Scandium nitrate

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Scandium(III) nitrate
Scandium nitrate.png
Names
IUPAC name
scandium(3+) trinitrate
Identifiers
3D model (JSmol)
ECHA InfoCard 100.033.350 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 236-701-5
PubChem CID
UNII
  • InChI=1S/3NO3.Sc/c3*2-1(3)4;/q3*-1;+3
    Key: DFCYEXJMCFQPPA-UHFFFAOYSA-N
  • [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[Sc+3]
Properties
Sc(NO3)3
Molar mass 230.97 g/mol
Appearanceoff-white crystals
Solubility in other solventswater and strong mineral acids
Related compounds
Related compounds
Scandium(III) chloride
Scandium(III) fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Scandium(III) nitrate, Sc(NO3)3, is an ionic compound. It is an oxidizer, as all nitrates are. The salt is applied in optical coatings, catalysts, electronic ceramics and the laser industry.

Contents

Preparation

Scandium nitrate can be prepared by the reaction between scandium metal with dinitrogen tetroxide. [1]

Sc + 3 N2O4 → Sc(NO3)3 + 3 NO

The anhydrous form can also be obtained by the reaction between scandium chloride and dinitrogen pentoxide. [2] The tetrahydrate can be obtained from the reaction between scandium hydroxide and nitric acid. [3]

Properties

Scandium nitrate is a white solid which dissolves in water and ethanol. [4] It has multiple hydrated forms, including the dihydrate, trihydrate, and tetrahydrate. The tri- and tetrahydrate exist in the monoclinic crystal system. Upon heating in air to 50 °C, the tetrahydrate transforms into the dihydrate, which at 60 °C further converts to Sc4O3(NO3)3·6.5H2O. At 140–220 °C, Sc4O5(NO3)3 is formed. [2]

Scandium nitrate has been found to form clusters when in an aqueous solution which can affect its behavior and properties in various ways. Small Angle neutron scattering [5] has been used in experiments to show the clusters can contain as many as 10 scandium ions. This number depends on the concentration of the original scandium nitrate in the solution.

Applications

Scandium nitrate has been found to be a successful catalyst in chemical reactions such as Beckmann rearrangement of ketoximes to amides [6] and the isomerization of allylic alcohols to aldehydes. The catalytic success of scandium nitrate can be increased by modifying its structure in ways such as adding a co catalyst. Scandium nitrate is also the precursor for the synthesis of other scandium based compounds such as scandium oxide or scandium hydroxide. Scandium nitrate has also been investigated for its potential in luminescent materials due to its ability to strongly emit in the blue region of the spectrum.

Related Research Articles

<span class="mw-page-title-main">Dinitrogen pentoxide</span> Chemical compound

Dinitrogen pentoxide is the chemical compound with the formula N2O5. It is one of the binary nitrogen oxides, a family of compounds that only contain nitrogen and oxygen. It exists as colourless crystals that sublime slightly above room temperature, yielding a colorless gas.

In chemistry, water(s) of crystallization or water(s) of hydration are water molecules that are present inside crystals. Water is often incorporated in the formation of crystals from aqueous solutions. In some contexts, water of crystallization is the total mass of water in a substance at a given temperature and is mostly present in a definite (stoichiometric) ratio. Classically, "water of crystallization" refers to water that is found in the crystalline framework of a metal complex or a salt, which is not directly bonded to the metal cation.

<span class="mw-page-title-main">Manganese(II) chloride</span> Chemical compound

Manganese(II) chloride is the dichloride salt of manganese, MnCl2. This inorganic chemical exists in the anhydrous form, as well as the dihydrate (MnCl2·2H2O) and tetrahydrate (MnCl2·4H2O), with the tetrahydrate being the most common form. Like many Mn(II) species, these salts are pink, with the paleness of the color being characteristic of transition metal complexes with high spin d5 configurations.

<span class="mw-page-title-main">Copper(II) chloride</span> Chemical compound

Copper(II) chloride, also known as cupric chloride, is an inorganic compound with the chemical formula CuCl2. The monoclinic yellowish-brown anhydrous form slowly absorbs moisture to form the orthorhombic blue-green dihydrate CuCl2·2H2O, with two water molecules of hydration. It is industrially produced for use as a co-catalyst in the Wacker process.

<span class="mw-page-title-main">Silver chromate</span> Chemical compound

Silver chromate is an inorganic compound with formula Ag2CrO4 which appears as distinctively coloured brown-red crystals. The compound is insoluble and its precipitation is indicative of the reaction between soluble chromate and silver precursor salts (commonly potassium/sodium chromate with silver nitrate). This reaction is important for two uses in the laboratory: in analytical chemistry it constitutes the basis for the Mohr method of argentometry, whereas in neuroscience it is used in the Golgi method of staining neurons for microscopy.

<span class="mw-page-title-main">Vanadium(III) chloride</span> Chemical compound

Vanadium(III) chloride describes the inorganic compound with the formula VCl3 and its hydrates. It forms a purple anhydrous form and a green hexahydrate [VCl2(H2O)4]Cl·2H2O. These hygroscopic salts are common precursors to other vanadium(III) complexes and is used as a mild reducing agent.

<span class="mw-page-title-main">Cadmium nitrate</span> Chemical compound

Cadmium nitrate describes any of the related members of a family of inorganic compounds with the general formula , the most commonly encountered form being the tetrahydrate. The anhydrous form is volatile, but the others are colourless crystalline solids that are deliquescent, tending to absorb enough moisture from the air to form an aqueous solution. Like other cadmium compounds, cadmium nitrate is known to be carcinogenic.

<span class="mw-page-title-main">Iron(III) nitrate</span> Chemical compound

Iron(III) nitrate, or ferric nitrate, is the name used for a series of inorganic compounds with the formula Fe(NO3)3.(H2O)n. Most common is the nonahydrate Fe(NO3)3.(H2O)9. The hydrates are all pale colored, water-soluble paramagnetic salts.

The chemical element nitrogen is one of the most abundant elements in the universe and can form many compounds. It can take several oxidation states; but the most common oxidation states are -3 and +3. Nitrogen can form nitride and nitrate ions. It also forms a part of nitric acid and nitrate salts. Nitrogen compounds also have an important role in organic chemistry, as nitrogen is part of proteins, amino acids and adenosine triphosphate.

<span class="mw-page-title-main">Nickel(II) nitrate</span> Chemical compound

Nickel nitrate is the inorganic compound Ni(NO3)2 or any hydrate thereof. The anhydrous form is not commonly encountered, thus "nickel nitrate" usually refers to nickel(II) nitrate hexahydrate. The formula for this species is written in two ways: Ni(NO3)2.6H2O and, more descriptively [Ni(H2O)6](NO3)2. The latter formula indicates that the nickel(II) center is surrounded by six water molecules in this hydrated salt. In the hexahydrate, the nitrate anions are not bonded to nickel. Also known are three other hydrates: Ni(NO3)2.9H2O, Ni(NO3)2.4H2O, and Ni(NO3)2.2H2O. Anhydrous Ni(NO3)2 is also known.

<span class="mw-page-title-main">Cobalt(II) nitrate</span> Chemical compound

Cobalt nitrate is the inorganic compound with the formula Co(NO3)2.xH2O. It is cobalt(II)'s salt. The most common form is the hexahydrate Co(NO3)2·6H2O, which is a red-brown deliquescent salt that is soluble in water and other polar solvents.

<span class="mw-page-title-main">Cobalt(III) nitrate</span> Chemical compound

Cobalt(III) nitrate is an inorganic compound with the chemical formula Co(NO3)3. It is a green, diamagnetic solid that sublimes at ambient temperature.

Indium(III) nitrate is a nitrate salt of indium which forms various hydrates. Only the pentahydrate has been crystallographically verified. Other hydrates are also reported in literature, such as the trihydrate.

<span class="mw-page-title-main">Thulium(III) nitrate</span> Chemical compound

Thulium(III) nitrate is an inorganic compound, a salt of thulium and nitric acid with the chemical formula Tm(NO3)3. The compound forms dark-green crystals, readily soluble in water, also forms crystalline hydrates.

<span class="mw-page-title-main">Transition metal nitrate complex</span> Compound of nitrate ligands

A transition metal nitrate complex is a coordination compound containing one or more nitrate ligands. Such complexes are common starting reagents for the preparation of other compounds.

<span class="mw-page-title-main">Berkelium(III) nitrate</span> Chemical compound

Berkelium(III) nitrate is the berkelium salt of nitric acid with the formula Bk(NO3)3. It commonly forms the tetrahydrate, Bk(NO3)3·4H2O, which is a light green solid. If heated to 450 °C, it decomposes to berkelium(IV) oxide and 22 milligrams of the solution of this compound is reported to cost one million dollars.

<span class="mw-page-title-main">Europium compounds</span> Compounds with at least one europium atom

Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl3, Eu(NO3)3 and Eu(CH3COO)3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in aqueous solution. Many europium compounds fluoresce under ultraviolet light due to the excitation of electrons to higher energy levels. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod.

Cobalt compounds are chemical compounds formed by cobalt with other elements.

Lutetium compounds are compounds formed by the lanthanide metal lutetium (Lu). In these compounds, lutetium generally exhibits the +3 oxidation state, such as LuCl3, Lu2O3 and Lu2(SO4)3. Aqueous solutions of most lutetium salts are colorless and form white crystalline solids upon drying, with the common exception of the iodide. The soluble salts, such as nitrate, sulfate and acetate form hydrates upon crystallization. The oxide, hydroxide, fluoride, carbonate, phosphate and oxalate are insoluble in water.

Radium compounds are compounds containing the element radium (Ra). Due to radium's radioactivity, not many compounds have been well characterized. Solid radium compounds are white as radium ions provide no specific coloring, but they gradually turn yellow and then dark over time due to self-radiolysis from radium's alpha decay. Insoluble radium compounds coprecipitate with all barium, most strontium, and most lead compounds.

References

  1. Brauer, Georg (1975). Handbuch der präparativen anorganischen Chemie (3rd ed.). Stuttgart: Enke. p. 1109. ISBN   3-432-02328-6. OCLC   310719485.
  2. 1 2 Scandium : its occurrence, chemistry, physics, metallurgy, biology, and technology. Chaim T. Horovitz. Academic Press. 2012. p. 119. ISBN   978-0323144513. OCLC   768016723.{{cite book}}: CS1 maint: others (link)
  3. Riedel, Erwin (2011). Anorganische Chemie. Christoph Janiak (8th ed.). Berlin: De Gruyter. p. 773. ISBN   978-3-11-022567-9. OCLC   753966312.
  4. William M., Haynes (2012). CRC Handbook of Chemistry and Physics. William M. Haynes (93rd ed.). Boca Raton, FL: CRC. p. 86. ISBN   978-1-4398-8049-4. OCLC   793213751.
  5. Karavaev, I. A.; Savinkina, E. V.; Grigor’ev, M. S.; Buzanov, G. A.; Kozerozhets, I. V. (2022-08-01). "New Coordination Compounds of Scandium Nitrate with Carbamide: Precursors for the Preparation of Nanosized Scandium Oxide". Russian Journal of Inorganic Chemistry. 67 (8): 1178–1183. doi:10.1134/S0036023622080186. ISSN   1531-8613. S2CID   252204399.
  6. Sekine, Tatsuya; Hasegawa, Yuko (February 1966). "Studies of Scandium in Various Solutions. I. An Ion-Exchange Study of Scandium(III) Chloride and Nitrate Complexes". Bulletin of the Chemical Society of Japan. 39 (2): 240–243. doi: 10.1246/bcsj.39.240 . ISSN   0009-2673.