Carbonate oxalate

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The carbonate oxalates are mixed anion compounds that contain both carbonate (CO3) and oxalate (C2O4) anions. Most compounds incorporate large trivalent metal ions, such as the rare earth elements. Some carbonate oxalate compounds of variable composition are formed by heating oxalates. [1]

Contents

Formation

One method to form carbonate oxalates is to heat a metal salt with ascorbic acid, which decomposes to oxalate and carbonate and combines with the metal. [2]

Reactions

When heated, oxalate carbonates decompose to carbon monoxide and carbonates, which form oxides at higher temperatures. [2]

List

formulanameformula weightcrystal formspace groupunit cell Åvolume Å3densitypropertiesreferences
Sc [3]
K4Ti2O2(C2O4)3·CO3 [4]
[Co*(C2O4)(CO3)]2−anionic complex [5]
[CoIII(CO3)(C2O4)(NH3)2]-anionic complex [6]
Sr[TiO(C2O4)CO3] [7]
[Y(H2O)]2(C2O4)(CO3)2yttrium oxalate carbonate421.876orthorhombicC2221a = 7.8177, b = 14.943, c = 9.4845, Z = 41108.02.526 [8]
Ba[ZrO(C2O4)(CO3)] [9]
[Ce(H2O)]2[(C2O4)2(CO3)]·2.5H2OtriclinicP1_a 6.329 b 8.743 c 13.000, α 105.61° β 90.55° γ 105.10° [10]
Pr4(C2O4)4(CO3)2]·3H2Ocatena(bis(μ4-Oxalato)-(μ3-oxalato)-(μ2-oxalato)-bis(μ6-carbonato)-bis(μ2-aqua)-diaqua-tetra-praseodymium hydrate)triclinicP1_a 6.298 b 8.673 c 12.970, α 105.42° β 90.55° γ 105.01° [11]
Pr2(C2O4)(CO3)2 [12]
Nd4(C2O4)4(CO3)2]·3H2Ocatena-[bis(μ4-Oxalato)-(μ3-oxalato)-(μ2-oxalato)-bis(μ6-carbonato)-bis(μ2-aqua)-diaqua-tetra-neodymium hydrate]triclinicP1_a 6.273(6)Å b 8.616(7)Å c 12.928(9)Å, α 105.50(6)° β 90.52(7)° γ 105.00(6)° [11]
(NH4)2[Nd2(CO3)(C2O4)3(H2O)]·H2Odiammonium aqua—carbonato-tri—oxalato-dineodymium(III) hydratetriclinicP1_a=8.706 b=9.530 c=10.327 α = 73.35° β = 86.90° γ = 80.50° Z=2809.692.808 [13]
Eu4(C2O4)4(CO3)2·3H2Ocatena(bis(μ4-Oxalato)-(μ3-oxalato)-(μ2-oxalato)-bis(μ6-carbonato)-bis(μ2-aqua)-diaqua-tetra-europium hydrate)triclinicP1_a 6.179 b 8.464 c 12.856, α 105.13° β 90.46° γ 104.86° [11]
[Eu(H2O)]2(C2O4)(CO3)2 [14]
[Gd(H2O)]2(C2O4)(CO3)2 [14]
[Tb(H2O)]2(C2O4)(CO3)2 [14]
[Dy(H2O)]2(C2O4)(CO3)2 [14]
[Ho(H2O)]2(C2O4)(CO3)2 [14]
Er2(CO3)2(C2O4)(H2O)2monoclinicCma = 7.773, b = 14.920, c = 4.7309, β = 90.12° Z = 2 [15]
Pb[ZrО(C2O4)CO3]
Pb4(CO3)2(C2O4)(OH)2535.41monoclinicP21/ca=11.8593 b=5.2486 c=9.0997 β =96.669 Z=4562.586.321colourless [16]
(NH4)4[Th(CO3)2(C2O4)2]•0.5Н2O [17]
(NH4)4[Th(CO3)2(C2O4)2]•10Н2O [17]
(CN3H6)3(NH4)[Th(CO3)2(C2O4)2]•3Н2O [17]
(CN3H6)3(NH4)[Th(CO3)3(C2O4)]•1.5Н2O [17]
(CN3H6)3(NH4)[Th(CO3)3(C2O4)]•3Н2O [17]
(CN3H6)6[Th2(CO3)5(C2O4)]hexaguandinium pentacarbonatooxalato dithorium [18]
(CN3H6)6[Th2(CO3)5(C2O4)2]•4Н2O [17]
(CN3H6)6[Th2(CO3)5(C2O4)2]•8Н2O [17]
(CN3H6)6[Th2(CO3)4(C2O4)3]•14Н2O [17]
(CN3H6)8[Th2(CO3)7(C2O4)] [17]
(CN3H6)8[Th2(CO3)7(C2O4)]•5Н2O [17]
(CN3H6)8[Th2(CO3)7(C2O4)]•6Н2O [17]
(CN3H6)8[Th2(CO3)5(C2O4)3]•Н2O [17]
(CN3H6)10[Th2(CO3)8(C2O4)]•8Н2O [17]
Na4[Th2(OH)2(CO3)4(C2O4)]•4Н2O [17]
Na4[Th2(OH)6(CO3)2(C2O4)]•2Н2O [17]
Na8Th(C2O4)2(CO3)4 •11Н2O [19]
Na8[Th(CO3)5(C2O4)]•11Н2O [17]
Na10[Th(CO3)5(C2O4)2]•11Н2O [17]
Na10[Th(CO3)5(C2O4)2]•16Н2O [17]
Na10[Th(OH)2(CO3)3(C2O4)3]•8Н2O [17]
Na10[Th(OH)2(CO3)3(C2O4)3] [17]
Na12[Th(CO3)6(C2O4)2]•11Н2O [17]
K2[Th2(OH)2(CO3)3(C2O4)]•2Н2O [17]
K2[Th2(OH)2(CO3)3(C2O4)] [17]
K4[Th(CO3)3(C2O4)]•6Н2O [17]
K5[Th2(OH)(CO3)4(C2O4)2]•2Н2O [17]
K6[Th(CO3)4(C2O4)]•8Н2O [17]
K6[Th(CO3)3(C2O4)2]•4Н2O [17]
K6[Th2(CO3)5(C2O4)2]•2Н2O [17]
K6[Th2(CO3)4(C2O4)3]•6Н2O [17]
K8[Th2(CO3)5(C2O4)3]•13Н2O [17]
K8[Th2(CO3)5(C2O4)3]•16Н2O [17]
K10[Th2(CO3)7(C2O4)2]•8Н2O [17]
K10[Th2(CO3)7(C2O4)2]•12Н2O [17]
K10[Th2(CO3)7(C2O4)2]•14Н2O [17]
K10[Th2(CO3)5(C2O4)4]•5Н2O [17]
K10[Th2(CO3)5(C2O4)4]•7Н2O [17]
(NH4)(CN3H6)3[(UO2)2(CO3)(C2O4)2(C3H4N2O2)] · H2O [20]
(CN3H6)4[(UO2)2(CO3)(C2O4)2(C5H8N2O2)] · 1.5H2Oguanidonium μ-carbonate μ-ethylmethylgyoximatedioxylatediuranylate sesquihydratemonoclinicP21a=6.909 b=15.794 c=30.064 β=96.720° Z=432582.383red plates [20] [21]
(CN3H6)4[(UO2)2(CO3)(C2O4)2(C6H8N2O2)] · 3H2O [20]
(NH4)(CN3H6)4[(UO2)2(CO3)(C2O4)2(C6H4N2O2)] · H2O [20]
(CN3H6)4[(UO2)2(C6H8N2O2)(CO3)(C2O4)2] · (C6H10N2O2) · 2H2Oguanidinium (3-methyl-1,2-cyclopenadionedioxime)dioxalato (μ-3-methyl-1,2-cyclopenadionedioxato) μ-carbonatodiuranylate dihydratetriclinicP1_a=9.2474 b=14.8562 c=16.8917 α = 68.504° β = 77.721° γ = 89.792° Z=22102.72.108red [22]
(CN3H6)4[(UO2)2(CO3)(C2O4)2(C7H10N2O2)] · H2O [20]
NH4(CN3H6)3[(UO2)2(C7H10N2O2)(CO3)(C2O4)2] · 2H2Oammonium guanidinium dioxalato (μ-3-methyl-1,2-cyclopenadionedioxato) μ-carbonatodiuranylate dihydrateorthorhombicP212121a=9.904 b=17.400 c=18.757 Z=43232.22.393red [22]
(CN3H6)4[(UO2)2(CO3)(C2O4)2(C6H10N2O2)] · H2Oguanidinium dioxalato μ-diethylglyoximato μ-carbonatodiuranylate monohydrate1176.59monoclinicP21/na=7.6140 b=15.4388 c=28.010 β=95.99° Z=43274.62.387orange [23]
(CN3H6)2(C2H2N2)[(UO2)2(CO3)(C2O4)2(C6H10N2O2)] · 3H2Oguanidinium ethylenediammonium dioxalato μ-diethylglyoximato μ-carbonatodiuranylate monohydrateorange [23]
[C(NH2)3]10[(UO2)6(μ3-O)2(μ2-OH)2(C2O4)4(CO3)4]· 2H2O2913.21triclinicP1_a=11.5919 b=11.7868 c=13.3545 α = 102.637° β = 93.278° γ = 95.273° Z=11759.72.749yellow [24]
PuPlutonium(III) oxalate carbonate [25]

References

  1. ↑ Cindrić, Marina; Strukan, Neven; Vrdoljak, Višnja; Devčić, Maja; Kamenar, Boris (2002-01-01). "Synthesis of Molybdovanadates Coordinated by Oxalato Ligands. The Crystal Structure of K 6 [Mo 6 V 2 O 24 (C 2 O 4 ) 2 ]·6H 2 O" . Journal of Coordination Chemistry. 55 (6): 705–710. doi:10.1080/00958970290027570. ISSN   0095-8972. S2CID   93516054.
  2. 1 2 Ma, Lin; Zhou, Xiaoliang; Yan, Zhengguang; Han, Xiaodong (May 2015). "Hydrothermal synthesis of [Y(H2O) ]2(C2O4)(CO3)2 powder using ascorbic acid". Advanced Powder Technology. 26 (3): 853–856. doi:10.1016/j.apt.2015.02.015.
  3. ↑ Fedorov, I. A.; Balakaeva, T. A. (1965-05-01). "SCANDIUM OXALATE-CARBONATE COMPOUNDS". Zh. Neorgan. Khim. (in Russian). 10. OSTI   4589394.
  4. ↑ Muraleedharan, K.; Labeeb, P.; Mujeeb, V. M. Abdul; Aneesh, M. H.; Devi, T. Ganga; Kannan, M. P. (2011-02-01). "Effect of Particle Size on Non-Isothermal Decomposition of Potassium Titanium Oxalate" . Zeitschrift für Physikalische Chemie. 225 (2): 169–181. doi:10.1524/zpch.2011.0051. ISSN   2196-7156. S2CID   101959591.
  5. ↑ Matsuura, Tatsuo; Hashimoto, Tetsuo (December 1966). "Szilard-Chalmers Reaction of Anionic Cobalt Complex Ions on Ion-Exchange Resins". Bulletin of the Chemical Society of Japan. 39 (12): 2647–2652. doi: 10.1246/bcsj.39.2647 . ISSN   0009-2673.
  6. ↑ Enomoto, Yoshihiro; Ito, Teiichi; Shibata, Muraji (1974-05-05). "The Preparation Ofcis,Cis-Dicyanocarbonatodiamminecobalte(III) Andcis,Cis-Oxalatodiaquodiamminecobalt(III) Complexes". Chemistry Letters. 3 (5): 423–426. doi: 10.1246/cl.1974.423 . ISSN   0366-7022.
  7. ↑ Gopalakrishnamurthy, H.S.; Subba Rao, M.; Narayanan Kutty, T.R. (October 1975). "Thermal decomposition of titanyl oxalates IV. Strontium and calcium titanyl oxalates" . Thermochimica Acta. 13 (2): 183–191. doi:10.1016/0040-6031(75)80080-3.
  8. ↑ Bataille, Thierry; Louër, Daniel (2000-12-01). "Powder and single-crystal X-ray diffraction study of the structure of [Y(H 2 O)] 2 (C 2 O 4 )(CO 3 ) 2". Acta Crystallographica Section B: Structural Science. 56 (6): 998–1002. Bibcode:2000AcCrB..56..998B. doi:10.1107/S0108768100010004. PMID   11099966.
  9. ↑ ВМ Погибко, ВВ Приседский, ИЛ Сидак (2010). "МЕХАНИЗМ ТЕРМИЧЕСКОГО РАЗЛОЖЕНИЯ ОКСАЛАТНОГО ПРЕКУРСОРА BaZrO3" (PDF). Archived (PDF) from the original on 2021-07-28.{{cite web}}: CS1 maint: multiple names: authors list (link)
  10. ↑ Runde, Wolfgang (2009). "Directed Synthesis of Crystalline Plutonium(III) and (IV) Oxalates: Accessing Redox-Controlled Separations in Acidic Solutions". Inorganic Chemistry. 48 (13): 5967–5972. doi:10.1021/ic900344u. PMID   19485387. S2CID   13498583.
  11. 1 2 3 Romero, S.; Mosset, A.; Trombe, J.C. (December 1996). "Two New Families of Lanthanide Mixed-Ligand Complexes, Oxalate–Carbonate and Oxalate–Formate: Synthesis and Structure of [Ce(H2O)]2(C2O4)2(CO3)·2.5 H2O and Ce(C2O4)(HCO2)" . Journal of Solid State Chemistry. 127 (2): 256–266. Bibcode:1996JSSCh.127..256R. doi:10.1006/jssc.1996.0382.
  12. ↑ Glasner, A.; Steinberg, M. (December 1961). "Thermal decomposition of the light rare earth oxalates" . Journal of Inorganic and Nuclear Chemistry. 22 (1–2): 39–48. doi:10.1016/0022-1902(61)80227-3.
  13. ↑ Trombe, Jean-Christian; Galy, Jean; Enjalbert, Renée (2002-10-15). "A neodymium(III)–ammonium complex involving oxalate and carbonate ligands: (NH 4 ) 2 [Nd 2 (C 2 O 4 ) 3 (CO 3 )(H 2 O)]·H 2 O" . Acta Crystallographica Section C: Crystal Structure Communications. 58 (10): m517 –m520. Bibcode:2002AcCrC..58M.517T. doi:10.1107/S0108270102014737. ISSN   0108-2701. PMID   12359932.
  14. 1 2 3 4 5 Romero, S (1997). "A new family of lanthanide oxalate carbonate, [Ln(H2O)]2(C2O4)(CO3)2 with Ln = Eu...Ho, presenting a relatively open framework". European Journal of Solid State and Inorganic Chemistry. 34: 209–219.
  15. ↑ Müller-Buschbaum, Klaus (2002). "Er2(CO3)2(C2O4)(H2O)2 — Synthese, Kristallstruktur und thermischer Abbau eines Carbonat-Oxalat-Hydrates des Erbiums" . Zeitschrift für anorganische und allgemeine Chemie (in German). 628 (8): 1761–1764. doi:10.1002/1521-3749(200208)628:8<1761::AID-ZAAC1761>3.0.CO;2-1. ISSN   1521-3749.
  16. ↑ Yang, Hui; Mao, Feifei; Xu, Cuixia (2018-05-24). "Syntheses, Crystal Structures and Properties of Two Novel Mixed Anion Hybrids with Formulas of Pb 6 O 2 (BO 3 ) 2 (C 2 O 4 ) and Pb 4 (CO 3 ) 2 (C 2 O 4 )(OH) 2" . ChemistrySelect. 3 (19): 5431–5438. doi:10.1002/slct.201801072. ISSN   2365-6549.
  17. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 Bagnall, Kenneth W. (2013-12-12). Th Thorium: Compounds with Carbon: Carbonates, Thiocyanates, Alkoxides, Carboxylates. Springer Science & Business Media. pp. 98–102. ISBN   978-3-662-06315-6.
  18. ↑ Bagnall, Kenneth W. (2013-12-12). Th Thorium: Compounds with Carbon: Carbonates, Thiocyanates, Alkoxides, Carboxylates. Springer Science & Business Media. p. 10. ISBN   978-3-662-06315-6.
  19. ↑ L. N. Essen, D. P. Alekseeva. "The production of mixed oxalate-carbonate complex compounds of thorium", Dokl. Akad. Nauk SSSR, 146:2 (1962), 380–382". www.mathnet.ru. Archived from the original on 2021-07-27. Retrieved 2021-07-27.
  20. 1 2 3 4 5 Beirakhov, A. G.; Orlova, I. M.; Mikhailov, Yu. N. (December 2014). "Coordination modes of α-dioximes in uranyl complexes" . Russian Journal of Inorganic Chemistry. 59 (14): 1679–1690. doi:10.1134/S0036023614140022. ISSN   0036-0236. S2CID   95903987.
  21. ↑ Beirakhov, A. G.; Orlova, I. M.; Il’in, E. G.; Aleksandrov, G. G.; Kanishcheva, A. S.; Mikhailov, Yu. N. (September 2010). "Uranyl complexes with ethylmethylglyoxime" . Russian Journal of Inorganic Chemistry. 55 (9): 1373–1380. doi:10.1134/S003602361009007X. ISSN   0036-0236. S2CID   97458234.
  22. 1 2 Beirakhov, A. G.; Orlova, I. M.; Il’in, E. G.; Kanishcheva, A. S.; Churakov, A. V.; Mikhailov, Yu. N. (July 2012). "Uranyl complexes with methyl derivatives of alicyclic dioximes" . Russian Journal of Inorganic Chemistry. 57 (7): 945–952. doi:10.1134/S0036023612070054. ISSN   0036-0236. S2CID   97320941.
  23. 1 2 Beirakhov, A. G.; Orlova, I. M.; Rotov, A. V.; Il’in, E. G.; Goeva, L. V.; Surazhskaya, M. D.; Churakov, A. V.; Mikhailov, Yu. N. (December 2016). "Conformation of diethylglyoxime in uranyl complexes" . Russian Journal of Inorganic Chemistry. 61 (12): 1522–1529. doi:10.1134/S0036023616120032. ISSN   0036-0236. S2CID   100478539.
  24. ↑ Fedoseev, A. M.; Grigor’ev, M. S.; Yusov, A. B. (September 2012). "Interaction of tetravalent actinides and Np(V) with some hydroxy carboxylic acids" . Radiochemistry. 54 (5): 443–451. doi:10.1134/S1066362212050049. ISSN   1066-3622. S2CID   95387998.
  25. ↑ Kartushova, R. E.; Rudenko, T. I.; Fomin, V. V. (1958). "Thermal decomposition of tetravalent and trivalent plutonium oxalates" (PDF). The Soviet Journal of Atomic Energy. 5 (1): 831–835. doi:10.1007/BF01505392. S2CID   94605282.
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