Praseodymium(III) perchlorate

Last updated
Praseodymium perchlorate
Praseodymium(III) perchlorate.svg
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.460 OOjs UI icon edit-ltr-progressive.svg
EC Number
PubChem CID
UN number 3098 [1]
  • InChI=1S/3ClHO4.Pr/c3*2-1(3,4)5;/h3*(H,2,3,4,5);/q;;;+3/p-3 [2]
    Key: OPAITELCMCAYEB-UHFFFAOYSA-K
  • [O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Pr+3]
Properties
Pr(ClO4)3
Molar mass 439.259 [2]
Density 1.563 [1]
Melting point liquid at room temperature [1]
Vapor pressure 0.21 psi (20 °C) [1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Praseodymium(III) perchlorate is the perchlorate salt of praseodymium, with the chemical formula of Pr(ClO4)3. [3]

Contents

Preparation

Praseodymium(III) perchlorate can be prepared from praseodymium(III,IV) oxide. [4] [5] Dissolving praseodymium(III,IV) oxide in a slight excess of hydrochloric acid and adding a small amount of hydrogen peroxide can prepare praseodymium perchlorate. [5]

Chemical properties

Praseodymium perchlorate can form two complexes with crown ether 18-crown-6 in stoichiometric ratios of 1:1 and 1:2., [6] and can form complexes with L-proline, [7] glutamic acid, [4] mandelic acid, [4] penicillamine. [4] It can also form complexes with imidazole and alanine. [5]

Related Research Articles

<span class="mw-page-title-main">Terbium(III) chloride</span> Chemical compound

Terbium(III) chloride (TbCl3) is a chemical compound. In the solid state TbCl3 has the YCl3 layer structure. Terbium(III) chloride frequently forms a hexahydrate.

<span class="mw-page-title-main">Hajime Tanabe</span> Japanese philosopher

Hajime Tanabe was a Japanese philosopher of science, particularly of mathematics and physics. His work brought together elements of Buddhism, scientific thought, Western philosophy, Christianity, and Marxism. In the postwar years, Tanabe coined the concept of metanoetics, proposing that the limits of speculative philosophy and reason must be surpassed by metanoia.

Wuyi University is a public university based in Jiangmen, Guangdong, China.

Yoshio Nishi was a Japanese scholar of Tibeto-Burman linguistics. He first studied linguistics while a student at the International Christian University (Tokyo) under the leadership of Roy Andrew Miller. After the master's coursework at the University of Tokyo and his time studying at Rangoon University, he taught at Kyushu University, Kagoshima University, Ehime University, and Kobe City University of Foreign Studies. In 1996 when the university newly founded the doctoral course at its graduate school, he was the only D-maru-gō professor of linguistics qualified to supervise doctoral students. He is now a professor emeritus at Kobe City University of Foreign Studies, and was nominated in 1993 as a distinguished professor at Central University of Nationalities in Beijing.

Yang Shouren is a professor in the School of Earth and Space Sciences in Peking University.

<span class="mw-page-title-main">Estradiol/megestrol acetate</span> Pharmaceutical combination

Estradiol/megestrol acetate (E2/MGA), sold under the brand names Mego-E and Chinese injectable No. 2, is a form of combined injectable birth control which is used in the People's Republic of China. It contains 3.5 mg estradiol (E2), an estrogen, and 25 mg megestrol acetate (MGA), a progestin. It is a microcrystalline aqueous suspension with a defined particle size range. The medication is given once per month by injection into muscle.

<span class="mw-page-title-main">Praseodymium(IV) oxide</span> Chemical compound

Praseodymium(IV) oxide is an inorganic compound with chemical formula PrO2.

Dysprosium(III) fluoride is an inorganic compound of dysprosium with a chemical formula DyF3.

Terbium(III) fluoride is an inorganic compound with chemical formula TbF3. It is hard to dissolve in water. It can be produced by reacting terbium(III) carbonate and 40% hydrofluoric acid at 40°C.

Gadolinium(III) fluoride is an inorganic compound with a chemical formula GdF3.

<span class="mw-page-title-main">Scandium perchlorate</span> Chemical compound

Scandium perchlorate is an inorganic compound with the chemical formula Sc(ClO4)3.

<span class="mw-page-title-main">Praseodymium(III) hydroxide</span> Chemical compound

Praseodymium(III) hydroxide is an inorganic compound with a chemical formula Pr(OH)3.

<span class="mw-page-title-main">TMSR-LF1</span> Molten salt reactor prototype

TMSR-LF1 is a 2 MWt molten salt reactor (MSR) pilot plant located in northwest China.

<span class="mw-page-title-main">Nickel(II) perchlorate</span> Compound of nickel

Nickel(II) perchlorate is a inorganic compound with the chemical formula of Ni(ClO4)2, and it is a strong oxidizing agent. Its colours are different depending on water. For example, the hydrate forms cyan crystals, the pentahydrate forms green crystals, but the hexahydrate (Ni(ClO4)2·6H2O) forms blue crystals.

Praseodymium(III) carbonate is an inorganic compound, with a chemical formula of Pr2(CO3)3. The anhydrous form is olive green, and many of its hydrates such as heptahydrate and octahydrate are known. They are all insoluble in water.

<span class="mw-page-title-main">Terbium compounds</span> Chemical compounds with at least one terbium atom

Terbium compounds are compounds formed by the lanthanide metal terbium (Tb). Terbium generally exhibits the +3 oxidation state in these compounds, such as in TbCl3, Tb(NO3)3 and Tb(CH3COO)3. Compounds with terbium in the +4 oxidation state are also known, such as TbO2 and BaTbF6. Terbium can also form compounds in the 0, +1 and +2 oxidation states.

<span class="mw-page-title-main">Gallium perrhenate</span> Chemical compound

Gallium perrhenate is an inorganic compound with the chemical formula of Ga(ReO4)3. It exists in the anhydrous and hydrate forms.

A niobate is an oxo-acid salt formed by niobium(V), and the common forms are metaniobate (NbO3) and orthoniobate (NbO43−). The most common niobates are lithium niobate (LiNbO3) and potassium niobate (KNbO3).

<span class="mw-page-title-main">Indium acetate</span> Chemical compound

Indium acetate is an acetate of indium, with the chemical formula In(CH3COO)3. It is soluble in water, acetic acid and mineral acids. It is the precursor of indium-containing compounds such as the solar cell materials CuInS2 and indium phosphide quantum dots.

China uses various methods to carry out nationwide anti-drug publicity and education and popularize drug prevention knowledge. The main purpose is to strengthen citizens' anti-drug awareness and improve citizens' awareness of the harm of drugs. A major task of comprehensive anti-drug publicity and education is to popularize drug prevention knowledge., reveal the serious harm of drug abuse to individuals, families, and society, strengthen the anti-drug awareness of the entire population, especially young people, educate the public security bureau to combat drug-related crimes, and build an effective mechanism for the whole society to prevent drug abuse.Minimize the proportion of new drug addicts.It can be said that the anti-drug publicity and education work with preventive education as the main task is the fundamental solution to the anti-drug work, and its effect kills two birds with one stone.

References

  1. 1 2 3 4 5 "Praseodymium perchlorate 13498-07-2". www.chemicalbook.com. Retrieved 2017-10-20.
  2. 1 2 3 "Praseodymium perchlorate". ChemSpider . Retrieved 2017-10-21.
  3. PubChem. "Praseodymium(3+) perchlorate". pubchem.ncbi.nlm.nih.gov. Retrieved 2022-07-11.
  4. 1 2 3 4 张若桦, 陈敬堂、江冬青 (1995). "镨(III)溶液光谱研究:高氯酸镨─谷氨酸/苦杏仁酸/青霉胺配合物". Acta Scientiarum Naturalium Universitatis Nankaiensis (1): 44-48. ISSN   0465-7942 . Retrieved 2017-10-21.
  5. 1 2 3 但悠梦, 胡卫兵、余华光、董家新、刘义、屈松生 (2006). "稀土配合物[Pr(C3H7NO2)2(C3H4N2)(H2O)](ClO4)3的标准生成焓及热分解动力学研究" [Standard Molar Enthalpy of Formation and Thermal Decomposition Kinetic Study of Rare Earth Complex [Pr(C3H7NO2)2(C3H4N2)(H2O)](ClO4)3]. Acta Chimica Sinica. 64 (1): 70-78. doi:10.3321/j.issn:0567-7351.2006.01.012. ISSN   0567-7351. S2CID   236111702 . Retrieved 2017-10-21.
  6. Xue Ganglin; Li Qianding; Hu Shaoming; Xu Hong; Ren Dehou; Zhuang Quanzhen (1996). "三水合高氯酸镨与18—冠—6配合物的研究" [Study on complexes of trihydrated praseodymium perchlorate with 18 -crown-6]. Acta Chimica Sinica (in Chinese). 54 (6): 568-574. ISSN   0567-7351 . Retrieved 2017-10-14.
  7. 张忠海, 姜晓娟, 库宗军. 高氯酸镨与L-脯氨酸配合物的合成及热化学和热分解动力学研究[C]// 中国化学会全国化学热力学和热分析学术会议. 2006.