Teflic acid

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Teflic acid
Teflic acid 2D full.svg
Space-filling model Teflic-acid-3D-spacefill.png
Space-filling model
Names
IUPAC name
Pentafluoroorthotelluric acid
Other names
Teflic acid
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.161.534 OOjs UI icon edit-ltr-progressive.svg
PubChem CID
  • InChI=1S/F5HOTe/c1-7(2,3,4,5)6/h6H Yes check.svgY
    Key: OAOSLENTGBMCNC-UHFFFAOYSA-N Yes check.svgY
  • InChI=1/F5HOTe/c1-7(2,3,4,5)6/h6H
    Key: OAOSLENTGBMCNC-UHFFFAOYAO
  • F[Te](F)(F)(F)(F)O
Properties
HOTeF5
Molar mass 239.60 g·mol−1
Appearancecolorless solid
Melting point 39.1 °C (102.4 °F; 312.2 K)
Boiling point 59.7 °C (139.5 °F; 332.8 K)
Acidity (pKa)8.8 (in Ac2O) [1]
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
corrosive, toxic
GHS labelling:
GHS-pictogram-acid.svg
Danger
H314
P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Yes check.svgY  verify  (what is  Yes check.svgYX mark.svgN ?)

Teflic acid is a chemical compound with the formula H O Te F 5. This strong acid is related to orthotelluric acid, Te(OH)6. Teflic acid has a slightly distorted octahedral molecular geometry.

Contents

Preparation

Teflic acid was accidentally discovered by Engelbrecht and Sladky. Their synthesis did not yield the anticipated telluryl fluoride TeO2F2, but a mixture of volatile telluric compounds, containing HOTeF5: [2]

BaTeO4 + 10 FSO2OH → HOTeF5 (25%)

Teflic acid can also be prepared from fluorosulfonic acid and barium tellurate: [3]

5 FSO2OH + Ba2+[TeO2(OH)4]2− → HOTeF5 + 4 H2SO4 + BaSO4

It is also the first hydrolysis product of tellurium hexafluoride:

TeF6 + H2O → HOTeF5 + HF

Teflates

Boron teflate Boron-teflate-3D-balls.png
Boron teflate

The conjugate base of teflic acid is called the teflate anion, F5TeO (not to be confused with triflate). Many teflates are known, one example being B(OTeF5)3, that can be pyrolysed to give acid anhydride O(TeF5)2. [3]

2 B(OTeF5)3 → 2 B(OTeF5)2F + O(TeF5)2

The teflate anion is known to resist oxidation. This property has allowed the preparation several highly unusual species such as the hexateflates M(OTeF5)6 (in which M = As, Sb, Bi). Xenon forms the cation Xe(OTeF5)+. [4]

Related Research Articles

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4
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4
, trifluoramine oxide ONF
3
, tetrafluoroborate BF
4
anion and the tetrafluoroberyllate BeF2−
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anion.

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References

  1. Perrin, D. D., ed. (1982) [1969]. Ionisation Constants of Inorganic Acids and Bases in Aqueous Solution. IUPAC Chemical Data (2nd ed.). Oxford: Pergamon (published 1984). Entry 220. ISBN   0-08-029214-3. LCCN   82-16524.
  2. Engelbrecht, A.; Sladky, F. "Pentafluoro-orthotellursaure, HOTeF5" Angewandte Chemie1964. 76(9), 379-380, doi : 10.1002/ange.19640760912.
  3. 1 2 Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. ISBN   0-12-352651-5.
  4. Mercier, H. P.A.; Sanders, J. C. P.; Schrobilgen, G. J. "The Hexakis(pentafluorooxotellurato)pnictate(V) Anions, M(OTeF5)6 (M = As, Sb, Bi): A Series of Very Weakly Coordinating Anions" Journal of the American Chemical Society, volume 116, 2921, (1994). doi : 10.1021/ja00086a025.

Further reading