Potassium aluminate

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Potassium aluminate [1]
Names
IUPAC name
potassium aluminate
Identifiers
  • 12003-63-3 Yes check.svgY
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.289 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 234-432-8
PubChem CID
UNII
  • InChI=1S/Al.K.2O/q;+1;;-1
    Key: KVOIJEARBNBHHP-UHFFFAOYSA-N
  • [O-][Al]=O.[K+]
Properties
K2Al2O4
Molar mass 196.156 g·mol−1
very soluble
Hazards
GHS labelling:
GHS-pictogram-acid.svg
Danger
H314
P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Potassium aluminate is an inorganic compound with the formula KAlO2, which in aqueous solution exists as K[Al(OH)4].

Reactions

Potassium aluminate can be used to produce Potassium alum with Sulfuric acid in this reaction.

KAlO2 + 2 H2SO4 ⇌ KAl(SO4)2 + 2 H2O

Related Research Articles

Muscovite Hydrated phyllosilicate mineral

Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula KAl2(AlSi3O10)(F,OH)2, or (KF)2(Al2O3)3(SiO2)6(H2O). It has a highly perfect basal cleavage yielding remarkably thin laminae (sheets) which are often highly elastic. Sheets of muscovite 5 meters × 3 meters (16.5 feet × 10 feet) have been found in Nellore, India.

Orthoclase Tectosilicate mineral found in igneous rock

Orthoclase, or orthoclase feldspar (endmember formula KAlSi3O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture," because its two cleavage planes are at right angles to each other. It is a type of potassium feldspar, also known as K-feldspar. The gem known as moonstone (see below) is largely composed of orthoclase.

Sodium hydroxide Chemical compound with formula NaOH

Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations Na+
and hydroxide anions OH
.

Alum Family of double sulfate salts of aluminium

An alum is a type of chemical compound, usually a hydrated double sulfate salt of aluminium with the general formula XAl(SO
4
)
2
·12 H
2
O
, where X is a monovalent cation such as potassium or ammonium. By itself, "alum" often refers to potassium alum, with the formula KAl(SO
4
)
2
·12 H
2
O
. Other alums are named after the monovalent ion, such as sodium alum and ammonium alum.

The Bayer process is the principal industrial means of refining bauxite to produce alumina (aluminium oxide) and was developed by Carl Josef Bayer. Bauxite, the most important ore of aluminium, contains only 30–60% aluminium oxide (Al2O3), the rest being a mixture of silica, various iron oxides, and titanium dioxide. The aluminium oxide must be purified before it can be refined to aluminium metal.

Potassium permanganate Chemical compound

Potassium permanganate is an inorganic compound with the chemical formula KMnO4 and composed of K+ and MnO
4
. It is a purplish-black crystalline salt, that dissolves in water to give intensely pink or purple solutions.

Potassium dichromate Chemical compound

Potassium dichromate, K2Cr2O7, is a common inorganic chemical reagent, most commonly used as an oxidizing agent in various laboratory and industrial applications. As with all hexavalent chromium compounds, it is acutely and chronically harmful to health. It is a crystalline ionic solid with a very bright, red-orange color. The salt is popular in the laboratory because it is not deliquescent, in contrast to the more industrially relevant salt sodium dichromate.

Silicate mineral Rock-forming minerals with predominantly silicate anions

Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust.

Sodium aluminate Chemical compound

Sodium aluminate is an inorganic chemical that is used as an effective source of aluminium hydroxide for many industrial and technical applications. Pure sodium aluminate (anhydrous) is a white crystalline solid having a formula variously given as NaAlO2, NaAl(OH)4 (hydrated), Na2O·Al2O3, or Na2Al2O4. Commercial sodium aluminate is available as a solution or a solid.
Other related compounds, sometimes called sodium aluminate, prepared by reaction of Na2O and Al2O3 are Na5AlO4 which contains discrete AlO45− anions, Na7Al3O8 and Na17Al5O16 which contain complex polymeric anions, and NaAl11O17, once mistakenly believed to be β-alumina, a phase of aluminium oxide.

In chemistry, an aluminate is a compound containing an oxyanion of aluminium, such as sodium aluminate. In the naming of inorganic compounds, it is a suffix that indicates a polyatomic anion with a central aluminum atom.

Double salt

A double salt is a salt that contains more than one different cation or anion. Examples of double salts include alums (with the general formula MIMIII[SO4]2·12H2O) and Tutton's salts (with the general formula [MI]2MII[SO4]2·6H2O). Other examples include potassium sodium tartrate, ammonium iron(II) sulfate (Mohr's salt), and bromlite. The fluorocarbonates contain fluoride and carbonate anions. Many coordination complexes form double salts.

Lithium aluminate Chemical compound

Lithium aluminate, also called lithium aluminium oxide, is an inorganic chemical compound, an aluminate of lithium. In microelectronics, lithium aluminate is considered as a lattice matching substrate for gallium nitride. In nuclear technology, lithium aluminate is of interest as a solid tritium breeder material, for preparing tritium fuel for nuclear fusion.

Ettringite Calcium sulfo-aluminate

Ettringite is a hydrous calcium aluminium sulfate mineral with formula: Ca6Al2(SO4)3(OH)12·26H2O. It is a colorless to yellow mineral crystallizing in the trigonal system. The prismatic crystals are typically colorless, turning white on partial dehydration. It is part of the ettringite-group which includes other sulfates such as thaumasite and bentorite.

Tricalcium aluminate Ca3Al2O6, often formulated as 3CaO·Al2O3 to highlight the proportions of the oxides from which it is made, is the most basic of the calcium aluminates. It does not occur in nature, but is an important mineral phase in Portland cement.

Calcium aluminates

Calcium aluminates are a range of materials obtained by heating calcium oxide and aluminium oxide together at high temperatures. They are encountered in the manufacture of refractories and cements.

Monocalcium aluminate (CaAl2O4) is one of the series of calcium aluminates. It does occur in nature, although only very rarely, as two polymorphs known as krotite and dmitryivanovite, both from meteorites. It is important in the composition of calcium aluminate cements.

An AFm phase is an "alumina, ferric oxide, monosulfate" phase, or aluminate ferrite monosulfate, or Al2O3, Fe2O3 mono, in cement chemist notation. AFm phases are important in the hydration of hydraulic cements.

Alum-(K)

Alum-(K) is a hydrous potassium aluminium sulfate mineral with formula KAl(SO4)2·12(H2O). It's IMA symbol is Aum-K. It is the mineral form of potassium alum and is referred to as potassium alum in older sources. It is a member of the alum group.

Cement hydration and strength development mainly depend on two silicate phases: tricalcium silicate (C3S) (alite), and dicalcium silicate (C2S) (belite). Upon hydration, the main reaction products are calcium silicate hydrates (C-S-H) and calcium hydroxide Ca(OH)2, written as CH in the cement chemist notation. C-S-H is the phase playing the role of the glue in the cement hardened paste and responsible of its cohesion. Cement also contains two aluminate phases: C3A and C4AF, respectively the tricalcium aluminate and the tetracalcium aluminoferrite. C3A hydration products are AFm, calcium aluminoferrite monosulfate, and ettringite, a calcium aluminoferrite trisulfate (AFt). C4AF hydrates as hydrogarnet and ferrous ettringite.

References

  1. Lide, David R. (1998). Handbook of Chemistry and Physics (87 ed.). Boca Raton, Florida: CRC Press. pp. 4–76. ISBN   0-8493-0594-2.