Silver tungstate

Last updated
Silver tungstate
Names
IUPAC name
Disilver;dioxido(dioxo)tungsten
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.357 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 236-708-3
PubChem CID
  • InChI=1S/2Ag.4O.W/q2*+1;;;2*-1;
    Key: QEKREONBSFPWTQ-UHFFFAOYSA-N
  • [O-][W](=O)(=O)[O-].[Ag+].[Ag+]
Properties
Ag2WO4
Molar mass 463.57 g mol−1
Hazards
GHS labelling: [1]
GHS-pictogram-exclam.svg
Warning
H315, H319, H335
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Silver tungstate is an inorganic tungstate with the chemical formula Ag2WO4. It has been applied in various fields such as photoluminescence, antibacterial action, ozone gas sensors and humidity sensors. [2] [3] It is also used in the electronic and chemical industries, and also used in proteomics research. [4]

Contents

Phases

Silver tungstate occurs in three polymorphic phases: orthorhombic (α), hexagonal (β) and cubic (γ). [2] α-silver tungstate is thermodynamically stable, while β- and γ-silver tungstate are metastable. [5]

Synthesis

Silver tungstate is synthesised through the following reaction between silver nitrate and sodium tungstate, producing sodium nitrate as a byproduct: [2]

Related Research Articles

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<span class="mw-page-title-main">Scintillator</span> Type of material

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<span class="mw-page-title-main">Tollens' reagent</span> Chemical reagent used to distinguish between aldehydes and ketones

Tollens' reagent is a chemical reagent used to distinguish between aldehydes and ketones along with some alpha-hydroxy ketones which can tautomerize into aldehydes. The reagent consists of a solution of silver nitrate, ammonia and some sodium hydroxide. It was named after its discoverer, the German chemist Bernhard Tollens. A positive test with Tollens' reagent is indicated by the precipitation of elemental silver, often producing a characteristic "silver mirror" on the inner surface of the reaction vessel.

<span class="mw-page-title-main">Tungsten trioxide</span> Chemical compound

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<span class="mw-page-title-main">Calcium pyrophosphate</span> Chemical compound

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<span class="mw-page-title-main">Lattice constant</span> Physical dimensions of unit cells in a crystal

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<span class="mw-page-title-main">Disodium octaborate</span> Chemical compound

Disodium octaborate is a borate of sodium, a chemical compound of sodium, boron, and oxygen — a salt with elemental formula Na2B8O13 or (Na+)2[B8O13]2−, also written as Na2O·4B2O3. It is a transparent colorless crystalline solid, soluble in water.

<span class="mw-page-title-main">Sodium metaborate</span> Chemical compound

Sodium metaborate is a chemical compound of sodium, boron, and oxygen with formula NaBO
2
. However, the metaborate ion is trimeric in the anhydrous solid, therefore a more correct formula is Na3B3O6 or (Na+)3[B3O6]3−. The formula can be written also as Na
2
O
·B
2
O
3
to highlight the relation to the main oxides of sodium and boron. The name is also applied to several hydrates whose formulas can be written NaBO2·nH2O for various values of n.

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Ammonium fluorosilicate (also known as ammonium hexafluorosilicate, ammonium fluosilicate or ammonium silicofluoride) has the formula (NH4)2SiF6. It is a toxic chemical, like all salts of fluorosilicic acid. It is made of white crystals, which have at least three polymorphs and appears in nature as rare minerals cryptohalite or bararite.

Barium tungstate is an inorganic chemical compound of barium and the tungstate anion.

<span class="mw-page-title-main">Silver cyanate</span> Chemical compound

Silver cyanate is the cyanate salt of silver. It can be made by the reaction of potassium cyanate with silver nitrate in aqueous solution, from which it precipitates as a solid.

Silver hyponitrite is an ionic compound with formula Ag2N2O2 or (Ag+
)2[ON=NO]2−, containing monovalent silver cations and hyponitrite anions. It is a bright canary yellow solid practically insoluble in water and most organic solvents, including DMF and DMSO.

Indium(III) nitrate is a nitrate salt of indium. It reacts with sodium tungstate to form In(OH)WO4, [In(OH)2]2WO4, NaInWO4 or In2(WO4)3 depending on pH.

<span class="mw-page-title-main">Nickel tungstate</span> Chemical compound

Nickel tungstate is an inorganic compound of nickel, tungsten and oxygen, with the chemical formula of NiWO4.

References

  1. "C&L Inventory". echa.europa.eu.
  2. 1 2 3 Sreedevi, A.; Priyanka, K. P.; Babitha, K. K.; Aloysius Sabu, N.; Anu, T. S.; Varghese, T. (2015-09-01). "Chemical synthesis, structural characterization and optical properties of nanophase α-Ag2WO4". Indian Journal of Physics. 89 (9): 889–897. Bibcode:2015InJPh..89..889S. doi:10.1007/s12648-015-0664-1. ISSN   0974-9845. S2CID   122042870.
  3. De Santana, Yuri V. B.; Gomes, José Ernane Cardoso; Matos, Leandro; Cruvinel, Guilherme Henrique; Perrin, André; Perrin, Christiane; Andrès, Juan; Varela, José A.; Longo, Elson (2014-01-01). "Silver Molybdate and Silver Tungstate Nanocomposites with Enhanced Photoluminescence". Nanomaterials and Nanotechnology. 4: 22. doi:10.5772/58923. hdl: 10234/121786 . ISSN   1847-9804. S2CID   7415517.
  4. "13465-93-5 - Silver tungsten oxide, 99% (metals basis) - Silver tungstate - 39661 - Alfa Aesar". www.alfa.com. Retrieved 2022-08-29.
  5. Alvarez Roca, Roman; Lemos, Pablo S.; Gracia, Lourdes; Andrés, Juan; Longo, Elson (2016-10-03). "Uncovering the metastable γ-Ag2WO4 phase: a joint experimental and theoretical study". RSC Advances . 7 (10): 5610–5620. Bibcode:2017RSCAd...7.5610R. doi: 10.1039/C6RA24692C .