Teflic acid

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Teflic acid
Teflic acid 2D full.svg
Space-filling model Teflic-acid-3D-spacefill.png
Space-filling model
Names
IUPAC name
Pentafluoroorthotelluric acid
Other names
Teflic acid
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.161.534 OOjs UI icon edit-ltr-progressive.svg
PubChem CID
  • InChI=1S/F5HOTe/c1-7(2,3,4,5)6/h6H Yes check.svgY
    Key: OAOSLENTGBMCNC-UHFFFAOYSA-N Yes check.svgY
  • InChI=1/F5HOTe/c1-7(2,3,4,5)6/h6H
    Key: OAOSLENTGBMCNC-UHFFFAOYAO
  • F[Te](F)(F)(F)(F)O
Properties
HOTeF5
Molar mass 239.60 g·mol−1
Appearancecolorless solid
Melting point 39.1 °C (102.4 °F; 312.2 K)
Boiling point 59.7 °C (139.5 °F; 332.8 K)
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
corrosive, toxic
GHS labelling:
GHS-pictogram-acid.svg
Danger
H314
P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Yes check.svgY  verify  (what is  Yes check.svgYX mark.svgN ?)

Teflic acid is a chemical compound with the formula H O Te F 5. This strong acid is related to orthotelluric acid, Te(OH)6. Teflic acid has a slightly distorted octahedral molecular geometry.

Contents

Preparation

Teflic acid was accidentally discovered by Engelbrecht and Sladky. Their synthesis did not yield the anticipated telluryl fluoride TeO2F2, but a mixture of volatile telluric compounds, containing HOTeF5: [1]

BaTeO4 + 10 FSO2OH → HOTeF5 (25%)

Teflic acid can also be prepared from fluorosulfonic acid and barium tellurate: [2]

5 FSO2OH + Ba2+[TeO2(OH)4]2− → HOTeF5 + 4 H2SO4 + BaSO4

It is also the first hydrolysis product of tellurium hexafluoride:

TeF6 + H2O → HOTeF5 + HF

Teflates

Boron teflate Boron-teflate-3D-balls.png
Boron teflate

The conjugate base of teflic acid is called the teflate anion, F5TeO (not to be confused with triflate). Many teflates are known, one example being B(OTeF5)3, that can be pyrolysed to give acid anhydride O(TeF5)2. [2]

2 B(OTeF5)3 → 2 B(OTeF5)2F + O(TeF5)2

The teflate anion is known to resist oxidation. This property has allowed the preparation several highly unusual species such as the hexateflates M(OTeF5)6 (in which M = As, Sb, Bi). Xenon forms the cation Xe(OTeF5)+. [3]

Related Research Articles

<span class="mw-page-title-main">Tellurium</span> Chemical element, symbol Te and atomic number 52

Tellurium is a chemical element; it has symbol Te and atomic number 52. It is a brittle, mildly toxic, rare, silver-white metalloid. Tellurium is chemically related to selenium and sulfur, all three of which are chalcogens. It is occasionally found in its native form as elemental crystals. Tellurium is far more common in the Universe as a whole than on Earth. Its extreme rarity in the Earth's crust, comparable to that of platinum, is due partly to its formation of a volatile hydride that caused tellurium to be lost to space as a gas during the hot nebular formation of Earth.

In chemistry, the oxidation state, or oxidation number, is the hypothetical charge of an atom if all of its bonds to other atoms were fully ionic. It describes the degree of oxidation of an atom in a chemical compound. Conceptually, the oxidation state may be positive, negative or zero. While fully ionic bonds are not found in nature, many bonds exhibit strong ionicity, making oxidation state a useful predictor of charge.

In chemistry, noble gas compounds are chemical compounds that include an element from the noble gases, group 18 of the periodic table. Although the noble gases are generally unreactive elements, many such compounds have been observed, particularly involving the element xenon.

<span class="mw-page-title-main">Tellurate</span> Compound containing an oxyanion of tellurium

In chemistry tellurate is a compound containing an oxyanion of tellurium where tellurium has an oxidation number of +6. In the naming of inorganic compounds it is a suffix that indicates a polyatomic anion with a central tellurium atom.

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<span class="mw-page-title-main">Fluoroantimonic acid</span> Chemical compound

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<span class="mw-page-title-main">Selenium tetrafluoride</span> Chemical compound

Selenium tetrafluoride (SeF4) is an inorganic compound. It is a colourless liquid that reacts readily with water. It can be used as a fluorinating reagent in organic syntheses (fluorination of alcohols, carboxylic acids or carbonyl compounds) and has advantages over sulfur tetrafluoride in that milder conditions can be employed and it is a liquid rather than a gas.

<span class="mw-page-title-main">Fluoroboric acid</span> Chemical compound

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Barium ferrate is the chemical compound of formula BaFeO4. This is a rare compound containing iron in the +6 oxidation state. The ferrate(VI) ion has two unpaired electrons, making it paramagnetic. It is isostructural with BaSO4, and contains the tetrahedral [FeO4]2− anion.

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<span class="mw-page-title-main">Tetrafluoroammonium</span> Chemical compound

The tetrafluoroammonium cation is a positively charged polyatomic ion with chemical formula NF+
4
. It is equivalent to the ammonium ion where the hydrogen atoms surrounding the central nitrogen atom have been replaced by fluorine. Tetrafluoroammonium ion is isoelectronic with tetrafluoromethane CF
4
, trifluoramine oxide ONF
3
and the tetrafluoroborate BF
4
anion.

<span class="mw-page-title-main">Bismuth pentafluoride</span> Chemical compound

Bismuth pentafluoride is an inorganic compound with the formula BiF5. It is a white solid that is highly reactive. The compound is of interest to researchers but not of particular value.

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References

  1. Engelbrecht, A.; Sladky, F. "Pentafluoro-orthotellursaure, HOTeF5" Angewandte Chemie1964. 76(9), 379-380, doi : 10.1002/ange.19640760912.
  2. 1 2 Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. ISBN   0-12-352651-5.
  3. Mercier, H. P.A.; Sanders, J. C. P.; Schrobilgen, G. J. "The Hexakis(pentafluorooxotellurato)pnictate(V) Anions, M(OTeF5)6 (M = As, Sb, Bi): A Series of Very Weakly Coordinating Anions" Journal of the American Chemical Society, volume 116, 2921, (1994). doi : 10.1021/ja00086a025.

Further reading