Indium perchlorate

Last updated
Indium perchlorate
Indium(III) perchlorate.svg
Names
Other names
Indium triperchlorate, indium(III) perchlorate
Identifiers
3D model (JSmol)
ECHA InfoCard 100.033.507 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 236-874-7
PubChem CID
  • InChI=1S/3ClHO4.In/c3*2-1(3,4)5;/h3*(H,2,3,4,5);/q;;;+3/p-3
    Key: TWFKOYFJBHUHCH-UHFFFAOYSA-K
  • [O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[In+3]
Properties
In(ClO
4
)
3
Molar mass 413.17
Appearancecolorless crystals
soluble
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Oxidizer
Related compounds
Other anions
indium nitrate, indium sulfate
Other cations
aluminum perchlorate, gallium perchlorate, thallium perchlorate
Related compounds
indium(I) perchlorate, indium chlorate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Indium perchlorate is the inorganic compound with the chemical formula In(ClO
4
)
3
. [1] The compound is an indium salt of perchloric acid. [2] [3]

Contents

Synthesis

Dissolving indium hydroxide in perchloric acid:

Physical properties

Indium(III) perchlorate forms colorless crystals. It is soluble in water and ethanol.

The compound forms a crystallohydrate In(ClO
4
)
3
•8H
2
O
, that melts in its own crystallization water at 80 °C. [4]

The octahydrate is easily soluble in ethanol and acetic acid.

Related Research Articles

<span class="mw-page-title-main">Ammonium perchlorate</span> Chemical compound

Ammonium perchlorate ("AP") is an inorganic compound with the formula NH4ClO4. It is a colorless or white solid that is soluble in water. It is a powerful oxidizer. Combined with a fuel, it can be used as a rocket propellant called ammonium perchlorate composite propellant. Its instability has involved it in a number of accidents, such as the PEPCON disaster.

<span class="mw-page-title-main">Perchloric acid</span> Chemical compound

Perchloric acid is a mineral acid with the formula HClO4. Usually found as an aqueous solution, this colorless compound is a stronger acid than sulfuric acid, nitric acid and hydrochloric acid. It is a powerful oxidizer when hot, but aqueous solutions up to approximately 70% by weight at room temperature are generally safe, only showing strong acid features and no oxidizing properties. Perchloric acid is useful for preparing perchlorate salts, especially ammonium perchlorate, an important rocket fuel component. Perchloric acid is dangerously corrosive and readily forms potentially explosive mixtures.

<span class="mw-page-title-main">Hydrazoic acid</span> Unstable and toxic chemical compound

Hydrazoic acid, also known as hydrogen azide or azoimide, is a compound with the chemical formula HN3. It is a colorless, volatile, and explosive liquid at room temperature and pressure. It is a compound of nitrogen and hydrogen, and is therefore a pnictogen hydride. It was first isolated in 1890 by Theodor Curtius. The acid has few applications, but its conjugate base, the azide ion, is useful in specialized processes.

<span class="mw-page-title-main">Dichlorine heptoxide</span> Chemical compound

Dichlorine heptoxide is the chemical compound with the formula Cl2O7. This chlorine oxide is the anhydride of perchloric acid. It is produced by the careful distillation of perchloric acid in the presence of the dehydrating agent phosphorus pentoxide:

<span class="mw-page-title-main">Sodium perchlorate</span> Chemical compound

Sodium perchlorate is the inorganic compound with the chemical formula NaClO4. It is a white crystalline, hygroscopic solid that is highly soluble in water and in alcohol. It is usually encountered as the monohydrate. The compound is noteworthy as the most water-soluble of the common perchlorate salts.

An oxyacid, oxoacid, or ternary acid is an acid that contains oxygen. Specifically, it is a compound that contains hydrogen, oxygen, and at least one other element, with at least one hydrogen atom bonded to oxygen that can dissociate to produce the H+ cation and the anion of the acid.

<span class="mw-page-title-main">Iron(III) oxide-hydroxide</span> Hydrous ferric oxide (HFO)

Iron(III) oxide-hydroxide or ferric oxyhydroxide is the chemical compound of iron, oxygen, and hydrogen with formula FeO(OH).

A solubility chart is a chart describing whether the ionic compounds formed from different combinations of cations and anions dissolve in or precipitate from solution.

<span class="mw-page-title-main">Fluorine perchlorate</span> Chemical compound

Fluorine perchlorate, also called perchloryl hypofluorite is the rarely encountered chemical compound of fluorine, chlorine, and oxygen with the chemical formula ClO
4
F
or FOClO
3
. It is an extremely unstable gas that explodes spontaneously and has a penetrating odor.

Barium perchlorate is a powerful oxidizing agent, with the formula Ba(ClO4)2. It is used in the pyrotechnic industry.

Germanium(II) hydroxide, normally written as Ge(OH)2, is a poorly characterised compound, sometimes called hydrous germanium(II) oxide or germanous hydroxide. It was first reported by Winkler in 1886.

<span class="mw-page-title-main">Vanadyl perchlorate</span> Chemical compound

Vanadyl perchlorate or vanadyl triperchlorate is a golden yellow coloured liquid or crystalline compound of vanadium, oxygen and perchlorate group. The substance consists of molecules covalently bound and is quite volatile.

<span class="mw-page-title-main">Rhodium(III) perchlorate</span> Chemical compound

Rhodium(III) perchlorate refers to the inorganic compound with the formula Rh(H2O)6(ClO4)3. It is a hygroscopic yellow solid. It is the perchlorate salt of the tricationic aquo complex [Rh(H2O)6]3+. The compound is prepared by treating hydrated rhodium(III) chloride and perchloric acid at elevated temperatures:

<span class="mw-page-title-main">Chromium(III) perchlorate</span> Chemical compound

Chromium(III) perchlorate is an inorganic compound with the chemical formula Cr(ClO4)3. It's hexahydrate Cr(ClO4)3·6H2O is a cyan solid that dissolves in water.

<span class="mw-page-title-main">Nickel(II) perchlorate</span> Compound of nickel

Nickel(II) perchlorate is a inorganic compound with the chemical formula of Ni(ClO4)2, and it is a strong oxidizing agent. Its colours are different depending on water. For example, the hydrate forms cyan crystals, the pentahydrate forms green crystals, but the hexahydrate (Ni(ClO4)2·6H2O) forms blue crystals.

<span class="mw-page-title-main">Neodymium(III) perchlorate</span> Chemical compound

Neodymium(III) perchlorate is an inorganic compound. It is a salt of neodymium and perchloric acid with the chemical formula of Nd(ClO4)3 – it is soluble in water, forming purple-pink, hydrated crystals.

<span class="mw-page-title-main">Lead(II) perchlorate</span> Chemical compound

Lead(II) perchlorate is a chemical compound with the formula Pb(ClO4)2·xH2O, where is x is 0,1, or 3. It is an extremely hygroscopic white solid that is very soluble in water.

<span class="mw-page-title-main">Zinc perchlorate</span> Chemical compound

Zinc perchlorate is the inorganic compound with the chemical formula Zn(ClO4)2 which forms the hexahydrate.

<span class="mw-page-title-main">Yttrium perchlorate</span> Chemical compound

Yttrium perchlorate is the inorganic compound with the chemical formula Y(ClO
4
)
3
. The compound is an yttrium salt of perchloric acid.

Ruthenium(IV) tetrachloride is an inorganic compound, a metal salt of ruthenium and hydrochloric acid with the formula RuCl4. The compound forms brown crystals, dissolves in cold water, and creates a hydrate.

References

  1. Burgess, J. (31 October 2007). Inorganic Reaction Mechanisms: Volume 1. Royal Society of Chemistry. p. 110. ISBN   978-1-84755-648-6 . Retrieved 15 March 2023.
  2. "Indium Perchlorate". Russian Journal of Physical Chemistry. British Library Lending Division. 48, Part 3: 1611. 1974. Retrieved 15 March 2023.
  3. Eyring, Edward M.; Owen, Jeffrey D. (April 1970). "Kinetics of aqueous indium(III) perchlorate dimerization". The Journal of Physical Chemistry . 74 (9): 1825–1828. doi:10.1021/j100704a001.
  4. "Indium(III) perchlorate hydrate". Sigma Aldrich . Retrieved 15 March 2023.