Names | |
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IUPAC name Disilver;dioxido(dioxo)tungsten | |
Identifiers | |
3D model (JSmol) | |
ChemSpider | |
ECHA InfoCard | 100.033.357 |
EC Number |
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PubChem CID | |
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Properties | |
Ag2WO4 | |
Molar mass | 463.57 g mol−1 |
Hazards | |
GHS labelling: [1] | |
Warning | |
H315, H319, H335 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Silver tungstate is an inorganic tungstate with the chemical formula Ag2WO4. It has been applied in various fields such as photoluminescence, antibacterial action, ozone gas sensors and humidity sensors. [2] [3] It is also used in the electronic and chemical industries, and also used in proteomics research. [4]
Silver tungstate occurs in three polymorphic phases: orthorhombic (α), hexagonal (β) and cubic (γ). [2] α-silver tungstate is thermodynamically stable, while β- and γ-silver tungstate are metastable. [5]
Silver tungstate is synthesised through the following reaction between silver nitrate and sodium tungstate, producing sodium nitrate as a byproduct: [2]
In a chemical reaction, chemical equilibrium is the state in which both the reactants and products are present in concentrations which have no further tendency to change with time, so that there is no observable change in the properties of the system. This state results when the forward reaction proceeds at the same rate as the reverse reaction. The reaction rates of the forward and backward reactions are generally not zero, but they are equal. Thus, there are no net changes in the concentrations of the reactants and products. Such a state is known as dynamic equilibrium.
Silver nitrate is an inorganic compound with chemical formula AgNO
3. It is a versatile precursor to many other silver compounds, such as those used in photography. It is far less sensitive to light than the halides. It was once called lunar caustic because silver was called luna by ancient alchemists who associated silver with the moon. In solid silver nitrate, the silver ions are three-coordinated in a trigonal planar arrangement.
In an aqueous solution, precipitation is the "sedimentation of a solid material from a liquid solution". The solid formed is called the precipitate. In case of an inorganic chemical reaction leading to precipitation, the chemical reagent causing the solid to form is called the precipitant.
Silver iodide is an inorganic compound with the formula AgI. The compound is a bright yellow solid, but samples almost always contain impurities of metallic silver that give a grey colouration. The silver contamination arises because some samples of AgI can be highly photosensitive. This property is exploited in silver-based photography. Silver iodide is also used as an antiseptic and in cloud seeding.
Copper(II) nitrate describes any member of the family of inorganic compounds with the formula Cu(NO3)2(H2O)x. The hydrates are blue solids. Anhydrous copper nitrate forms blue-green crystals and sublimes in a vacuum at 150-200 °C. Common hydrates are the hemipentahydrate and trihydrate.
Tollens' reagent is a chemical reagent used to distinguish between aldehydes and ketones along with some alpha-hydroxy ketones which can tautomerize into aldehydes. The reagent consists of a solution of silver nitrate, ammonium hydroxide and some sodium hydroxide. It was named after its discoverer, the German chemist Bernhard Tollens. A positive test with Tollens' reagent is indicated by the precipitation of elemental silver, often producing a characteristic "silver mirror" on the inner surface of the reaction vessel.
Calcium pyrophosphate (Ca2P2O7) is a chemical compound, an insoluble calcium salt containing the pyrophosphate anion. There are a number of forms reported: an anhydrous form, a dihydrate, Ca2P2O7·2H2O and a tetrahydrate, Ca2P2O7·4H2O. Deposition of dihydrate crystals in cartilage are responsible for the severe joint pain in cases of calcium pyrophosphate deposition disease (pseudo gout) whose symptoms are similar to those of gout. Ca2P2O7 is commonly used as a mild abrasive agent in toothpastes, because of its insolubility and nonreactivity toward fluoride.
Silver carbonate is the chemical compound with the formula Ag2CO3. This salt is yellow but typical samples are grayish due to the presence of elemental silver. It is poorly soluble in water, like most transition metal carbonates.
Silver azide is the chemical compound with the formula AgN3. It is a silver(I) salt of hydrazoic acid. It forms a colorless crystals. Like most azides, it is a primary explosive.
Silver molybdate (Ag2MoO4), a chemical compound, is a yellow, cubic crystalline substance often used in glass. Its crystals present two types of electronic structure, depending on the pressure conditions to which the crystal is subjected. At room temperature, Ag2MoO4 exhibits a spinel-type cubic structure, known as β-Ag2MoO4, which is more stable in nature. However, when exposed to high hydrostatic pressure, the tetragonal α-Ag2MoO4 forms as a metastable phase.
Sodium metaborate is a chemical compound of sodium, boron, and oxygen with formula NaBO2. However, the metaborate ion is trimeric in the anhydrous solid, therefore a more correct formula is Na3B3O6 or (Na+)3[B3O6]3−. The formula can be written also as Na2O·B2O3 to highlight the relation to the main oxides of sodium and boron. The name is also applied to several hydrates whose formulas can be written NaBO2·nH2O for various values of n.
Cadmium hydroxide is an inorganic compound with the formula Cd(OH)2. It is a white crystalline ionic compound that is a key component of nickel–cadmium battery.
Barium tungstate is an inorganic chemical compound of barium and the tungstate anion.
Silver cyanate is the cyanate salt of silver. It can be made by the reaction of potassium cyanate with silver nitrate in aqueous solution, from which it precipitates as a solid.
Silver nitrite is an inorganic compound with the formula AgNO2.
Indium(III) nitrate is a nitrate salt of indium which forms various hydrates. Only the pentahydrate has been crystallographically verified. Other hydrates are also reported in literature, such as the trihydrate.
Silver chlorite is a chemical compound with the formula AgClO2. This slightly yellow solid is shock sensitive and has an orthorhombic crystal structure.
Nickel tungstate is an inorganic compound of nickel, tungsten and oxygen, with the chemical formula of NiWO4.
Neodymium tungstate is an inorganic compound, a salt of neodymium and tungstic acid with the chemical formula Nd2(WO4)3. It forms hydrated light purple crystals that are slightly soluble in water.