Cerium oxalate

Last updated
Cerium oxalate
Cerium oxalate.svg
Cerium oxalate.jpg
Names
IUPAC name
Cerium(III) oxalate
Other names
  • Cerium oxalate
  • Cerous oxalate
Identifiers
  • 139-42-4 Yes check.svgY
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.004.875 OOjs UI icon edit-ltr-progressive.svg
PubChem CID
UNII
  • InChI=1S/3C2H2O4.2Ce/c3*3-1(4)2(5)6;;/h3*(H,3,4)(H,5,6);;/q;;;2*+3/p-6
    Key: ZMZNLKYXLARXFY-UHFFFAOYSA-H
  • C(=O)(C(=O)[O-])[O-].C(=O)(C(=O)[O-])[O-].C(=O)(C(=O)[O-])[O-].[Ce+3].[Ce+3]
Properties
C6Ce2O12
Molar mass 544.286 g·mol−1
AppearanceWhite crystals
Melting point Decomposes
Slightly soluble
Pharmacology
A04AD02 ( WHO )
Hazards
Main hazards Corrosive, Irritant, Respiratory irritant, Toxic
Safety data sheet External SDS
GHS pictograms GHS-pictogram-acid.svg GHS-pictogram-skull.svg GHS-pictogram-silhouette.svg [1]
GHS Signal word Danger [1]
H301, H311, H314, H319, H331, H335, H370 [1]
P260, P264, P270, P271, P280, P301+P310, P302+P352, P304+P340, P305+P351+P338, P308+P313, P332+P313, P403+P233 [1]
NFPA 704 (fire diamond)
3
0
1
Flash point 188.8 °C
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Yes check.svgY  verify  (what is  Yes check.svgYX mark.svgN ?)
Infobox references

Cerium(III) oxalate (cerous oxalate) is the inorganic cerium salt of oxalic acid. It is a white crystalline solid with the chemical formula of Ce2(C2O4)3. It could be obtained by the reaction of oxalic acid with cerium(III) chloride.

Contents

Uses

Cerium(III) oxalate is used as an antiemetic. [2] [3] It has been identified as part of the invisible ink that was used by Stasi operatives during the Cold War. [4]

Toxicity

Cerium(III) oxalate irritates skin and mucous membranes, and is a strong irritant to eyes. If it gets into the eyes, there is a danger of severe eye injury.

Cerium salts increase the blood coagulation rate, and exposure to cerium salts can cause sensitivity to heat.

Oxalates are corrosive to tissue and are powerful irritants. They have a caustic effect on the linings of the digestive tracts and can cause kidney damage.

Related Research Articles

Rhubarb Species of herbaceous perennial plant with fleshy, sour edible stalks

Rhubarb is the fleshy, edible stalks (petioles) of species and hybrids of Rheum in the family Polygonaceae, which are cooked and used for food. The whole plant – a herbaceous perennial growing from short, thick rhizomes – is also called rhubarb. Historically, different plants have been called "rhubarb" in English. The large, triangular leaves contain high levels of oxalic acid and anthrone glycosides, making them inedible. The small flowers are grouped in large compound leafy greenish-white to rose-red inflorescences.

Invisible ink

Invisible ink, also known as security ink or sympathetic ink, is a substance used for writing, which is invisible either on application or soon thereafter, and can later be made visible by some means. Invisible ink is one form of steganography.

Calcium oxalate Calcium compound

Calcium oxalate (in archaic terminology, oxalate of lime) is a calcium salt of oxalate with the chemical formula CaC2O4·(H2O)x, where x varies from 0 to 3. All forms are colorless or white. The monohydrate occurs naturally as the mineral whewellite, forming envelope-shaped crystals, known in plants as raphides. The rarer dihydrate (mineral: weddellite) and trihydrate (mineral: caoxite) are also recognized.

Oxalic acid Simplest dicarboxylic acid

Oxalic acid is an organic acid with the IUPAC name ethanedioic acid and formula HO2C−CO2H. It is the simplest dicarboxylic acid. It is a white crystalline solid that forms a colorless solution in water. Its name comes from the fact that early investigators isolated oxalic acid from flowering plants of the genus Oxalis, commonly known as wood-sorrels. It occurs naturally in many foods, but excessive ingestion of oxalic acid or prolonged skin contact can be dangerous.

Oxalate Any derivative of oxalic acid; chemical compound containing oxalate moiety

Oxalate (IUPAC: ethanedioate) is a compound found in some foods, which when consumed exits the body through the urine. Excess consumption has been linked to gout and kidney stones. Many metal ions form insoluble precipitates with oxalate, a prominent example being calcium oxalate, the primary constituent of the most common kind of kidney stones. Several plant foods such as the root and/or leaves of spinach, rhubarb, and buckwheat are high in oxalic acid and can contribute to the formation of kidney stones in some individuals. Chemically, oxalate is a dianion with the formula C
2
O2−
4
, also written (COO)2−
2
. Either name is often used for derivatives, such as salts of oxalic acid, for example sodium oxalate Na2C2O4, or dimethyl oxalate ((CH3)2C2O4). Oxalate also forms coordination compounds where it is sometimes abbreviated as ox.

Sodium oxalate Chemical compound

Sodium oxalate, or disodium oxalate, is the sodium salt of oxalic acid with the formula Na2C2O4. It is a white, crystalline, odorless solid, that decomposes above 290 °C.

Glyoxylic acid Chemical compound

Glyoxylic acid or oxoacetic acid is an organic compound. Together with acetic acid, glycolic acid, and oxalic acid, glyoxylic acid is one of the C2 carboxylic acids. It is a colourless solid that occurs naturally and is useful industrially.

Americium dioxide (AmO2) is a black compound of americium. In the solid state AmO2 adopts the fluorite, CaF2 structure. It is used as a source of alpha particles.

Barium oxalate Chemical compound

Barium oxalate (BaC2O4), a barium salt of oxalic acid, is a white odorless powder that is sometimes used as a green pyrotechnic colorant generally in specialized pyrotechnic compositions containing magnesium metal powder. Flame color is rich and vivid without additional chlorine donors. Such compositions burn rate is satisfied without commonly used oxidizers as nitrates, chlorates and perchlorates.

Potassium ferrioxalate Chemical compound

Potassium ferrioxalate, also called potassium trisoxalatoferrate or potassium tris(oxalato)ferrate(III) is a chemical compound with the formula K
3
[Fe(C
2
O
4
)
3
]. It often occurs as the trihydrate K3[Fe(C2O4)3]·3H2O. Both are crystalline compounds, lime green in colour.

Barium bromide Chemical compound

Barium bromide is the chemical compound with the formula BaBr2. Like barium chloride, it dissolves well in water and is toxic.

Cerium Chemical element, symbol Ce and atomic number 58

Cerium is a chemical element with the symbol Ce and atomic number 58. Cerium is a soft, ductile, and silvery-white metal that tarnishes when exposed to air, and it is soft enough to be cut with a steel kitchen knife. Cerium is the second element in the lanthanide series, and while it often shows the +3 oxidation state characteristic of the series, it also has a stable +4 state that does not oxidize water. It is also considered one of the rare-earth elements. Cerium has no biological role in humans and is not very toxic.

Potassium hydrogenoxalate Chemical compound

Potassium hydrogenoxalate is a salt with formula KHC2O4 or K+·HO2C-CO2. It is one of the most common salts of the hydrogenoxalate anion, and can be obtained by reacting potassium hydroxide with oxalic acid in 1:1 mole ratio.

Thorium oxalate Chemical compound

Thorium oxalate is the inorganic compound with the formula Th(C2O4)2(H2O)4. It is a white insoluble solid prepared by the reaction of thorium(IV) salts with an oxalic acid. The material is a coordination polymer. Each Th(IV) center is bound to 10 oxygen centers: eight provided by the bridging oxalates and two by a pair of aquo ligands. Two additional water of hydration are observed in the lattice.

Sodium hydrogenoxalate Partly deprotonated oxalic acid

Sodium hydrogenoxalate is salt of formula NaHC
2
O
4
, consisting of sodium cations Na+
and hydrogenoxalate anions HC
2
O
4
or -. The anion can be described as the result of removing one hydrogen ion H+
from oxalic acid H
2
C
2
O
4
, or adding one to the oxalate cation C
2
O2+
4
.

Americium(III) hydroxide is a radioactive inorganic compound with the chemical formula Am(OH)3. It consists of one americium atom and three hydroxide groups. It was first discovered in 1944, closely related to the Manhattan Project. However, these results were confidential and were only released to the public in 1945. It was the first isolated sample of americium, and the first americium compound discovered.

Praseodymium oxalate is an inorganic compound, a salt of praseodymium metal and oxalic acid with the chemical formula C6O12Pr2. The compound forms light green crystals, insoluble in water, also forms crystalline hydrates.

Copper oxalate Chemical compound

Copper oxalate is an inorganic compound, a salt of copper metal and oxalic acid with the chemical formula CuC
2
O
4
. The compound is practically insoluble in water, alcohol, ether, and acetic acid but soluble in ammonium hydroxide. Copper oxalate forms a hydrate, which forms acid-blue crystals.

Yttrium oxalate Chemical compound

Yttrium oxalate is an inorganic compound, a salt of yttrium and oxalic acid with the chemical formula Y2(C2O4)3. The compound does not dissolve in water and forms crystalline hydrates—colorless crystals.

Samarium(III) oxalate is an inorganic compound, a salt of samarium and oxalic acid with the formula Sm2(C2O4)3. The compound does not dissolve in water, forms a crystalline hydrate with yellow crystals.

References

  1. 1 2 3 4 "Cerium(III) Oxalate, Anhydrous". American Elements . Retrieved 2019-03-26.
  2. "KEGG DRUG: Cerium oxalate". KEGG DRUG Database. Retrieved 2019-03-26.
  3. Milne, G. W. A. (2017-11-01). Drugs: Synonyms and Properties: Synonyms and Properties. ISBN   9781351755092.
  4. "Cold War Invisible Ink Secrets Unlocked". ScienceDaily. 2006-11-08.