Manganese(II) carbonate

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Manganese(II) carbonate
Calcium-carbonate-xtal-3D-SF.png
Manganese (II) Carbonate.jpg
Names
IUPAC name
Manganese(II) carbonate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.009.040 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 209-942-9
PubChem CID
UNII
  • InChI=1S/CH2O3.Mn/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2 Yes check.svgY
    Key: XMWCXZJXESXBBY-UHFFFAOYSA-L Yes check.svgY
  • InChI=1/CH2O3.Mn/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2
    Key: XMWCXZJXESXBBY-NUQVWONBAJ
  • [Mn+2].[O-]C([O-])=O
Properties
MnCO3
Molar mass 114.95 g mol−1
AppearanceWhite to faint pink solid
Density 3.12 g/cm3
Melting point 200–300 °C (392–572 °F; 473–573 K)
decomposes [1] [2]
negligible
2.24 x 10−11
Solubility soluble in dilute acid, CO2
insoluble in alcohol, ammonia
+11,400·10−6 cm3/mol
1.597 (20 °C, 589 nm)
Structure
hexagonal-rhombohedral
Thermochemistry
94.8 J/mol·K [2]
Std molar
entropy
(S298)
109.5 J/mol·K [2]
-881.7 kJ/mol [2]
-811.4 kJ/mol [2]
Hazards
Flash point Non-flammable
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Yes check.svgY  verify  (what is  Yes check.svgYX mark.svgN ?)

Manganese carbonate is a compound with the chemical formula Mn CO3. Manganese carbonate occurs naturally as the mineral rhodochrosite but it is typically produced industrially. It is a pale pink, water-insoluble solid. Approximately 20,000 metric tonnes were produced in 2005. [3]

Contents

Structure and production

MnCO3 adopts a structure like calcite, consisting of manganese(II) ions in an octahedral coordination geometry. [4]

Treatment of aqueous solutions of manganese(II) nitrate with ammonia and carbon dioxide leads to precipitation of this faintly pink solid. The side product, ammonium nitrate is used as fertilizer.

Pink rhodochrosite, the mineral form of MnCO3, is of practical value as well as sought by collectors. Rhodochrosite-Pyrite-Calcite-219228.jpg
Pink rhodochrosite, the mineral form of MnCO3, is of practical value as well as sought by collectors.

Reactions and uses

The carbonate is insoluble in water but, like most carbonates, hydrolyses upon treatment with acids to give water-soluble salts.

Manganese carbonate decomposes with release of carbon dioxide, i.e. calcining, at 200 °C to give MnO1.88:

MnCO3 + 0.44 O2 → MnO1.8 + CO2

This method is sometimes employed in the production of manganese dioxide, which is used in dry-cell batteries and for ferrites. [3]

Manganese carbonate is widely used as an additive to plant fertilizers to cure manganese deficient crops. It is also used in health foods, in ceramics as a glaze colorant and flux, and in concrete stains. [5]

It is used in medicine as a hematinic.

Toxicity

Manganese poisoning, also known as manganism, may be caused by long-term exposure to manganese dust or fumes.

See also

Related Research Articles

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A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula CO2−3. The word carbonate may also refer to a carbonate ester, an organic compound containing the carbonate group C(=O)(O–)2.

<span class="mw-page-title-main">Manganese</span> Chemical element, symbol Mn and atomic number 25

Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy uses, particularly in stainless steels. It improves strength, workability, and resistance to wear. Manganese oxide is used as an oxidising agent; as a rubber additive; and in glass making, fertilisers, and ceramics. Manganese sulfate can be used as a fungicide.

<span class="mw-page-title-main">Nitrate</span> Polyatomic ion (NO3, charge –1) found in explosives and fertilisers

Nitrate is a polyatomic ion with the chemical formula NO
3
. Salts containing this ion are called nitrates. Nitrates are common components of fertilizers and explosives. Almost all inorganic nitrates are soluble in water. An example of an insoluble nitrate is bismuth oxynitrate.

<span class="mw-page-title-main">Oxide</span> Chemical compound where oxygen atoms are combined with atoms of other elements

An oxide is a chemical compound containing at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion of oxygen, an O2– ion with oxygen in the oxidation state of −2. Most of the Earth's crust consists of oxides. Even materials considered pure elements often develop an oxide coating. For example, aluminium foil develops a thin skin of Al2O3 that protects the foil from further oxidation.

<span class="mw-page-title-main">Sodium carbonate</span> Chemical compound

Sodium carbonate, Na2CO3, (also known as washing soda, soda ash and soda crystals) is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield moderately alkaline solutions in water. Historically, it was extracted from the ashes of plants growing in sodium-rich soils. Because the ashes of these sodium-rich plants were noticeably different from ashes of wood (once used to produce potash), sodium carbonate became known as "soda ash". It is produced in large quantities from sodium chloride and limestone by the Solvay process.

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<span class="mw-page-title-main">Manganese dioxide</span> Chemical compound

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2
. This blackish or brown solid occurs naturally as the mineral pyrolusite, which is the main ore of manganese and a component of manganese nodules. The principal use for MnO
2
is for dry-cell batteries, such as the alkaline battery and the zinc–carbon battery. MnO
2
is also used as a pigment and as a precursor to other manganese compounds, such as KMnO
4
. It is used as a reagent in organic synthesis, for example, for the oxidation of allylic alcohols. MnO
2
is α polymorph that can incorporate a variety of atoms in the "tunnels" or "channels" between the manganese oxide octahedra. There is considerable interest in α-MnO
2
as a possible cathode for lithium-ion batteries.

<span class="mw-page-title-main">Ammonium bicarbonate</span> Chemical compound

Ammonium bicarbonate is an inorganic compound with formula (NH4)HCO3. The compound has many names, reflecting its long history. Chemically speaking, it is the bicarbonate salt of the ammonium ion. It is a colourless solid that degrades readily to carbon dioxide, water and ammonia.

<span class="mw-page-title-main">Potassium permanganate</span> Chemical compound

Potassium permanganate is an inorganic compound with the chemical formula KMnO4. It is a purplish-black crystalline salt, that dissolves in water as K+ and MnO
4
, an intensely pink to purple solution.

<span class="mw-page-title-main">Hopcalite</span> Catalyst to oxidise carbon monoxide at room temperature

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<span class="mw-page-title-main">Manganese(II) chloride</span> Chemical compound

Manganese(II) chloride is the dichloride salt of manganese, MnCl2. This inorganic chemical exists in the anhydrous form, as well as the dihydrate (MnCl2·2H2O) and tetrahydrate (MnCl2·4H2O), with the tetrahydrate being the most common form. Like many Mn(II) species, these salts are pink, with the paleness of the color being characteristic of transition metal complexes with high spin d5 configurations.

<span class="mw-page-title-main">Manganate</span> Chemical compound

In inorganic nomenclature, a manganate is any negatively charged molecular entity with manganese as the central atom. However, the name is usually used to refer to the tetraoxidomanganate(2−) anion, MnO2−
4
, also known as manganate(VI) because it contains manganese in the +6 oxidation state. Manganates are the only known manganese(VI) compounds.

<span class="mw-page-title-main">Hexafluorosilicic acid</span> Octahedric silicon compound

Hexafluorosilicic acid is an inorganic compound with the chemical formula H
2
SiF
6
. Aqueous solutions of hexafluorosilicic acid consist of salts of the cation and hexafluorosilicate anion. These salts and their aqueous solutions are colorless.

<span class="mw-page-title-main">Nickel(II) carbonate</span> Chemical compound

Nickel(II) carbonate describes one or a mixture of inorganic compounds containing nickel and carbonate. From the industrial perspective, the most important nickel carbonate is basic nickel carbonate with the formula Ni4CO3(OH)6(H2O)4. Simpler carbonates, ones more likely encountered in the laboratory, are NiCO3 and its hexahydrate. All are paramagnetic green solids containing Ni2+ cations. The basic carbonate is an intermediate in the hydrometallurgical purification of nickel from its ores and is used in electroplating of nickel.

<span class="mw-page-title-main">Manganese(II) sulfate</span> Chemical compound

Manganese(II) sulfate usually refers to the inorganic compound with the formula MnSO4·H2O. This pale pink deliquescent solid is a commercially significant manganese(II) salt. Approximately 260,000 tonnes of manganese(II) sulfate were produced worldwide in 2005. It is the precursor to manganese metal and many other chemical compounds. Manganese-deficient soil is remediated with this salt.

<span class="mw-page-title-main">Manganese(II) oxide</span> Chemical compound

Manganese(II) oxide is an inorganic compound with chemical formula MnO. It forms green crystals. The compound is produced on a large scale as a component of fertilizers and food additives.

<span class="mw-page-title-main">Manganese(II) acetate</span> Chemical compound

Manganese(II) acetate are chemical compounds with the formula Mn(CH3CO2)2·(H2O)n where n = 0, 2, 4. These materials are white or pale pink solids. Some of these compounds are used as a catalyst and as fertilizer.

<span class="mw-page-title-main">Manganese(II) nitrate</span> Chemical compound

Manganese(II) nitrate refers to the inorganic compounds with formula Mn(NO3)2·(H2O)n. These compounds are nitrate salts containing varying amounts of water. A common derivative is the tetrahydrate, Mn(NO3)2·4H2O, but mono- and hexahydrates are also known as well as the anhydrous compound. Some of these compounds are useful precursors to the oxides of manganese. Typical of a manganese(II) compound, it is a paramagnetic pale pink solid.

References

  1. Sigma-Aldrich Co., Manganese(II) carbonate. Retrieved on 2014-05-06.
  2. 1 2 3 4 5 "Manganese(II) carbonate".
  3. 1 2 Arno H. Reidies (2007). "Manganese Compounds". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a16_123. ISBN   978-3527306732.
  4. Pertlik, F. (1986). "Structures of hydrothermally synthesized cobalt(II) carbonate and nickel(II) carbonate". Acta Crystallographica Section C. 42: 4–5. doi:10.1107/S0108270186097524.
  5. "How To Stain Concrete with Manganese"