Silver perchlorate

Silver perchlorate

Names
IUPAC name Silver(I) perchlorate
Systematic IUPAC name Silver(I) chlorate(VII)
Other names Perchloric acid, silver(1+) salt Argentous perchlorate
Identifiers
CAS Number	7783-93-9  Y 14242-05-8 (hydrate) N
3D model (JSmol)	Interactive image
ChemSpider	22968  Y
ECHA InfoCard	100.029.123
EC Number	232-035-4
PubChem CID	24562
UNII	SV4X1U113O  Y
CompTox Dashboard (EPA)	DTXSID40884427
InChI InChI=1S/Ag.ClHO4/c;2-1(3,4)5/h;(H,2,3,4,5)/q+1;/p-1 Y Key: YDHABVNRCBNRNZ-UHFFFAOYSA-M Y InChI=1/Ag.ClHO4/c;2-1(3,4)5/h;(H,2,3,4,5)/q+1;/p-1 Key: YDHABVNRCBNRNZ-REWHXWOFAI
SMILES [Ag+].[O-]Cl(=O)(=O)=O
Properties
Chemical formula	AgClO4
Molar mass	207.319 g/mol
Appearance	Colorless hygroscopic crystals
Density	2.806 g/cm3
Melting point	486 °C (907 °F; 759 K) (decomposes)
Solubility in water	557 g/100 mL (25 °C) 792.8 g/100 mL (99 °C)
Solubility	soluble in organic solvents
Structure
Crystal structure	cubic
Hazards
GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H272, H314
Precautionary statements	P210, P220, P221, P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P370+P378, P405, P501
NFPA 704 (fire diamond)	2 0 2 OX
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N  verify  (what is  YN ?) Infobox references

Silver perchlorate is the chemical compound with the formula AgClO₄. This white solid forms a monohydrate and is mildly deliquescent. It is a useful source of the Ag⁺ ion, although the presence of perchlorate presents risks. It is used as a catalyst in organic chemistry.

Production

Silver perchlorate is created by heating a mixture of perchloric acid with silver nitrate.

Alternatively, it can be prepared by the reaction between barium perchlorate and silver sulfate, or from the reaction of perchloric acid with silver oxide.

Solubility

Silver perchlorate is noteworthy for its solubility in aromatic solvents such as benzene (52.8 g/L) and toluene (1010 g/L). ^[1] In these solvents, the silver cation binds to the arene, as has been demonstrated by X-ray crystallographic studies on crystals obtained from such solutions. ^{[2] [3]} Its solubility in water is extremely high, up to 500 g per 100 mL water. X-ray diffraction experiments show that aqueous solutions contain [Ag(H₂O)₂]⁺ with Ag-O distances near 240 picometer. ^[4]

Related reagents

Similar to silver nitrate, silver perchlorate is an effective reagent for replacing halides ligands with perchlorate, which is a weakly or non-coordinating anion. The use of silver perchlorate in chemical synthesis has declined due to concerns about explosiveness of perchlorate salts. Other silver reagents are silver tetrafluoroborate, and the related silver trifluoromethanesulfonate and silver hexafluorophosphate.

References

1. F. Březina; J. Mollin; R. Pastorek; Z. Šindelář (1986). Chemické tabulky anorganických sloučenin[Chemical tables of inorganic compounds] (in Czech). Prague: SNTL.
2. E. A. Hall Griffith; E. L. Amma (1974). "Metal Ion-Aromatic Complexes. XVIII. Preparation and Molecular Structure of Naphthalene-Tetrakis(silver perchlorate) Tetrahydrate". Journal of the American Chemical Society. 96 (3): 743–749. doi:10.1021/ja00810a018.
3. R. K. McMullan; T. F. Koetzle; C. J. Fritchie Jr. (1997). "Low-Temperature Neutron Diffraction Study of the Silver Perchlorate–Benzene π Complex". Acta Crystallographica B. 53 (4): 645–653. Bibcode:1997AcCrB..53..645M. doi:10.1107/S0108768197000712. S2CID   97838907.
4. Masunobu Maeda; Yoshiteru Maegawa; Toshio Yamaguchi; Hitoshi Ohtaki (19 April 2006). "X-Ray Diffraction Studies on the Structures of Diammine- and Aquasilver(I) Complexes in Aqueous Solution". Bulletin of the Chemical Society of Japan. doi:10.1246/bcsj.52.2545.