Tb(H2O)6(ClO4)3 | |
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3D model (JSmol) |
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Properties | |
Cl3O12Tb | |
Molar mass | 457.26 g·mol−1 |
Appearance | light pink crystals (hexahydrate) [1] |
Density | 2.21 g/cm3 (hexahydrate) [2] |
soluble (anhydrous, hexahydrate) [1] | |
Hazards | |
GHS labelling: [3] | |
Danger | |
H272, H315, H319, H335 | |
P210, P220, P261, P264, P264+P265, P271, P280, P302+P3sub52 | , P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P405, P501|
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Terbium perchlorate refers to an inorganic compound having chemical formula Tb(ClO4)3(H2O)x. Usually this salt is encountered as its hexahydrate. This terbium(III) compound can be obtained by treating terbium(III,IV) oxide with perchloric acid. [4] The perchlorates are non-coordinating anions, so this substance can be used as a starting material for forming Tb(III) complexes. For example, reaction with alanine forms a complex in which the carboxylate portion of four alanine units bridge between two terbium atoms. [5] It can be used to synthesize terbium-containing metal-organic framework materials. [6] [7]
Terbium is a chemical element; it has the symbol Tb and atomic number 65. It is a silvery-white, rare earth metal that is malleable and ductile. The ninth member of the lanthanide series, terbium is a fairly electropositive metal that reacts with water, evolving hydrogen gas. Terbium is never found in nature as a free element, but it is contained in many minerals, including cerite, gadolinite, monazite, xenotime and euxenite.
Perchloric acid is a mineral acid with the formula HClO4. It is an oxoacid of chlorine. Usually found as an aqueous solution, this colorless compound is a stronger acid than sulfuric acid, nitric acid and hydrochloric acid. It is a powerful oxidizer when hot, but aqueous solutions up to approximately 70% by weight at room temperature are generally safe, only showing strong acid features and no oxidizing properties. Perchloric acid is useful for preparing perchlorate salts, especially ammonium perchlorate, an important rocket fuel component. Perchloric acid is dangerously corrosive and readily forms potentially explosive mixtures.
Aluminium chloride, also known as aluminium trichloride, is an inorganic compound with the formula AlCl3. It forms a hexahydrate with the formula [Al(H2O)6]Cl3, containing six water molecules of hydration. Both the anhydrous form and the hexahydrate are colourless crystals, but samples are often contaminated with iron(III) chloride, giving them a yellow colour.
Chromium(III) chloride (also called chromic chloride) is an inorganic chemical compound with the chemical formula CrCl3. It forms several hydrates with the formula CrCl3·nH2O, among which are hydrates where n can be 5 (chromium(III) chloride pentahydrate CrCl3·5H2O) or 6 (chromium(III) chloride hexahydrate CrCl3·6H2O). The anhydrous compound with the formula CrCl3 are violet crystals, while the most common form of the chromium(III) chloride are the dark green crystals of hexahydrate, CrCl3·6H2O. Chromium chlorides find use as catalysts and as precursors to dyes for wool.
Silver perchlorate is the chemical compound with the formula AgClO4. This white solid forms a monohydrate and is mildly deliquescent. It is a useful source of the Ag+ ion, although the presence of perchlorate presents risks. It is used as a catalyst in organic chemistry.
A solubility chart is a chart describing whether the ionic compounds formed from different combinations of cations and anions dissolve in or precipitate from solution.
Vanadium(III) chloride describes the inorganic compound with the formula VCl3 and its hydrates. It forms a purple anhydrous form and a green hexahydrate [VCl2(H2O)4]Cl·2H2O. These hygroscopic salts are common precursors to other vanadium(III) complexes and is used as a mild reducing agent.
Terbium(III) bromide (TbBr3) is a crystalline chemical compound.
Terbium(III) chloride (TbCl3) is a chemical compound. In the solid state TbCl3 has the YCl3 layer structure. Terbium(III) chloride frequently forms a hexahydrate.
Iron(III) nitrate, or ferric nitrate, is the name used for a series of inorganic compounds with the formula Fe(NO3)3.(H2O)n. Most common is the nonahydrate Fe(NO3)3.(H2O)9. The hydrates are all pale colored, water-soluble paramagnetic salts.
Terbium(III) iodide (TbI3) is an inorganic chemical compound.
Berkelium forms a number of chemical compounds, where it normally exists in an oxidation state of +3 or +4, and behaves similarly to its lanthanide analogue, terbium. Like all actinides, berkelium easily dissolves in various aqueous inorganic acids, liberating gaseous hydrogen and converting into the trivalent oxidation state. This trivalent state is the most stable, especially in aqueous solutions, but tetravalent berkelium compounds are also known. The existence of divalent berkelium salts is uncertain and has only been reported in mixed lanthanum chloride-strontium chloride melts. Aqueous solutions of Bk3+ ions are green in most acids. The color of the Bk4+ ions is yellow in hydrochloric acid and orange-yellow in sulfuric acid. Berkelium does not react rapidly with oxygen at room temperature, possibly due to the formation of a protective oxide surface layer; however, it reacts with molten metals, hydrogen, halogens, chalcogens and pnictogens to form various binary compounds. Berkelium can also form several organometallic compounds.
Copper(II) perchlorate is an inorganic compound with the chemical formula Cu(ClO4)2(H2O)x. The anhydrous solid is rarely encountered but several hydrates are known. Most important is the perchlorate salt of the aquo complex copper(II) perchlorate hexahydrate, [Cu(H2O)6]2+.
Yttrium(III) nitrate is an inorganic compound, a salt with the formula Y(NO3)3. The hexahydrate is the most common form commercially available.
Terbium(III) nitrate is an inorganic chemical compound, a salt of terbium and nitric acid, with the formula Tb(NO3)3. The hexahydrate crystallizes as triclinic colorless crystals with the formula [Tb(NO3)3(H2O)4]·2H2O. It can be used to synthesize materials with green emission.
Iron(II) perchlorate is the inorganic compound with the formula Fe(ClO4)2·6H2O. A green, water-soluble solid, it is produced by the reaction of iron metal with dilute perchloric acid followed by evaporation of the solution:
Nickel(II) perchlorate is a collection of inorganic compounds with the chemical formula of Ni(ClO4)2(H2O)x. Its colors of these solids vary with the degree of hydration. For example, the hydrate forms cyan crystals, the pentahydrate forms green crystals, but the hexahydrate (Ni(ClO4)2·6H2O) forms blue crystals. Nickel(II) perchlorate hexahydrate is highly soluble in water and soluble in some polar organic solvents.
Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl3, Eu(NO3)3 and Eu(CH3COO)3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in aqueous solution. Many europium compounds fluoresce under ultraviolet light due to the excitation of electrons to higher energy levels. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod.
Terbium compounds are compounds formed by the lanthanide metal terbium (Tb). Terbium generally exhibits the +3 oxidation state in these compounds, such as in TbCl3, Tb(NO3)3 and Tb(CH3COO)3. Compounds with terbium in the +4 oxidation state are also known, such as TbO2 and BaTbF6. Terbium can also form compounds in the 0, +1 and +2 oxidation states.
Transition metal perchlorate complexes are coordination complexes with one or more perchlorate ligands. Perchlorate can bind to metals through one, two, three, or all four oxygen atoms. Usually however, perchlorate is a counterion, not a ligand.