Silver lactate

Last updated
Silver lactate
Silver lactate.svg
Names
Other names
silver; 1-hydroxy-1-oxopropan-2-olate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.036.221 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 239-859-3
PubChem CID
  • InChI=1S/C3H5O3.Ag/c1-2(4)3(5)6;/h2H,1H3,(H,5,6);/q-1;+1
    Key: CUPCAVOUAWGFEI-UHFFFAOYSA-N
  • [Ag+].[O-]C(C(=O)O)C
Properties
CH3CH(OH)COOAg
Molar mass 196.93 g/mol
AppearanceGray to purple powder or flakes
Melting point 120–122 °C (248–252 °F; 393–395 K)
Boiling point 227.6 °C (441.7 °F; 500.8 K)
Soluble
Hazards
GHS labelling:
GHS-pictogram-exclam.svg
Warning
H315, H319, H335
P302, P305, P338, P351, P352
NFPA 704 (fire diamond)
NFPA 704.svgHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 0: Will not burn. E.g. waterInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no code
2
0
1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Silver lactate is an organic chemical compound, a salt of silver and lactic acid [1] with the formula CH3CH(OH)COOAg. [2] [3]

Contents

Synthesis

Silver lactate can be made by the reaction of silver carbonate with lactic acid.

Physical properties

Silver lactate forms light gray crystals. [4]

Silver lactate is soluble in water, slightly soluble in ethanol.

Silver lactate forms a crystalline hydrate of composition CH3CH(OH)COOAg•H2O.

Silver lactate is a reagent for the precipitation of uric acid. [5]

Chemical properties

The compound reacts with triphenylphosphine gold chloride in a mixed solvent of benzene and dichloromethane to obtain colorless triphenylphosphine gold lactate. [6]

The compound reacts with a tetraphosphine ligand, dppbpda, to obtain a coordination polymer [(dppbpda)Ag4(CH3CH(OH)COO)4]n. [7]

Related Research Articles

<span class="mw-page-title-main">Carboxylic acid</span> Organic compound containing a –C(=O)OH group

In organic chemistry, a carboxylic acid is an organic acid that contains a carboxyl group attached to an R-group. The general formula of a carboxylic acid is often written as R−COOH or R−CO2H, sometimes as R−C(O)OH with R referring to an organyl group, or hydrogen, or other groups. Carboxylic acids occur widely. Important examples include the amino acids and fatty acids. Deprotonation of a carboxylic acid gives a carboxylate anion.

<span class="mw-page-title-main">Lactic acid</span> Organic acid

Lactic acid is an organic acid. It has the molecular formula C3H6O3. It is white in the solid state and it is miscible with water. When in the dissolved state, it forms a colorless solution. Production includes both artificial synthesis as well as natural sources. Lactic acid is an alpha-hydroxy acid (AHA) due to the presence of a hydroxyl group adjacent to the carboxyl group. It is used as a synthetic intermediate in many organic synthesis industries and in various biochemical industries. The conjugate base of lactic acid is called lactate (or the lactate anion). The name of the derived acyl group is lactoyl.

Iron(III) chloride describes the inorganic compounds with the formula FeCl3(H2O)x. Also called ferric chloride, these compounds are some of the most important and commonplace compounds of iron. They are available both in anhydrous and in hydrated forms which are both hygroscopic. They feature iron in its +3 oxidation state. The anhydrous derivative is a Lewis acid, while all forms are mild oxidizing agents. It is used as a water cleaner and as an etchant for metals.

<span class="mw-page-title-main">Lead(II) chloride</span> Chemical compound

Lead(II) chloride (PbCl2) is an inorganic compound which is a white solid under ambient conditions. It is poorly soluble in water. Lead(II) chloride is one of the most important lead-based reagents. It also occurs naturally in the form of the mineral cotunnite.

In chemistry, an acetylide is a compound that can be viewed as the result of replacing one or both hydrogen atoms of acetylene (ethyne) HC≡CH by metallic or other cations. The term is also used, more loosely, for any compound obtained in the same way from an acetylene derivative RC≡CH, where R is some organic side chain.

<span class="mw-page-title-main">Polyglycolide</span> Chemical compound

Polyglycolide or poly(glycolic acid) (PGA), also spelled as polyglycolic acid, is a biodegradable, thermoplastic polymer and the simplest linear, aliphatic polyester. It can be prepared starting from glycolic acid by means of polycondensation or ring-opening polymerization. PGA has been known since 1954 as a tough fiber-forming polymer. Owing to its hydrolytic instability, however, its use has initially been limited. Currently polyglycolide and its copolymers (poly(lactic-co-glycolic acid) with lactic acid, poly(glycolide-co-caprolactone) with ε-caprolactone and poly (glycolide-co-trimethylene carbonate) with trimethylene carbonate) are widely used as a material for the synthesis of absorbable sutures and are being evaluated in the biomedical field.

<span class="mw-page-title-main">Triphenylphosphine</span> Chemical compound

Triphenylphosphine (IUPAC name: triphenylphosphane) is a common organophosphorus compound with the formula P(C6H5)3 and often abbreviated to PPh3 or Ph3P. It is versatile compound that is widely used as a reagent in organic synthesis and as a ligand for transition metal complexes, including ones that serve as catalysts in organometallic chemistry. PPh3 exists as relatively air stable, colorless crystals at room temperature. It dissolves in non-polar organic solvents such as benzene and diethyl ether.

<span class="mw-page-title-main">Polylactic acid</span> Biodegradable polymer

Polylactic acid, also known as poly(lactic acid) or polylactide (PLA), is a thermoplastic polyester with backbone formula (C
3
H
4
O
2
)
n
or [–C(CH
3
)HC(=O)O–]
n
, formally obtained by condensation of lactic acid C(CH
3
)(OH)HCOOH
with loss of water. It can also be prepared by ring-opening polymerization of lactide [–C(CH
3
)HC(=O)O–]
2
, the cyclic dimer of the basic repeating unit.

<span class="mw-page-title-main">Calcium lactate</span> Chemical compound

Calcium lactate is a white crystalline salt with formula C
6
H
10
CaO
6
, consisting of two lactate anions H
3
C
(CHOH)CO
2
for each calcium cation Ca2+
. It forms several hydrates, the most common being the pentahydrate C
6
H
10
CaO
6
·5H
2
O
.

<span class="mw-page-title-main">Copper(I) cyanide</span> Chemical compound

Copper(I) cyanide is an inorganic compound with the formula CuCN. This off-white solid occurs in two polymorphs; impure samples can be green due to the presence of Cu(II) impurities. The compound is useful as a catalyst, in electroplating copper, and as a reagent in the preparation of nitriles.

<span class="mw-page-title-main">Ethyl lactate</span> Chemical compound

Ethyl lactate, also known as lactic acid ethyl ester, is the organic compound with the formula CH3CH(OH)CO2CH2CH3. It is the ethyl ester of lactic acid. A colorless liquid, it is a chiral ester. Being naturally derived, it is readily available as a single enantiomer. It is commonly used as a solvent. This compound is considered biodegradable and can be used as a water-rinsible degreaser. Ethyl lactate is found naturally in small quantities in a wide variety of foods including wine, chicken, and various fruits. The odor of ethyl lactate when dilute is mild, buttery, creamy, with hints of fruit and coconut.

Organosodium chemistry is the chemistry of organometallic compounds containing a carbon to sodium chemical bond. The application of organosodium compounds in chemistry is limited in part due to competition from organolithium compounds, which are commercially available and exhibit more convenient reactivity.

<span class="mw-page-title-main">Metal halides</span>

Metal halides are compounds between metals and halogens. Some, such as sodium chloride are ionic, while others are covalently bonded. A few metal halides are discrete molecules, such as uranium hexafluoride, but most adopt polymeric structures, such as palladium chloride.

Lactonitrile is the organic compound with the formula CH3CH(OH)CN. It is an intermediate in the industrial production of ethyl lactate and lactic acid. It is the cyanohydrin of acetaldehyde. It is a colorless liquid, although degraded samples can appear yellow.

<span class="mw-page-title-main">Vinylphosphonic acid</span> Chemical compound

Vinylphosphonic acid is an organophosphorus compound with the formula C2H3PO3H2. It is a colorless, low-melting solid, although commercial samples are often yellowish viscous liquids. It is used to prepare adhesives. As in other phosphonic acids, the phosphorus center is tetrahedral, being bonded to an organic group (vinyl in this case), two OH groups, and an oxygen.

<span class="mw-page-title-main">Lithium lactate</span> Chemical compound

Lithium lactate is a chemical compound, a salt of lithium and lactic acid with the formula CH3CH(OH)COOLi, an amorphous solid, very soluble in water.

<span class="mw-page-title-main">Manganese lactate</span> Chemical compound

Manganese lactate is an organic chemical compound, a salt of manganese and lactic acid with the formula Mn(C3H5O3)2. The compound forms light pink crystals, soluble in water, forming crystalline hydrates.

<span class="mw-page-title-main">Cobalt lactate</span> Chemical compound

Cobalt lactate is a chemical compound, a salt of cobalt and lactic acid with the formula Co(C3H5O3)2.

<span class="mw-page-title-main">Cadmium lactate</span> Chemical compound

Cadmium lactate is an organic chemical compound, a salt of cadmium and lactic acid with the formula Cd(C3H5O3)2.

<span class="mw-page-title-main">Zinc lactate</span> Chemical compound

Zinc lactate is a chemical compound, a salt of zinc and lactic acid with the formula Zn(C3H5O3)2.

References

  1. Hacker, Gerhard W.; Gu, Jiang (17 April 2002). Gold and Silver Staining: Techniques in Molecular Morphology. CRC Press. p. 62. ISBN   978-1-4200-4023-4 . Retrieved 18 January 2022.
  2. "Silver Lactate". American Elements . Retrieved 18 January 2022.
  3. "Silver lactate". Sigma Aldrich . Retrieved 18 January 2022.
  4. Hayat, M. A. (3 August 1995). Immunogold-Silver Staining: Principles, Methods, and Applications. CRC Press. p. 30. ISBN   978-0-8493-2449-9 . Retrieved 18 January 2022.
  5. Cornell University Medical Bulletin. 1928. p. 296. Retrieved 18 January 2022.
  6. Fackler, John P.; Khan, M. Nazrul I.; King, Christopher; Staples, Richard J.; Winpenny, Richard E. P. (1 July 1991). "Decarboxylation of (triphenylphosphine)gold(I) carboxylates". Organometallics . 10 (7): 2178–2183. doi:10.1021/om00053a021. ISSN   0276-7333 . Retrieved 23 January 2022.
  7. Zhang, Min; Feng, Meng-Yao; Yan, Jia-Jun; Li, Hai-Yan; Young, David James; Li, Hong-Xi; Ren, Zhi-Gang (21 June 2021). "New Silver(I)-P4 Coordination Polymers Strongly Adsorb Congo Red to Yield Composites with Enhanced Photocurrent Responses". European Journal of Inorganic Chemistry . 2021 (23): 2262–2265. doi:10.1002/ejic.202100228. S2CID   235558940 . Retrieved 23 January 2022.