Zinc perchlorate

Last updated
Zinc perchlorate
Zinc(II) perchlorate.svg
Zinc perchlorate hexahydrate.jpg
Names
Other names
Zinc diperchlorate, zinc(II) perchlorate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.733 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 237-122-0
PubChem CID
UNII
  • InChI=1S/2ClHO4.Zn/c2*2-1(3,4)5;/h2*(H,2,3,4,5);/q;;+2/p-2
    Key: RXBXBWBHKPGHIB-UHFFFAOYSA-L
  • [O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Zn+2]
Properties
Cl
2
O
8
Zn
Molar mass 261.826
Appearancecolorless solid
Density 2.252 g/cm–3
Melting point 106 °C (223 °F; 379 K)
Boiling point 210 °C (410 °F; 483 K)
soluble
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Zinc perchlorate is the inorganic compound with the chemical formula Cl
2
O
8
Zn
. [1] [2]

Contents

Synthesis

Zinc perchlorate can be prepared by dissolving zinc oxide or zinc carbonate in perchloric acid: [3]

Chemical properties

The compound decomposes when heated to high temperatures and may explode if heated too strongly.

Like most other perchlorates such as copper perchlorate and lead perchlorate, zinc perchlorate is prone to deliquescence.

Zinc perchlorate can form complexes with ligands such as 8-aminoquinoline, tricarbohydrazide, and tetraphenylethylene tetratriazole. [4]

Physical properties

The compound forms a hexahydrate Zn(ClO
4
)
2
·6H
2
O
. [5] [6]

Zinc perchlorate forms a hygroscopic colorless solid, odorless, soluble in water and low-weight alcohols.

Uses

Zinc perchlorate is used as an oxidizing agent and catalyst.

Related Research Articles

<span class="mw-page-title-main">Ammonium</span> Polyatomic ion (NH₄, charge +1)

The ammonium cation is a positively-charged polyatomic ion with the chemical formula NH+4 or [NH4]+. It is formed by the protonation of ammonia. Ammonium is also a general name for positively charged or protonated substituted amines and quaternary ammonium cations, where one or more hydrogen atoms are replaced by organic groups.

In chemistry, an amphoteric compound is a molecule or ion that can react both as an acid and as a base. What exactly this can mean depends on which definitions of acids and bases are being used.

Silane is an inorganic compound with chemical formula, SiH4. It is a colourless, pyrophoric, toxic gas with a sharp, repulsive smell, somewhat similar to that of acetic acid. Silane is of practical interest as a precursor to elemental silicon. Silane with alkyl groups are effective water repellents for mineral surfaces such as concrete and masonry. Silanes with both organic and inorganic attachments are used as coupling agents.

<span class="mw-page-title-main">Potassium chlorate</span> Chemical compound

Potassium chlorate is a compound containing potassium, chlorine and oxygen, with the molecular formula KClO3. In its pure form, it is a white crystalline substance. After sodium chlorate, it is the second most common chlorate in industrial use. It is a strong oxidizing agent and its most important application is in safety matches. In other applications it is mostly obsolete and has been replaced by safer alternatives in recent decades. It has been used

<span class="mw-page-title-main">Zinc chloride</span> Chemical compound

Zinc chloride is the name of inorganic chemical compounds with the formula ZnCl2 and its hydrates. Zinc chlorides, of which nine crystalline forms are known, are colorless or white, and are highly soluble in water. This salt is hygroscopic and even deliquescent. Zinc chloride finds wide application in textile processing, metallurgical fluxes, and chemical synthesis. No mineral with this chemical composition is known aside from the very rare mineral simonkolleite, Zn5(OH)8Cl2·H2O.

In chemistry, water(s) of crystallization or water(s) of hydration are water molecules that are present inside crystals. Water is often incorporated in the formation of crystals from aqueous solutions. In some contexts, water of crystallization is the total mass of water in a substance at a given temperature and is mostly present in a definite (stoichiometric) ratio. Classically, "water of crystallization" refers to water that is found in the crystalline framework of a metal complex or a salt, which is not directly bonded to the metal cation.

<span class="mw-page-title-main">Aluminium chloride</span> Chemical compound

Aluminium chloride, also known as aluminium trichloride, is an inorganic compound with the formula AlCl3. It forms hexahydrate with the formula [Al(H2O)6]Cl3, containing six water molecules of hydration. Both are colourless crystals, but samples are often contaminated with iron(III) chloride, giving a yellow color.

<span class="mw-page-title-main">Cobalt(II) chloride</span> Chemical compound

Cobalt(II) chloride is an inorganic compound of cobalt and chlorine, with the formula CoCl
2
. The compound forms several hydrates CoCl
2
·nH
2
O
, for n = 1, 2, 6, and 9. Claims of the formation of tri- and tetrahydrates have not been confirmed. The anhydrous form is a blue crystalline solid; the dihydrate is purple and the hexahydrate is pink. Commercial samples are usually the hexahydrate, which is one of the most commonly used cobalt compounds in the lab.

<span class="mw-page-title-main">Single displacement reaction</span> Type of chemical reaction

A single-displacement reaction, also known as single replacement reaction or exchange reaction, is a chemical reaction in which one element is replaced by another in a compound.

<span class="mw-page-title-main">Chromium(III) chloride</span> Chemical compound

Chromium(III) chloride (also called chromic chloride) describes any of several chemical compounds with the formula CrCl3 · xH2O, where x can be 0, 5, and 6. The anhydrous compound with the formula CrCl3 is a violet solid. The most common form of the trichloride is the dark green hexahydrate, CrCl3 · 6 H2O. Chromium chlorides find use as catalysts and as precursors to dyes for wool.

<span class="mw-page-title-main">Nickel(II) chloride</span> Chemical compound

Nickel(II) chloride (or just nickel chloride) is the chemical compound NiCl2. The anhydrous salt is yellow, but the more familiar hydrate NiCl2·6H2O is green. Nickel(II) chloride, in various forms, is the most important source of nickel for chemical synthesis. The nickel chlorides are deliquescent, absorbing moisture from the air to form a solution. Nickel salts have been shown to be carcinogenic to the lungs and nasal passages in cases of long-term inhalation exposure.

<span class="mw-page-title-main">Thionyl chloride</span> Inorganic compound (SOCl2)

Thionyl chloride is an inorganic compound with the chemical formula SOCl2. It is a moderately volatile, colourless liquid with an unpleasant acrid odour. Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes per year being produced during the early 1990s, but is occasionally also used as a solvent. It is toxic, reacts with water, and is also listed under the Chemical Weapons Convention as it may be used for the production of chemical weapons.

<span class="mw-page-title-main">Fluorine perchlorate</span> Chemical compound

Fluorine perchlorate, also called perchloryl hypofluorite is the rarely encountered chemical compound of fluorine, chlorine, and oxygen with the chemical formula ClO
4
F
or FOClO
3
. It is an extremely unstable gas that explodes spontaneously and has a penetrating odor.

Zinc compounds are chemical compounds containing the element zinc which is a member of the group 12 of the periodic table. The oxidation state of zinc in most compounds is the group oxidation state of +2. Zinc may be classified as a post-transition main group element with zinc(II). Zinc compounds are noteworthy for their nondescript behavior, they are generally colorless, do not readily engage in redox reactions, and generally adopt symmetrical structures.

<span class="mw-page-title-main">Nickel oxyacid salts</span>

The Nickel oxyacid salts are a class of chemical compounds of nickel with an oxyacid. The compounds include a number of minerals and industrially important nickel compounds.

<span class="mw-page-title-main">Rhodium(III) perchlorate</span> Chemical compound

Rhodium(III) perchlorate refers to the inorganic compound with the formula Rh(H2O)6(ClO4)3. It is a hygroscopic yellow solid. It is the perchlorate salt of the tricationic aquo complex [Rh(H2O)6]3+. The compound is prepared by treating hydrated rhodium(III) chloride and perchloric acid at elevated temperatures:

<span class="mw-page-title-main">Chromium(II) sulfide</span> Chemical compound

Chromium(II) sulfide is an inorganic compound of chromium and sulfur with the chemical formula CrS. The compound forms black hexagonal crystals, insoluble in water.

<span class="mw-page-title-main">Chromium(III) perchlorate</span> Chemical compound

Chromium(III) perchlorate is an inorganic compound with the chemical formula Cr(ClO4)3. It's hexahydrate Cr(ClO4)3·6H2O is a cyan solid that dissolves in water.

<span class="mw-page-title-main">Nickel(II) perchlorate</span> Compound of nickel

Nickel(II) perchlorate is a inorganic compound with the chemical formula of Ni(ClO4)2, and it is a strong oxidizing agent. Its colours are different depending on water. For example, the hydrate forms cyan crystals, the pentahydrate forms green crystals, but the hexahydrate (Ni(ClO4)2·6H2O) forms blue crystals.

<span class="mw-page-title-main">Indium perchlorate</span> Chemical compound

Indium perchlorate is the inorganic compound with the chemical formula In(ClO
4
)
3
. The compound is an indium salt of perchloric acid.

References

  1. Kumar, Raj; Thilagavathi, Ramasamy; Gulhane, Rajesh; Chakraborti, Asit K. (2 May 2006). "Zinc(II) perchlorate as a new and highly efficient catalyst for formation of aldehyde 1,1-diacetate at room temperature and under solvent-free conditions". Journal of Molecular Catalysis A: Chemical. 250 (1): 226–231. doi:10.1016/j.molcata.2006.01.063. ISSN   1381-1169 . Retrieved 14 March 2023.
  2. Advances in Inorganic Chemistry. Academic Press. 5 December 1984. p. 283. ISBN   978-0-08-057877-4 . Retrieved 14 March 2023.
  3. Lin, Lili; Liu, Xiaohua; Feng, Xiaoming (27 May 2014). "Zinc(II) Perchlorate Hexahydrate". Encyclopedia of Reagents for Organic Synthesis: 1–5. doi:10.1002/047084289X.rn01657. ISBN   9780470842898 . Retrieved 14 March 2023.
  4. "8-aminoquinoline zinc perchlorate metal complex, and preparation method and application thereof". 30 April 2014. Retrieved 14 March 2023.
  5. "Zinc Perchlorate Hexahydrate". American Elements . Retrieved 14 March 2023.
  6. "Zinc perchlorate hexahydrate". Sigma Aldrich . Retrieved 14 March 2023.
HClO4 He
LiClO4 Be(ClO4)2 B(ClO4)4
B(ClO4)3
ROClO3 N(ClO4)3
NH4ClO4
NOClO4
H3OClO4 FClO4 Ne
NaClO4 Mg(ClO4)2 Al(ClO4)3
Al(ClO4)4
Al(ClO4)2−5
Al(ClO4)3−6
SiPS ClO4
ClOClO3
Cl2O7
Ar
KClO4 Ca(ClO4)2 Sc(ClO4)3 Ti(ClO4)4 VO(ClO4)3
VO2(ClO4)
Cr(ClO4)3 Mn(ClO4)2 Fe(ClO4)2
Fe(ClO4)3
Co(ClO4)2,
Co(ClO4)3
Ni(ClO4)2 Cu(ClO4)2 Zn(ClO4)2 Ga(ClO4)3 GeAsSeBrKr
RbClO4 Sr(ClO4)2 Y(ClO4)3 Zr(ClO4)4 Nb(ClO4)5 MoTcRu Rh(ClO4)3 Pd(ClO4)2 AgClO4 Cd(ClO4)2 In(ClO4)3 Sn(ClO4)4 Sb TeO(ClO4)2 IXe
CsClO4 Ba(ClO4)2   Lu(ClO4)3 Hf(ClO4)4 Ta(ClO4)5
TaO(ClO4)3
TaO2ClO4
WReOsIrPtAu Hg2(ClO4)2,
Hg(ClO4)2
Tl(ClO4),
Tl(ClO4)3
Pb(ClO4)2 Bi(ClO4)3 PoAtRn
FrClO4 Ra LrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg
La Ce(ClO4)x Pr(ClO4)3 Nd(ClO4)3 Pm Sm(ClO4)3 Eu(ClO4)3 Gd(ClO4)3 Tb(ClO4)3 Dy(ClO4)3 Ho(ClO4)3 Er(ClO4)3 Tm(ClO4)3 Yb(ClO4)3
Ac Th(ClO4)4 Pa UO2(ClO4)2 NpPuAmCmBkCfEsFmMdNo