Oxalate nitrate

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An oxalate nitrate is a chemical compound or salt that contains oxalate and nitrate anions (NO3- and C2O42-). These are mixed anion compounds. Some have third anions. Oxalate acts as a ligand, which normally complexes two metal atoms.

Contents

Naming

An oxalate nitrate compound may also be called a nitrate oxalate. In chemical formulae, oxalate may be indicated by "ox". As a ligand oxalate is termed "oxalato", and nitrate, "nitrato".

Production

Most oxalate nitrates are formed by crystallisation from water solutions. One issue is the insolubility of metal oxalates.

Properties

On heating, oxalate nitrates lose NO2, NO, CO, and CO2 and form metal carbonates or oxides.

Related to these are the oxalate phosphates and oxalate perchlorates.

List

nameformularatio

C2O4:NO3

 mw system space group unit cell Åvolumedensitypropertiesreferences
phen = 1,10-phenanthroline[Cr(phen)2(C2O4)]NO3·H2C2O4·H2OmonoclinicCca=15.856 b=14.353 c=13.141 β=106.517° Z=428671.553orange [1]
bpy = 2,2′-bipyridine[Cr(bpy)2(C2O4)]NO3·1/2H2C2O4·4H2OmonoclinicP21/ca=10.5565 b=17.1770 c=14.8525 β=99.272° Z=42658.001.578orange [1]
fac-triammin-aquo-oxalato-cobalt(III)-nitrate monohydrate,fac-[Co(NH3)3(C2O4)(H2O)]NO3·H2OmonoclinicP21/na=7.853 b=10.000 c=13.192 β=105.06° [2]
[Co(NH3)4(C2O4)]NO3·H2OP212121a=7.944 b=9.90 c=12.700 Z=4999.151.968
Oxalato di(1,10-phenanthroline-N,N′) cobalt(III) nitrate 3.88 hydrate[Co(C12H8N2)2(C2O4)]NO3·3.88H2O639.14orthorhombicIbcaa = 15.492 b = 17.938 c = 19.635 Z = 854571.556pink [3]
ept = N-(2-aminoethyl)-1,3-diaminopropane[(Ni(ept)H2O)2ox](NO3)2 [4]
Ni2en4(C2O4)(NO3)2 [5]
bpy = 2,2′-bipyridine[{Ni(bpy)2}2(μ-C2O4)](NO3)2·H2C2O41044.23triclinicP1a 9.2921 b 12.8702 c 18.9812 α 84.660° β 75.969° γ 85.056° Z=22187.91.585violet [6]
m-xpt = bis(pyridyltriazole) ligand[Ni2(m-xpt)2(C2O4)](NO3)2 [7]
dien = diethylenetriamine(H3dien)[Ni(NO3)(C2O4)2].2H2OmonoclinicP21/ca=10.218 b=11.074 c=14.897 β=103.988°blue [8]
bpt = pyridyltriazole ligandCu2(bpt)2(NO3)2(DMF)2(C2O4) [7]
[(Cu(ept))2ox](NO3)2·H2O [4]
Diethylenetriammonium nitrato-bis(oxalato)cuprate (II) dihydrate(H3dien)[Cu(NO3)(C2O4)2].2H2OmonoclinicP21/ca = 10.1054 b = 11.0825 c = 14.8238 β = 103.516° Z = 41614.2 [9]
dien=diethylenetriamine[Cu2(C2O4)(dien)2](NO3)3monoclinicP2/ca = 23.7888(10), b = 6.7055(3), c = 12.7842(6) and β = 95.534 [10]
Sparteine copper(II) nitrate oxalateCu2(C15H26N2)2(NO3)2(C2O4)1:2light green [11]
di-2-pyridylamineCu2(dpyam)2(μ-C2O4)(NO3)2(DMF)2triclinicP1a=8.353 b=9.100 c=12.245 α=72.035° β=75.228° γ=78.552° [12]
(μ2-oxalato)-bis(di-2-pyridylamine)-bis(N,N',-dimethylformamide)-di-copper(ii) iodide nitrate[Cu2(dpyam)2(μ-C2O4)(DMF)2](I)1.6(NO3)0.4triclinicP1a=8.4616 b=8.9112 c=12.3824 α=71.913° β=76.329° γ=80.225° [13]
Cu2(dpyam)2(C2O4)(NO3)2((CH3)2SO)2] [14]
Cu2(bpy)2(C2O4)(NO3)2(H2O)2 [14]
meprizole=(4-methoxy-2-(5-methoxy-3-methylo-pyrazol-1-yl)-6-methylpyrmadine)[Cu2(mepirizole)2(C2O4)(NO3)2(H2O)]2[Cu2(mepirizole)2(C2O4)(NO3)2]monoclinicP21/ca=20.073 b=13.842 c=11.451 β=119.09° Z=4 [15]
Cu2(histamine)2(C2O4)(H2O)2(NO3)2triclinicP1a=7.579 b=8.133 c=9.161 α=77.06° β=89.23° γ=82.54° Z=1545.6 [16]
[Cu2(bpy)2(C2O4)(H2O)2][Cu(bpy)(C2O4)](NO3)2 [17]
trimeen = N,N,N'-trimethylethylenediamine[(Cu(trimeen)H2O)2ox](NO3)2 ·2H2O [18]
Pz2CPh2 = diphenyldipyrazolylmethaneCu2(Pz2CPh2)2(NO3)2(μ-C2O4)triclinicP1a = 8.863 b = 10.241 c = 11.43 α = 98.98° β = 110.45° γ = 103.66° Z=2 [19]
Pz3m2CPh2 = diphenylbis(3-methylpyrazolyl)methane[Cu2(Pz3m2CPh2)2(H2O)2(μ-C2O4)](NO3)2·H2OmonoclinicC2/ca = 23.459 b = 8.8568 c = 21.782 β = 100.889° Z=4 [19]
phen = 1,10-phenanthroline; (μ2-Oxalato-O,O',O'',O''')-diaqua-bis(1,10-phenanthroline)-di-copper(ii) dinitrate[Cu2(ox)(phen)2(H2O)2](NO3)2monoclinicP21/na=7.128 b=11.715 c=16.529 β=91.80° [20]
4,4’-bipyridine; 1,10-phenanthroline;[Cu2(ox)(4,4’-bpy)(phen)2](NO3)2855.72monoclinicC2/ca=23.144 b=10.6601 c=13.4363 β=93.123° Z=43310.4green [21]
Bipy = 2,2′-bipyridine;Cu2(Bipy)2(H2O)2(C2O4)(NO3)2 [22]
μ-oxalato-κ4O1,O2:O1′,O2′-bis(aqua(nitrato-κO){[1-(2-pyridyl-κN)ethylidene]hydrazine-κN}copper(II)) μ-oxalato-κ4O1,O2:O1′,O2′-bis((methanol-κO)(nitrato-κO){[1-(2-pyridyl-κN)ethylidene]hydrazine-κN}copper(II))[Cu2(C2O4)(NO3)2(C7H9N3)2(H2O)2][Cu2(C2O4)(NO3)2(C7H9N3)2(CH4O)2]triclinicP1a = 9.8358 b = 12.377 c = 12.714 α = 103.704° β = 112.573° γ = 107.821° Z = 11245.15 [23]
(μ2-oxalato)-bis(dimethylsulfoxido)-bis(di-2-pyridylamine)-dinitrato-di-copper(ii)[Cu2(dpyam)2(C2O4)(NO3)2((CH3)2SO)2triclinicP1a 8.7190 b 8.9680 c 11.421 α 68.58° β 77.79° γ 80.58° [24]
(μ2-Oxalato-O,O',O'',O''')-diaqua-bis(2,3-bis(2-pyridyl)pyrazine)-di-copper(ii) dinitrate tetrahydrate[Cu2(dpp)2(H2O)2(NO3)2(ox)]·4H2OmonoclinicP21/ca=9.704b=7.2598 c=25.865 β=97.395° [25]
L=4,4′-methylenebis(1-(2-pyridyl)-3,5-dimethylpyrazole;

(μ2-4,4'-Methylenebis(1-(2-pyridyl)-3,5-dimethylpyrazole))-bis(nitrato-O)-di-copper acetonitrile solvate

CuL(C2O4)(NO3)monoclinicP2/na=8.5679 b=9.3862 c=20.5910 β=101.038° [26]
bis(μ2-oxalato)-tetrakis(2,2'-bipyridine)-(oxalato)-di-copper(ii)-chromium(iii) nitrate monohydrate[{Cu(μ-C2O4)(bpy)2}2Cr(C2O4)]NO3·H2OmonoclinicC2/ca=6.428 b=17.162 c=16.749 β=110.721° [27]
bis(tris(2,2'-bipyridine)-copper(ii)) tris(oxalato)-chromium(iii) nitrate nonahydrate[Cu(bpy)3]2[Cr(C2O4)3]NO3·9H2OmonoclinicP21/ca=31.314 b=13.536 c=22.202 β=132.01° [27]
(μ2-Oxalato)-tetrakis(μ2-N,N'-propane-1,3-bis(3-methoxysalicylideneiminato))-diaqua-bis(nitrato-O)-tetra-copper(ii)-di-neodymium(iii) dinitrate hexahydrate[{(LCuII(ONO2))(LCuII(H2O))NdIII}2(μ-C2O4)](NO3)2 · 6H2OmonoclinicP21a=16.982 b=15.241 c=17.368 β=96.71° [28]
(H3O,N2H5)5{[Ce(H2O)][Ce(NO3)]2(C2O4)6}.6H2OtetragonalP43212a=11.6521 c=27.9597 [29]
(H3O,N2H5)2{Nd(C2O4)2NO3}monoclinicP21/ca=9.296 b=17.214 c=9.214 β=116.586 [29]
(H3O,N2H5)2(NO3)2{Eu2(H2O)6(C2O4)3}monoclinicP21/na=8.0806 b=18.986 c=17.318 β=99.331° [29]
melaminium[C3H7N6]6[Dy(C2O4)4][NO3]triclinicP1a=9.777 b=10.676 c=25.083 α=97.18° β=79.81° γ=86.52°2570 [30]
melaminium[C3H7N6]6[Ho(C2O4)4][NO3]triclinicP1a=9.760 b=10.660 c=25.051 α=87.24° β=87.24° γ=79.96°2559 [30]
(N2H5){Er(C2O4)2}.2H2OtetragonalP43212a=11.3348 c=9.2646
melaminium[C3H7N6]6[Yb(C2O4)4][NO3]triclinicP1a=9.7297 b=10.5937 c=24.9904 α=87.271° β=80.123° γ=86.955°2532.15 [30]
lead nitrate oxalatePb2(NO3)2(C2O4)⋅2H2OmonoclinicP21/ca=10.623 b=7.9559 c=6.1932 β=104.49° Z=4 [31] [32]
(OPb2)2(C2O4)(NO3)2monoclinicP21/ca=11.8682 b=5.2501 c=9.0989 β=96.741° [33]
μ-Oxalato-κ4O1,O2:O1′,O2′-bis[aqua(2,2′-bipyridine-κN)(nitrato-κ2O,O′)lead(II)]Pb2(C2O4)(NO3)2(C10H8N2)2(H2O)2monoclinicP21/ca=9.579 b=20.633 c=6.765 β=91.687° Z=21336.5 [34]
bipy = 2,2′-bipyridine; (μ2-oxalato)-bis(2,2'-bipyridine)-dinitrato-diaqua-di-leadPb2(ox)(bipy)2(NO3)2(H2O)2monoclinicP21/ca=9.5444 b=20.5956 c=6.7449 β=91.819° [35]
phen = 1,10-phenanthroline{Pb(phen)2}2Cr(ox)2(phen)][Cr(ox)2(phen)](NO3)2triclinicP1a 13.311 b 18.861 c 19.500 α 115.14° β 107.54° γ 96.28° [36]
AgPb(C2O4)(NO3)heat decompose to Ag and PbCO3 [37]
tetraethyldiglycolamide[Th(TEDGA)2(C2O4)][NO3]2[H2C2O4].6H2O1128.86tetragonalP42212a=18.714 c=12.9212 Z=44525.21.657@100K Th is 10 coordinate [38]
tetraethyldiglycolamide[Th2(C2O4)3(TEDGA)4][NO3][HC2O4][H2C2O4]4.7H2O2340.47triclinicP1a=15.6611 b=17.9082 c=18.1814 α=89.896° β=65.549° γ=87.623° Z=24637.21.676@100K is 10 coordinate, bicapped square antiprism [38]
diammonium oxalatotetranitratouranylate(NH4)2[{UO2(NO3)2}2(μ4-C2O4)] · 2H2O1:4monoclinicP21/ca = 8.650 b = 11.700 c = 20.213 β = 93.92° Z = 42040.9 [39]
Aqua-(2,2'-bipyridine)-bis(nitrato)-(μ2-oxalato)-dioxo-uranium(vi)-copper(ii)UO2Cu(C2O4)(NO3)2(bipy)(H2O)triclinicP1a 7.7582 b 11.0274 c 12.181 α 66.717° β 85.541° γ 87.653° [40]
(μ2-2,2'-bipyrimidine)-bis(μ2-oxalato)-bis(μ2-hydroxo)-tetraoxo-bis(nitrato)-di-copper-di-uranium[(UO2)2Cu2(C2O4)2(bipym)3(OH)2]·2NO3triclinicP1a 9.9169 b 10.9294 c 11.1783 α 103.449° β 110.754° γ 110.069° [40]
[C6H14N]4[UO2(C2O4)2(HC2O4)]NO3·2H2O1033.86monoclinicP21/ca=11.9358 b=18.7279 c=19.1956 β=102.210° Z=44193.81.637 [41]
[C8H18N][UO2(C2O4)(NO3)]monoclinicP21/ca=11.3688 b=11.0238 c=13.4478 β=11.465° Z=41557.52.338 [41]

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<span class="mw-page-title-main">Copper(II) nitrate</span> Chemical compound

Copper(II) nitrate describes any member of the family of inorganic compounds with the formula Cu(NO3)2(H2O)x. The hydrates are blue solids. Anhydrous copper nitrate forms blue-green crystals and sublimes in a vacuum at 150-200 °C. Common hydrates are the hemipentahydrate and trihydrate.

<span class="mw-page-title-main">Potassium ferrioxalate</span> Chemical compound

Potassium ferrioxalate, also called potassium trisoxalatoferrate or potassium tris(oxalato)ferrate(III) is a chemical compound with the formula K3[Fe(C2O4)3]. It often occurs as the trihydrate K3[Fe(C2O4)3]·3H2O. Both are crystalline compounds, lime green in colour.

<span class="mw-page-title-main">Nickel(II) bis(acetylacetonate)</span> Coordination complex

Nickel(II) bis(acetylacetonate) is a coordination complex with the formula [Ni(acac)2]3, where acac is the anion C5H7O2− derived from deprotonation of acetylacetone. It is a dark green paramagnetic solid that is soluble in organic solvents such as toluene. It reacts with water to give the blue-green diaquo complex Ni(acac)2(H2O)2.

<span class="mw-page-title-main">Cobalt(II) oxalate</span> Chemical compound

Cobalt(II) oxalate is the inorganic compound with the formula of CoC2O4. Like other simple inorganic oxalates, it is a coordination polymer. The oxalate ligands bridge of Co(OH2)2 centres. Each cobalt adopts octahedral coordination geometry.

<span class="mw-page-title-main">Titanium(IV) nitrate</span> Chemical compound

Titanium nitrate is the inorganic compound with formula Ti(NO3)4. It is a colorless, diamagnetic solid that sublimes readily. It is an unusual example of a volatile binary transition metal nitrate. Ill defined species called titanium nitrate are produced upon dissolution of titanium or its oxides in nitric acid.

The oxalatonickelates are a class of compounds that contain nickel complexed by oxalate groups. They form a series of double salts, and include clusters with multiple nickel atoms. Since oxalate functions as a bidentate ligand it can satisfy two coordinate positions around the nickel atom, or it can bridge two nickel atoms together.

<span class="mw-page-title-main">Caesium oxalate</span> Chemical compound

Caesium oxalate, or dicesium oxalate, or cesium oxalate is a chemical compound with the chemical formula Cs2C2O4. It is a cesium salt of oxalic acid. It consists of cesium cations Cs+ and oxalate anions C2O2−4.

Nitrate chlorides are mixed anion compounds that contain both nitrate (NO3−) and chloride (Cl−) ions. Various compounds are known, including amino acid salts, and also complexes from iron group, rare-earth, and actinide metals. Complexes are not usually identified as nitrate chlorides, and would be termed chlorido nitrato complexes.

The nitrate selenites are mixed anion compounds containing distinct nitrate (NO3−)and selenite (SO32−) groups. The compounds are colourless unless coloured by cations.

<span class="mw-page-title-main">Transition metal oxalate complex</span>

Transition metal oxalate complexes are coordination complexes with oxalate (C2O42−) ligands. Some are useful commercially, but the topic has attracted regular scholarly scrutiny. Oxalate (C2O42-) is a kind of dicarboxylate ligand. As a small, symmetrical dinegative ion, oxalate commonly forms five-membered MO2C2 chelate rings. Mixed ligand complexes are known, e.g., [Co(C2O4)(NH3)4]κ+.

The carbonate oxalates are mixed anion compounds that contain both carbonate (CO3) and oxalate (C2O4) anions. Most compounds incorporate large trivalent metal ions, such as the rare earth elements. Some carbonate oxalate compounds of variable composition are formed by heating oxalates.

<span class="mw-page-title-main">Oxalate phosphate</span> Chemical compound containing oxalate and phosphate anions

The oxalate phosphates are chemical compounds containing oxalate and phosphate anions. They are also called oxalatophosphates or phosphate oxalates. Some oxalate-phosphate minerals found in bat guano deposits are known. Oxalate phosphates can form metal organic framework compounds.

A nitrate nitrite, or nitrite nitrate, is a coordination complex or other chemical compound that contains both nitrite and nitrate anions (NO3− and NO2−). They are mixed-anion compounds, and they are mixed-valence compounds. Some have third anions. Many nitrite nitrate compounds are coordination complexes of cobalt. Such a substance was discovered by Wolcott Gibbs and Frederick Genth in 1857.

The oxalate phosphites are chemical compounds containing oxalate and phosphite anions. They are also called oxalatophosphites or phosphite oxalates. Oxalate phosphates can form metal organic framework compounds.

<span class="mw-page-title-main">Transition metal nitrate complex</span> Compound of nitrate ligands

A transition metal nitrate complex is a coordination compound containing one or more nitrate ligands. Such complexes are common starting reagents for the preparation of other compounds.

<span class="mw-page-title-main">Niobium oxalate</span> Chemical compound

Niobium(V) oxalate is the hydrogen oxalate salt of niobium(V). The neutral salt has not been prepared.

Oxalate sulfates are mixed anion compounds containing oxalate and sulfate. They are mostly transparent, and any colour comes from the cations.

<span class="mw-page-title-main">Europium compounds</span> Chemical compounds

Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl3, Eu(NO3)3 and Eu(CH3COO)3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in aqueous solution. Many europium compounds fluoresce under ultraviolet light due to the excitation of electrons to higher energy levels. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod.

An oxalate chloride or oxalato chloride is a mixed anion compound contains both oxalate and chloride anions.

Carbonate nitrates are mixed anion compounds containing both carbonate and nitrate ions.

References

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  16. ↑ Min, Kil Sik; Suh, Myunghyun Paik (June 2000). "Self-Assembly, Structures, and Magnetic Properties of Ladder-Like Copper(II) Coordination Polymers". Journal of Solid State Chemistry. 152 (1): 183–190. Bibcode:2000JSSCh.152..183M. doi:10.1006/jssc.2000.8682.
  17. ↑ Juan Shi; Guang-Ming Yang; Peng Cheng; Dai-Zheng Liao; Zong-Hui Jiang; Geng-Lin Wang (January 1997). "Synthesis, structure and magnetic properties of oxalate-bridged complex [Cu2(bpy)2(C2O4)(H2O2)][Cu(bpy)(C2O4)](NO3)2". Polyhedron. 16 (3): 531–534. doi:10.1016/0277-5387(96)00244-6.
  18. ↑ Smékal, ZdenĚk; Langer, Vratislav; Wrzeszcz, Grzegorz; Klasová, Petra (2002-01-01). "Synthesis and Characterization of Binuclear (μ-Oxalato) Copper(II) Complexes with N,N′ -Diethylethylenediamine or N,N,N′ -Trimethylethylenediamine". Journal of Coordination Chemistry. 55 (5): 595–608. doi:10.1080/00958970290020900. ISSN   0095-8972. S2CID   98024533.
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  21. ↑ Kim, Jung-Sook; Lee, Uk; Koo, Bon-Kweon (2010-02-20). "1D Chain Crystal Structure of Copper(II) Oxalate Containing a 4,4'-Bipyridine and 1,10-Phenanthroline Ligands: [Cu 2 (ox)(4,4'-bpy)(phen) 2 ](NO 3 ) 2". Bulletin of the Korean Chemical Society. 31 (2): 487–490. doi:10.5012/bkcs.2010.31.02.487. ISSN   0253-2964.
  22. ↑ Boutobba, Zina; Direm, Amani; Sayin, Koray; El Bali, Brahim; Lachkar, Mohammed; Benali-Cherif, Nourredine (March 2020). "Crystal structure, Hirshfeld surface analysis and theoretical calculations of an oxalato-bridged copper(II) complex: μ-oxalato-bis[(2,2'-bipyridine) hydrate copper(II) nitrate]". Journal of the Iranian Chemical Society. 17 (3): 671–685. doi:10.1007/s13738-019-01805-0. ISSN   1735-207X. S2CID   207912853.
  23. ↑ Diallo, Madina; Tamboura, Farba Bouyagui; Gaye, Mohamed; Barry, Aliou Hamady; Bah, Youssouph (2008-09-01). "The cocrystal μ-oxalato-κ 4 O 1 , O 2 : O 1′ , O 2′ -bis(aqua(nitrato-κ O ){[1-(2-pyridyl-κ N )ethylidene]hydrazine-κ N }copper(II)) μ-oxalato-κ 4 O 1 , O 2 : O 1′ , O 2′ -bis((methanol-κ O )(nitrato-κ O ){[1-(2-pyridyl-κ N )ethylidene]hydrazine-κ N }copper(II)) (1/1)". Acta Crystallographica Section E. 64 (9): m1124–m1125. doi:10.1107/S1600536808024550. ISSN   1600-5368. PMC   2960478 . PMID   21201585.
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  27. 1 2 Jurić, Marijana; Planinić, Pavica; Brničević, Nevenka; Milić, Dalibor; Matković-Čalogović, Dubravka; Pajić, Damir; Zadro, Krešo (July 2006). "New Heterometallic (Cu II and Cr III ) Complexes – First Crystal Structure of an Oxalate-Bridged Ferromagnetically Coupled [Cu II Cr III Cu II ] System". European Journal of Inorganic Chemistry. 2006 (13): 2701–2710. doi:10.1002/ejic.200501092. ISSN   1434-1948.
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