. [4]

Unlike the basic acetate, with its six lipophilic methyl groups, the basic nitrate is insoluble in most solvents.

Related Research Articles

<span class="mw-page-title-main">Dinitrogen tetroxide</span> Chemical compound

Dinitrogen tetroxide, commonly referred to as nitrogen tetroxide (NTO), and occasionally (usually among ex-USSR/Russia rocket engineers) as amyl, is the chemical compound N2O4. It is a useful reagent in chemical synthesis. It forms an equilibrium mixture with nitrogen dioxide. Its molar mass is 92.011 g/mol.

<span class="mw-page-title-main">Silver nitrate</span> Chemical compound

Silver nitrate is an inorganic compound with chemical formula AgNO
3
. It is a versatile precursor to many other silver compounds, such as those used in photography. It is far less sensitive to light than the halides. It was once called lunar caustic because silver was called luna by ancient alchemists who associated silver with the moon. In solid silver nitrate, the silver ions are three-coordinated in a trigonal planar arrangement.

<span class="mw-page-title-main">Lead(II) nitrate</span> Chemical compound

Lead(II) nitrate is an inorganic compound with the chemical formula Pb(NO3)2. It commonly occurs as a colourless crystal or white powder and, unlike most other lead(II) salts, is soluble in water.

<span class="mw-page-title-main">Nitrogen dioxide</span> Chemical compound with formula NO₂

Nitrogen dioxide is a chemical compound with the formula NO2. One of several nitrogen oxides, nitrogen dioxide is a reddish-brown gas. It is a paramagnetic, bent molecule with C2v point group symmetry. Industrially, NO2 is an intermediate in the synthesis of nitric acid, millions of tons of which are produced each year, primarily for the production of fertilizers.

<span class="mw-page-title-main">Copper(II) nitrate</span> Chemical compound

Copper(II) nitrate describes any member of the family of inorganic compounds with the formula Cu(NO3)2(H2O)x. The hydrates are blue solids. Anhydrous copper nitrate forms blue-green crystals and sublimes in a vacuum at 150-200 °C. Common hydrates are the hemipentahydrate and trihydrate.

<span class="mw-page-title-main">Beryllium fluoride</span> Chemical compound

Beryllium fluoride is the inorganic compound with the formula Be F2. This white solid is the principal precursor for the manufacture of beryllium metal. Its structure resembles that of quartz, but BeF2 is highly soluble in water.

<span class="mw-page-title-main">Uranyl nitrate</span> Chemical compound

Uranyl nitrate is a water-soluble yellow uranium salt with the formula UO2(NO3)2 · n H2O. The hexa-, tri-, and dihydrates are known. The compound is mainly of interest because it is an intermediate in the preparation of nuclear fuels.

<span class="mw-page-title-main">Arsenic pentoxide</span> Chemical compound

Arsenic pentoxide is the inorganic compound with the formula As2O5. This glassy, white, deliquescent solid is relatively unstable, consistent with the rarity of the As(V) oxidation state. More common, and far more important commercially, is arsenic(III) oxide (As2O3). All inorganic arsenic compounds are highly toxic and thus find only limited commercial applications.

<span class="mw-page-title-main">Zirconium tetrafluoride</span> Chemical compound

Zirconium(IV) fluoride describes members of a family inorganic compounds with the formula (ZrF4(H2O)x. All are colorless, diamagnetic solids. Anhydrous Zirconium(IV) fluoride' is a component of ZBLAN fluoride glass.

<span class="mw-page-title-main">Zinc nitrate</span> Chemical compound

Zinc nitrate is an inorganic chemical compound with the formula Zn(NO3)2. This colorless, crystalline salt is highly deliquescent. It is typically encountered as a hexahydrate Zn(NO3)2·6H2O. It is soluble in both water and alcohol.

<span class="mw-page-title-main">Iron(III) nitrate</span> Chemical compound

Iron(III) nitrate, or ferric nitrate, is the name used for a series of inorganic compounds with the formula Fe(NO3)3.(H2O)n. Most common is the nonahydrate Fe(NO3)3.(H2O)9. The hydrates are all pale colored, water-soluble paramagnetic salts.

<span class="mw-page-title-main">Basic beryllium acetate</span> Chemical compound

Basic beryllium acetate is the chemical compound with the formula Be4O(O2CCH3)6. This compound adopts a distinctive structure, but it has no applications and has been only lightly studied. It is a colourless solid that is soluble in organic solvents.

<span class="mw-page-title-main">Beryllium hydride</span> Chemical compound

Beryllium hydride is an inorganic compound with the chemical formula n. This alkaline earth hydride is a colourless solid that is insoluble in solvents that do not decompose it. Unlike the ionically bonded hydrides of the heavier Group 2 elements, beryllium hydride is covalently bonded.

<span class="mw-page-title-main">Cadmium hydroxide</span> Chemical compound

Cadmium hydroxide is an inorganic compound with the formula Cd(OH)2. It is a white crystalline ionic compound that is a key component of nickel–cadmium battery.

<span class="mw-page-title-main">Bismuth(III) nitrate</span> Chemical compound

Bismuth(III) nitrate is a salt composed of bismuth in its cationic +3 oxidation state and nitrate anions. The most common solid form is the pentahydrate. It is used in the synthesis of other bismuth compounds. It is available commercially. It is the only nitrate salt formed by a group 15 element, indicative of bismuth's metallic nature.

<span class="mw-page-title-main">Titanium(IV) nitrate</span> Chemical compound

Titanium nitrate is the inorganic compound with formula Ti(NO3)4. It is a colorless, diamagnetic solid that sublimes readily. It is an unusual example of a volatile binary transition metal nitrate. Ill defined species called titanium nitrate are produced upon dissolution of titanium or its oxides in nitric acid.

<span class="mw-page-title-main">Vanadyl nitrate</span> Chemical compound

Vanadyl nitrate, also called vanadium oxytrinitrate or vanadium oxynitrate is an inorganic compound of vanadium in the +5 oxidation state with nitrate ligands and oxygen. The formula is VO(NO3)3. It is a pale yellow viscous liquid.

<span class="mw-page-title-main">Tin(IV) nitrate</span> Chemical compound

Tin(IV) nitrate is a salt of tin with nitric acid. It is a volatile white solid, subliming at 40 °C under a vacuum. Unlike other nitrates, it reacts with water to produce nitrogen dioxide.

Lutetium(III) nitrate is an inorganic compound, a salt of lutetium and nitric acid with the chemical formula Lu(NO3)3. The compound forms colorless crystals, dissolves in water, and also forms crystalline hydrates. The compound is poisonous.

<span class="mw-page-title-main">Transition metal nitrate complex</span> Compound of nitrate ligands

A transition metal nitrate complex is a coordination compound containing one or more nitrate ligands. Such complexes are common starting reagents for the preparation of other compounds.

References

  1. 1 2 3 NIOSH Pocket Guide to Chemical Hazards. "#0054". National Institute for Occupational Safety and Health (NIOSH).
  2. Addison, C.C.; Logan, N. (1964). Anhydrous Metal Nitrates. Advances in Inorganic Chemistry and Radiochemistry. Vol. 6. pp. 71–142. doi:10.1016/S0065-2792(08)60225-3. ISBN   9780120236060.
  3. Haley, M. J.; Wallwork, S. C.; Duffin, B.; Logan, N.; Addison, C. C. (1997). "Hexa-μ-nitrato-μ4-oxo-tetraberyllium". Acta Crystallographica Section C Crystal Structure Communications. 53 (7): 829–830. doi:10.1107/S010827019700303X.
  4. Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 122. ISBN   978-0-08-037941-8.