Names | |||
---|---|---|---|
IUPAC name Pentafluoroorthotelluric acid | |||
Other names Teflic acid | |||
Identifiers | |||
3D model (JSmol) | |||
ChemSpider | |||
ECHA InfoCard | 100.161.534 | ||
PubChem CID | |||
CompTox Dashboard (EPA) | |||
| |||
| |||
Properties | |||
HOTeF5 | |||
Molar mass | 239.60 g·mol−1 | ||
Appearance | colorless solid | ||
Melting point | 39.1 °C (102.4 °F; 312.2 K) | ||
Boiling point | 59.7 °C (139.5 °F; 332.8 K) | ||
Acidity (pKa) | 8.8 (in Ac2O) [1] | ||
Hazards | |||
Occupational safety and health (OHS/OSH): | |||
Main hazards | corrosive, toxic | ||
GHS labelling: | |||
Danger | |||
H314 | |||
P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501 | |||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Teflic acid is a chemical compound with the formula H O Te F 5. This strong acid is related to orthotelluric acid, Te(OH)6. Teflic acid has a slightly distorted octahedral molecular geometry.
Teflic acid was accidentally discovered by Engelbrecht and Sladky. Their synthesis did not yield the anticipated telluryl fluoride TeO2F2, but a mixture of volatile telluric compounds, containing HOTeF5: [2]
Teflic acid can also be prepared from fluorosulfonic acid and barium tellurate: [3]
It is also the first hydrolysis product of tellurium hexafluoride:
The conjugate base of teflic acid is called the teflate anion, F5TeO− (not to be confused with triflate). Many teflates are known, one example being B(OTeF5)3, that can be pyrolysed to give acid anhydride O(TeF5)2. [3]
The teflate anion is known to resist oxidation. This property has allowed the preparation several highly unusual species such as the hexateflates M(OTeF5)−6 (in which M = As, Sb, Bi). Xenon forms the cation Xe(OTeF5)+. [4]
Tellurium is a chemical element; it has symbol Te and atomic number 52. It is a brittle, mildly toxic, rare, silver-white metalloid. Tellurium is chemically related to selenium and sulfur, all three of which are chalcogens. It is occasionally found in its native form as elemental crystals. Tellurium is far more common in the Universe as a whole than on Earth. Its extreme rarity in the Earth's crust, comparable to that of platinum, is due partly to its formation of a volatile hydride that caused tellurium to be lost to space as a gas during the hot nebular formation of Earth.
In chemistry, noble gas compounds are chemical compounds that include an element from the noble gases, group 18 of the periodic table. Although the noble gases are generally unreactive elements, many such compounds have been observed, particularly involving the element xenon.
In chemistry, tellurate is a compound containing an oxyanion of tellurium where tellurium has an oxidation number of +6. In the naming of inorganic compounds it is a suffix that indicates a polyatomic anion with a central tellurium atom.
An inorganic nonaqueous solvent is a solvent other than water, that is not an organic compound. These solvents are used in chemical research and industry for reactions that cannot occur in aqueous solutions or require a special environment. Inorganic nonaqueous solvents can be classified into two groups, protic solvents and aprotic solvents. Early studies on inorganic nonaqueous solvents evaluated ammonia, hydrogen fluoride, sulfuric acid, as well as more specialized solvents, hydrazine, and selenium oxychloride.
Antimony pentafluoride is the inorganic compound with the formula SbF5. This colourless, viscous liquid is a strong Lewis acid and a component of the superacid fluoroantimonic acid, formed upon mixing liquid HF with liquid SbF5 in 1:1 ratio. It is notable for its strong Lewis acidity and the ability to react with almost all known compounds.
Fluoroantimonic acid is a mixture of hydrogen fluoride and antimony pentafluoride, containing various cations and anions. This mixture is a superacid that, in terms of corrosiveness, is trillions of times stronger than pure sulfuric acid when measured by its Hammett acidity function. It even protonates some hydrocarbons to afford pentacoordinate carbocations. Like its precursor hydrogen fluoride, it attacks glass, but can be stored in containers lined with PTFE (Teflon) or PFA.
Selenium tetrafluoride (SeF4) is an inorganic compound. It is a colourless liquid that reacts readily with water. It can be used as a fluorinating reagent in organic syntheses (fluorination of alcohols, carboxylic acids or carbonyl compounds) and has advantages over sulfur tetrafluoride in that milder conditions can be employed and it is a liquid rather than a gas.
Tantalum(V) fluoride is the inorganic compound with the formula TaF5. It is one of the principal molecular compounds of tantalum. Characteristic of some other pentafluorides, the compound is volatile but exists as an oligomer in the solid state.
Fluoroboric acid or tetrafluoroboric acid is an inorganic compound with the simplified chemical formula H+[BF4]−. Solvent-free tetrafluoroboric acid has not been reported. The term "fluoroboric acid" usually refers to a range of compounds including hydronium tetrafluoroborate, which are available as solutions. The ethyl ether solvate is also commercially available, where the fluoroboric acid can be represented by the formula [H( 2O)n]+[BF4]−, where n is 2.
Barium ferrate is the chemical compound of formula BaFeO4. This is a rare compound containing iron in the +6 oxidation state. The ferrate(VI) ion has two unpaired electrons, making it paramagnetic. It is isostructural with BaSO4, and contains the tetrahedral [FeO4]2− anion.
Arsenic trifluoride is a chemical compound of arsenic and fluorine with the chemical formula AsF3. It is a colorless liquid which reacts readily with water. Like other inorganic arsenic compounds, it is highly toxic.
The tetrafluoroammonium cation is a positively charged polyatomic ion with chemical formula NF+
4. It is equivalent to the ammonium ion where the hydrogen atoms surrounding the central nitrogen atom have been replaced by fluorine. Tetrafluoroammonium ion is isoelectronic with tetrafluoromethane CF
4, trifluoramine oxide ONF
3, tetrafluoroborate BF−
4 anion and the tetrafluoroberyllate BeF2−
4 anion.
Bismuth pentafluoride is an inorganic compound with the formula BiF5. It is a white solid that is highly reactive. The compound is of interest to researchers but not of particular value.
Germanium tetrafluoride (GeF4) is a chemical compound of germanium and fluorine. It is a colorless gas.
In chemistry, molecular oxohalides (oxyhalides) are a group of chemical compounds in which both oxygen and halogen atoms are attached to another chemical element A in a single molecule. They have the general formula AOmXn, where X is a halogen. Known oxohalides have fluorine (F), chlorine (Cl), bromine (Br), and/or iodine (I) in their molecules. The element A may be a main group element, a transition element, a rare earth element or an actinide. The term oxohalide, or oxyhalide, may also refer to minerals and other crystalline substances with the same overall chemical formula, but having an ionic structure.
Difluorophosphate or difluorodioxophosphate or phosphorodifluoridate is an anion with formula PO2F−2. It has a single negative charge and resembles perchlorate and monofluorosulfonate in shape and compounds. These ions are isoelectronic, along with tetrafluoroaluminate, phosphate, orthosilicate, and sulfate. It forms a series of compounds. The ion is toxic to mammals as it causes blockage to iodine uptake in the thyroid. However it is degraded in the body over several hours.
Tellurium compounds are compounds containing the element tellurium (Te). Tellurium belongs to the chalcogen family of elements on the periodic table, which also includes oxygen, sulfur, selenium and polonium: Tellurium and selenium compounds are similar. Tellurium exhibits the oxidation states −2, +2, +4 and +6, with +4 being most common.
Mixed-anion compounds, heteroanionic materials or mixed-anion materials are chemical compounds containing cations and more than one kind of anion. The compounds contain a single phase, rather than just a mixture.
The borotellurates are heteropoly anion compounds which have tellurate groups attached to boron atoms. The ratio of tellurate to borate reflects the degree of condensation. In [TeO4(BO3)2]8- the anions are linked into a chain. In [TeO2(BO3)4]10− the structure is zero dimensional with isolated anions. These arrangements of oxygen around boron and tellurium can have forms resembling silicates. The first borotellurates to be discovered were the mixed sodium rare earth compounds in 2015.
A tellurite tellurate is chemical compound or salt that contains tellurite and tellurate anions [TeO3]2- [TeO4 ]2-. These are mixed anion compounds, meaning the compounds are cations that contain one or more anions. Some have third anions. Environmentally, tellurite [TeO3]2- is the more abundant anion due to tellurate's [TeO4 ]2- low solubility limiting its concentration in biospheric waters. Another way to refer to the anions is tellurium's oxyanions, which happen to be relatively stable.