Potassium telluride

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Potassium telluride
CaF2 polyhedra.png
K+: __   Te2-: __
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.032.039 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 235-256-4
PubChem CID
  • InChI=1S/2K.Te
    Key: JNKJTXHDWHQVDL-UHFFFAOYSA-N
  • [K][Te][K]
Properties
K2Te
Molar mass 298.64 g/mol
Appearancepale yellow powder, turns grey when exposed to air [1]
Melting point 874 °C
Related compounds
Other anions
Potassium oxide
Potassium sulfide
Potassium selenide
Potassium polonide
Other cations
Lithium telluride
Sodium telluride
Rubidium telluride
Caesium telluride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Potassium telluride is an inorganic compound with a chemical formula K2Te. It is formed from potassium and tellurium, making it a telluride. [2] Potassium telluride is a white powder. Like rubidium telluride and caesium telluride, it can be used as an ultraviolet detector in space. Its crystal structure is similar to other tellurides, which have an anti-fluorite structure.

Contents

Production

Tellurium will react with melting potassium cyanide (KCN) producing potassium telluride. It can also be produced by direct combination of potassium and tellurium, usually in liquid ammonia solvent: [3]

Reactions

Adding potassium telluride to water and letting the filtrate stand in air leads to an oxidation reaction that generates potassium hydroxide (KOH) and elemental tellurium: [3] [4]

Related Research Articles

<span class="mw-page-title-main">Acid–base reaction</span> Chemical reaction between an acid and a base

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<span class="mw-page-title-main">Tellurium</span> Chemical element, symbol Te and atomic number 52

Tellurium is a chemical element; it has symbol Te and atomic number 52. It is a brittle, mildly toxic, rare, silver-white metalloid. Tellurium is chemically related to selenium and sulfur, all three of which are chalcogens. It is occasionally found in its native form as elemental crystals. Tellurium is far more common in the Universe as a whole than on Earth. Its extreme rarity in the Earth's crust, comparable to that of platinum, is due partly to its formation of a volatile hydride that caused tellurium to be lost to space as a gas during the hot nebular formation of Earth.

<span class="mw-page-title-main">Potassium oxide</span> Chemical compound

Potassium oxide (K2O) is an ionic compound of potassium and oxygen. It is a base. This pale yellow solid is the simplest oxide of potassium. It is a highly reactive compound that is rarely encountered. Some industrial materials, such as fertilizers and cements, are assayed assuming the percent composition that would be equivalent to K2O.

<span class="mw-page-title-main">Alkaline fuel cell</span> Type of fuel cell

The alkaline fuel cell (AFC), also known as the Bacon fuel cell after its British inventor, Francis Thomas Bacon, is one of the most developed fuel cell technologies. Alkaline fuel cells consume hydrogen and pure oxygen, to produce potable water, heat, and electricity. They are among the most efficient fuel cells, having the potential to reach 70%.

<span class="mw-page-title-main">Tellurium dioxide</span> Chemical compound

Tellurium dioxide (TeO2) is a solid oxide of tellurium. It is encountered in two different forms, the yellow orthorhombic mineral tellurite, β-TeO2, and the synthetic, colourless tetragonal (paratellurite), α-TeO2. Most of the information regarding reaction chemistry has been obtained in studies involving paratellurite, α-TeO2.

<span class="mw-page-title-main">Tellurate</span> Compound containing an oxyanion of tellurium

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Rubidium telluride is the inorganic compound with the formula Rb2Te. It is a yellow-green powder that melts at either 775 °C or 880 °C (two different values have been reported). It is an obscure material of minor academic interest.

<span class="mw-page-title-main">Hydrogen telluride</span> Chemical compound

Hydrogen telluride is the inorganic compound with the formula H2Te. A hydrogen chalcogenide and the simplest hydride of tellurium, it is a colorless gas. Although unstable in ambient air, the gas can exist at very low concentrations long enough to be readily detected by the odour of rotting garlic at extremely low concentrations; or by the revolting odour of rotting leeks at somewhat higher concentrations. Most compounds with Te–H bonds (tellurols) are unstable with respect to loss of H2. H2Te is chemically and structurally similar to hydrogen selenide, both are acidic. The H–Te–H angle is about 90°. Volatile tellurium compounds often have unpleasant odours, reminiscent of decayed leeks or garlic.

<span class="mw-page-title-main">Tritellurium dichloride</span> Chemical compound

Tritellurium dichloride is the inorganic compound with the formula Te3Cl2. It is one of the more stable lower chlorides of tellurium.

Tellurium compounds are compounds containing the element tellurium (Te). Tellurium belongs to the chalcogen family of elements on the periodic table, which also includes oxygen, sulfur, selenium and polonium: Tellurium and selenium compounds are similar. Tellurium exhibits the oxidation states −2, +2, +4 and +6, with +4 being most common.

<span class="mw-page-title-main">Neptunium(IV) fluoride</span> Chemical compound

Neptunium(IV) fluoride or neptunium tetrafluoride is a inorganic compound with the formula NpF4. It is a green salt and is isostructural with UF4.

The telluride phosphides are a class of mixed anion compounds containing both telluride and phosphide ions. The phosphidotelluride or telluridophosphide compounds have a [TeP]3− group in which the tellurium atom has a bond to the phosphorus atom. A formal charge of −2 is on the phosphorus and −1 on the tellurium. There is no binary compound of tellurium and phosphorus. Not many telluride phosphides are known, but they have been discovered for noble metals, actinides, and group 4 elements.

The telluride iodides are chemical compounds that contain both telluride ions (Te2−) and iodide ions (I). They are in the class of mixed anion compounds or chalcogenide halides.

<span class="mw-page-title-main">Rubidium sulfide</span> Chemical compound

Rubidium sulfide is an inorganic compound and a salt with the chemical formula Rb2S. It is a white solid with similar properties to other alkali metal sulfides.

Curium compounds are compounds containing the element curium (Cm). Curium usually forms compounds in the +3 oxidation state, although compounds with curium in the +4, +5 and +6 oxidation states are also known.

Lithium telluride (Li2Te) is an inorganic compound of lithium and tellurium. Along with LiTe3, it is one of the two intermediate solid phases in the lithium-tellurium system. It can be prepared by directly reacting lithium and tellurium in a beryllium oxide crucible at 950°C.

<span class="mw-page-title-main">Gold(I) cyanide</span> Chemical compound

Gold(I) cyanide is the inorganic compound with the chemical formula AuCN. It is the binary cyanide of gold(I). It is an odourless, tasteless yellow solid. Wet gold(I) cyanide is unstable to light and will become greenish. Gold(I) cyanide itself is only of academic interest, but its derivative dicyanoaurate is an intermediate in gold cyanidation, the extraction of gold from its ores.

<span class="mw-page-title-main">Potassium perrhenate</span> Chemical compound

Potassium perrhenate is an inorganic compound with the chemical formula KReO4.

<span class="mw-page-title-main">Rubidium oxalate</span> Chemical compound

Rubidium oxalate is the oxalate salt of rubidium, with the chemical formula of Rb2C2O4.

References

  1. Sangester J. and Pelton AD; Journal of Phase Equilibria, 1997, 18(4) p. 394.
  1. Linda D. Schultz (October 1990). "Synthesis and characterization of potassium polytellurides in liquid ammonia solution". Inorganica Chimica Acta. 176 (2): 271–275. doi:10.1016/S0020-1693(00)84855-0 . Retrieved 2019-11-23.
  2. Brigitte Eisenmann, Herbert Schäfer: K2Te3 : The First Binary Alkali-Metal Polytelluride with Te2−3-Ions. In: Angewandte Chemie International Edition in English. 17, 1978, S. 684, doi : 10.1002/anie.197806841.
  3. 1 2 Wolfgang A. Herrmann, Christian Erich Zybill (2014). Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 4, 1997 Volume 4: Sulfur, Selenium and Tellurium. Georg Thieme Verlag. p. 191. ISBN   978-3-13-179191-7.
  4. Adolf Pinner (1885), Repetitorium Der Anorganischen Chemie [Repetitorium of Inorganic Chemistry] (in German), Рипол Классик, p. 116, ISBN   978-5-87746-719-4