Potassium bicarbonate

Last updated
Potassium bicarbonate
Potassium bicarbonate.svg
Names
IUPAC name
potassium hydrogencarbonate
Other names
potassium hydrogencarbonate, potassium acid carbonate
Identifiers
3D model (JSmol)
4535309
ChEBI
ChEMBL
ChemSpider
DrugBank
ECHA InfoCard 100.005.509 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 206-059-0
E number E501(ii) (acidity regulators, ...)
KEGG
PubChem CID
UNII
  • InChI=1S/CH2O3.K/c2-1(3)4;/h(H2,2,3,4);/q;+1/p-1 Yes check.svgY
    Key: TYJJADVDDVDEDZ-UHFFFAOYSA-M Yes check.svgY
  • InChI=1/CH2O3.K/c2-1(3)4;/h(H2,2,3,4);/q;+1/p-1
    Key: TYJJADVDDVDEDZ-REWHXWOFAA
  • [K+].[O-]C(=O)O
Properties
KHCO3
Molar mass 100.115 g/mol
Appearancewhite crystals
Odor odorless
Density 2.17 g/cm3
Melting point 292 °C (558 °F; 565 K) (decomposes)
22.4 g/100 mL (20 °C) [1]
Solubility practically insoluble in alcohol
Acidity (pKa)10.329 [2]

6.351 (carbonic acid) [2]

Thermochemistry
-963.2 kJ/mol
Pharmacology
A12BA04 ( WHO )
Hazards [3]
GHS labelling:
GHS-pictogram-exclam.svg
Warning
H315, H319, H335
P261, P264, P280, P302+P352, P304+P340, P305+P351+P338, P312, P332+P313, P362, P403+P233, P405
NFPA 704 (fire diamond)
NFPA 704.svgHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
0
0
Flash point Non-Flammable
Lethal dose or concentration (LD, LC):
> 2000 mg/kg (rat, oral)
Safety data sheet (SDS) MSDS
Related compounds
Other anions
Potassium carbonate
Other cations
Sodium bicarbonate
Ammonium bicarbonate
Related compounds
Potassium bisulfate
Monopotassium phosphate
Dipotassium phosphate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
X mark.svgN  verify  (what is  Yes check.svgYX mark.svgN ?)

Potassium bicarbonate (IUPAC name: potassium hydrogencarbonate, also known as potassium acid carbonate) is the inorganic compound with the chemical formula KHCO3. It is a white solid. [1]

Contents

A fire extinguisher containing potassium bicarbonate Potassium bicarbonate purple-K.jpg
A fire extinguisher containing potassium bicarbonate

Production and reactivity

It is manufactured by treating an aqueous solution of potassium carbonate with carbon dioxide: [1]

K2CO3 + CO2 + H2O → 2 KHCO3

Decomposition of the bicarbonate occurs between 100 and 120 °C (212 and 248 °F):

2 KHCO3 → K2CO3 + CO2 + H2O

This reaction is employed to prepare high purity potassium carbonate.

Uses

Food and drink

This compound is a source of carbon dioxide for leavening in baking. It can substitute for baking soda (sodium bicarbonate) for those with a low-sodium diet, [4] and it is an ingredient in low-sodium baking powders. [5] [6]

As an inexpensive, nontoxic base, it is widely used in diverse application to regulate pH or as a reagent. Examples include as buffering agent in medications, an additive in winemaking.

Potassium bicarbonate is often added to bottled water to improve taste, [7] and is also used in club soda.

Medical uses and health

Higher potassium intake may prevent development of kidney stone disease. [8] Higher potassium intake is associated with a reduced risk of stroke. [9]

Fire extinguishers

Potassium bicarbonate is used as a fire suppression agent ("BC dry chemical") in some dry chemical fire extinguishers, as the principal component of the Purple-K dry chemical, and in some applications of condensed aerosol fire suppression. It is the only dry chemical fire suppression agent recognized by the U.S. National Fire Protection Association for firefighting at airport crash rescue sites. It is about twice as effective in fire suppression as sodium bicarbonate. [10]

Agriculture

Potassium bicarbonate has widespread use in crops, especially for neutralizing acidic soil. [11]

Potassium bicarbonate is an effective fungicide against powdery mildew and apple scab, allowed for use in organic farming. [12] [13] [14] [15]

Potassium bicarbonate is a contact killer for Spanish moss when mixed 14 cup per gallon. [16]

History

The word saleratus, from Latin sal æratus meaning "aerated salt", first used in the nineteenth century, refers to both potassium bicarbonate and sodium bicarbonate. [17]

Related Research Articles

<span class="mw-page-title-main">Bicarbonate</span> Polyatomic anion

In inorganic chemistry, bicarbonate is an intermediate form in the deprotonation of carbonic acid. It is a polyatomic anion with the chemical formula HCO
3
.

<span class="mw-page-title-main">Carbonate</span> Salt or ester of carbonic acid

A carbonate is a salt of carbonic acid, H2CO3, characterized by the presence of the carbonate ion, a polyatomic ion with the formula CO2−3. The word "carbonate" may also refer to a carbonate ester, an organic compound containing the carbonate groupO=C(−O−)2.

<span class="mw-page-title-main">Natron</span> Carbonate mineral

Natron is a naturally occurring mixture of sodium carbonate decahydrate (Na2CO3·10H2O, a kind of soda ash) and around 17% sodium bicarbonate (also called baking soda, NaHCO3) along with small quantities of sodium chloride and sodium sulfate. Natron is white to colourless when pure, varying to gray or yellow with impurities. Natron deposits are sometimes found in saline lake beds which arose in arid environments. Throughout history natron has had many practical applications that continue today in the wide range of modern uses of its constituent mineral components.

<span class="mw-page-title-main">Sodium bicarbonate</span> Chemical compound

Sodium bicarbonate (IUPAC name: sodium hydrogencarbonate), commonly known as baking soda or bicarbonate of soda, is a chemical compound with the formula NaHCO3. It is a salt composed of a sodium cation (Na+) and a bicarbonate anion (HCO3). Sodium bicarbonate is a white solid that is crystalline, but often appears as a fine powder. It has a slightly salty, alkaline taste resembling that of washing soda (sodium carbonate). The natural mineral form is nahcolite. It is a component of the mineral natron and is found dissolved in many mineral springs.

<span class="mw-page-title-main">Sodium carbonate</span> Chemical compound

Sodium carbonate is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield alkaline solutions in water. Historically, it was extracted from the ashes of plants grown in sodium-rich soils, and because the ashes of these sodium-rich plants were noticeably different from ashes of wood, sodium carbonate became known as "soda ash". It is produced in large quantities from sodium chloride and limestone by the Solvay process, as well as by carbonating sodium hydroxide which is made using the Chlor-alkali process.

<span class="mw-page-title-main">Baking powder</span> Dry chemical leavening agent

Baking powder is a dry chemical leavening agent, a mixture of a carbonate or bicarbonate and a weak acid. The base and acid are prevented from reacting prematurely by the inclusion of a buffer such as cornstarch. Baking powder is used to increase the volume and lighten the texture of baked goods. It works by releasing carbon dioxide gas into a batter or dough through an acid–base reaction, causing bubbles in the wet mixture to expand and thus leavening the mixture. The first single-acting baking powder was developed by food manufacturer Alfred Bird in England in 1843. The first double-acting baking powder, which releases some carbon dioxide when dampened and later releases more of the gas when heated by baking, was developed by Eben Norton Horsford in the U.S. in the 1860s.

<span class="mw-page-title-main">Potassium hydroxide</span> Inorganic compound (KOH)

Potassium hydroxide is an inorganic compound with the formula KOH, and is commonly called caustic potash.

<span class="mw-page-title-main">Potassium carbonate</span> Chemical compound

Potassium carbonate is the inorganic compound with the formula K2CO3. It is a white salt, which is soluble in water and forms a strongly alkaline solution. It is deliquescent, often appearing as a damp or wet solid. Potassium carbonate is mainly used in the production of soap and glass. Commonly, it can be found as the result of leakage of alkaline batteries.

<span class="mw-page-title-main">Magnesium carbonate</span> Chemical compound

Magnesium carbonate, MgCO3, is an inorganic salt that is a colourless or white solid. Several hydrated and basic forms of magnesium carbonate also exist as minerals.

<span class="mw-page-title-main">Ammonium bicarbonate</span> Chemical compound

Ammonium bicarbonate is an inorganic compound with formula (NH4)HCO3. The compound has many names, reflecting its long history. Chemically speaking, it is the bicarbonate salt of the ammonium ion. It is a colourless solid that degrades readily to carbon dioxide, water and ammonia.

The Solvay process or ammonia-soda process is the major industrial process for the production of sodium carbonate (soda ash, Na2CO3). The ammonia-soda process was developed into its modern form by the Belgian chemist Ernest Solvay during the 1860s. The ingredients for this are readily available and inexpensive: salt brine (from inland sources or from the sea) and limestone (from quarries). The worldwide production of soda ash in 2005 was estimated at 42 million tonnes, which is more than six kilograms (13 lb) per year for each person on Earth. Solvay-based chemical plants now produce roughly three-quarters of this supply, with the remaining being mined from natural deposits. This method superseded the Leblanc process.

<span class="mw-page-title-main">Powdery mildew</span> Fungal plant disease

Powdery mildew is a fungal disease that affects a wide range of plants. Powdery mildew diseases are caused by many different species of ascomycete fungi in the order Erysiphales. Powdery mildew is one of the easier plant diseases to identify, as its symptoms are quite distinctive. Infected plants display white powdery spots on the leaves and stems. The lower leaves are the most affected, but the mildew can appear on any above-ground part of the plant. As the disease progresses, the spots get larger and denser as large numbers of asexual spores are formed, and the mildew may spread up and down the length of the plant.

<span class="mw-page-title-main">Ammonium carbonate</span> Chemical used as leavening agent and smelling salt

Ammonium carbonate is a salt with the chemical formula (NH4)2CO3. Since it readily degrades to gaseous ammonia and carbon dioxide upon heating, it is used as a leavening agent and also as smelling salt. It is also known as baker's ammonia and is a predecessor to the more modern leavening agents baking soda and baking powder. It is a component of what was formerly known as sal volatile and salt of hartshorn, and produces a pungent smell when baked. It comes in the form of a white powder or block, with a molar mass of 96.09 g/mol and a density of 1.50 g/cm3. It is a strong electrolyte.

Calcium bicarbonate, also called calcium hydrogencarbonate, has the chemical formula Ca(HCO3)2. The term does not refer to a known solid compound; it exists only in aqueous solution containing calcium (Ca2+), bicarbonate (HCO
3
), and carbonate (CO2−
3
) ions, together with dissolved carbon dioxide (CO2). The relative concentrations of these carbon-containing species depend on the pH; bicarbonate predominates within the range 6.36–10.25 in fresh water.

<span class="mw-page-title-main">Potassium superoxide</span> Chemical compound

Potassium superoxide is an inorganic compound with the formula KO2. It is a yellow paramagnetic solid that decomposes in moist air. It is a rare example of a stable salt of the superoxide anion. It is used as a CO2 scrubber, H2O dehumidifier, and O2 generator in rebreathers, spacecraft, submarines, and spacesuits.

<span class="mw-page-title-main">Monocalcium phosphate</span> Chemical compound

Monocalcium phosphate is an inorganic compound with the chemical formula Ca(H2PO4)2 ("AMCP" or "CMP-A" for anhydrous monocalcium phosphate). It is commonly found as the monohydrate ("MCP" or "MCP-M"), Ca(H2PO4)2·H2O. Both salts are colourless solids. They are used mainly as superphosphate fertilizers and are also popular leavening agents.

<span class="mw-page-title-main">Disodium pyrophosphate</span> Chemical compound

Disodium pyrophosphate or sodium acid pyrophosphate (SAPP) is an inorganic compound with the chemical formula Na2H2P2O7. It consists of sodium cations (Na+) and dihydrogen pyrophosphate anions (H2P2O2−7). It is a white, water-soluble solid that serves as a buffering and chelating agent, with many applications in the food industry. When crystallized from water, it forms a hexahydrate, but it dehydrates above room temperature. Pyrophosphate is a polyvalent anion with a high affinity for polyvalent cations, e.g. Ca2+.

<span class="mw-page-title-main">Fire extinguisher</span> Active fire protection device

A fire extinguisher is a handheld active fire protection device usually filled with a dry or wet chemical used to extinguish or control small fires, often in emergencies. It is not intended for use on an out-of-control fire, such as one which has reached the ceiling, endangers the user, or otherwise requires the equipment, personnel, resources or expertise of a fire brigade. Typically, a fire extinguisher consists of a hand-held cylindrical pressure vessel containing an agent that can be discharged to extinguish a fire. Fire extinguishers manufactured with non-cylindrical pressure vessels also exist but are less common.

<span class="mw-page-title-main">Condensed aerosol fire suppression</span> Particle-based form of fire extinction

Condensed aerosol fire suppression is a particle-based method of fire extinction. It is similar to but not identical to dry chemical fire extinction methods, using an innovative pyrogenic, condensed aerosol fire suppressant. It is a highly effective fire suppression method for class A, B, C, E and F. Some aerosol-generating compounds produce a corrosive by-product that may damage electronic equipment, although later generations lower the effect.

<span class="mw-page-title-main">Americium(III) hydroxide</span> Chemical compound

Americium(III) hydroxide is a radioactive inorganic compound with the chemical formula Am(OH)3. It consists of one americium atom and three hydroxy groups. It was first discovered in 1944, closely related to the Manhattan Project. However, these results were confidential and were only released to the public in 1945. It was the first isolated sample of an americium compound, and the first americium compound discovered.

References

  1. 1 2 3 H. Schultz; G. Bauer; E. Schachl; F. Hagedorn; P. Schmittinger (2005). "Potassium Compounds". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a22_039. ISBN   3-527-30673-0.
  2. 1 2 Goldberg, Robert N.; Kishore, Nand; Lennen, Rebecca M. (2003). "Thermodynamic quantities for the ionization reactions of buffers in water". In David R. Lide (ed.). CRC handbook of chemistry and physics (84th ed.). Boca Raton, FL: CRC Press. pp. 7–13. ISBN   978-0-8493-0595-5 . Retrieved 6 March 2011.
  3. "Potassium bicarbonate". pubchem.ncbi.nlm.nih.gov.
  4. "Potassium Bicarbonate". encyclopedia.com. Cengage. Retrieved May 29, 2020.
  5. "Home cooking with less salt". harvard.edu. Harvard University. March 2020. Retrieved May 29, 2020.
  6. Wilkens, Katy G. (15 December 2018). "You Have the (Baking) Power with Low-Sodium Baking Powders". agingkingcounty.org. Aging & Disability Services for Seattle & King County. Retrieved May 29, 2020.
  7. "Why Your Bottled Water Contains Four Different Ingredients". Time Magazine. July 24, 2014.
  8. He FJ, MacGregor GA (2008). "Beneficial effects of potassium on human health". Physiologia Plantarum . 133 (4): 725–735. doi:10.1111/j.1399-3054.2007.01033.x. PMID   18724413.
  9. Vinceti M, Filippini T, Orsini N (2016). "Meta-Analysis of Potassium Intake and the Risk of Stroke". Journal of the American Heart Association . 5 (10): e004210. doi:10.1161/JAHA.116.004210. PMC   5121516 . PMID   27792643.
  10. "Purple-K-Powder". US Naval Research Laboratory. Archived from the original on 15 February 2009. Retrieved 8 February 2012.
  11. "Potassium Bicarbonate Handbook" (PDF). Armand Products Company. Archived from the original (PDF) on 2021-01-22. Retrieved 2016-09-06.
  12. "Use of Baking Soda as a Fungicide". Archived from the original on 2010-05-07. Retrieved 2010-02-14.
  13. "Powdery Mildew - Sustainable Gardening Australia". Archived from the original on 2016-03-03.
  14. "Organic Fruit Production in Michigan".
  15. "Efficacy of Armicarb (potassium bicarbonate) against scab and sooty blotch on apples" (PDF).
  16. "How to Toss Your Spanish Moss". SkyFrog landscape company. 4 December 2020.
  17. "saleratus". merriam-webster.com. Merriam-Webster. Retrieved May 29, 2020.