Zinc arsenide

Last updated
Zinc arsenide
Names
Other names
trizinc diarsenide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.338 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 234-486-2
PubChem CID
  • InChI=1S/2As.3Zn
    Key: RHKSESDHCKYTHI-UHFFFAOYSA-N
  • [Zn].[Zn]=[As].[Zn]=[As]
Properties
Zn3As2
Molar mass 345.984 g/mol
AppearanceSilver grey [1]
Density 5.53 g/cm3 [1]
Melting point 1,015 °C (1,859 °F; 1,288 K)
Insoluble [1]
Structure
Tetragonal
Hazards
GHS labelling:
GHS-pictogram-acid.svg GHS-pictogram-skull.svg GHS-pictogram-silhouette.svg
Danger
H301, H331, H350, H410
P201, P202, P222, P231+P232, P261, P264, P270, P271, P273, P280, P281, P301+P310+P330, P304+P340, P308+P313, P321, P370+P378, P391, P403+P233, P405, P422, P501
NFPA 704 (fire diamond)
4
0
0
Safety data sheet (SDS) [1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Zinc arsenide (Zn3As2) is a binary compound of zinc with arsenic which forms gray tetragonal crystals. It is an inorganic semiconductor with a band gap of 1.0 eV. [2]

Contents

Synthesis and reactions

Zinc arsenide can be prepared by the reaction of zinc with arsenic

3 Zn + 2 As → Zn3As2

Structure

Zn3As2 has a room-temperature tetragonal form that converts to a different tetragonal phase at 190 °C and to a third phase at 651 °C. [3] In the room-temperature form, the zinc atoms are tetrahedrally coordinated and the arsenic atoms are surrounded by six zinc atoms at the vertices of a distorted cube. The crystalline structure of zinc arsenide is very similar to that of cadmium arsenide (Cd3As2), zinc phosphide (Zn3P2) and cadmium phosphide (Cd3P2). These compounds of the Zn-Cd-P-As quaternary system exhibit full continuous solid-solution. [4]

Electronic structure

Its lowest direct and indirect bandgaps are within 30 meV or each other. [2]

Related Research Articles

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Arsenide bromides or bromide arsenides are compounds containing anions composed of bromide (Br) and arsenide (As3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the arsenide chlorides, arsenide iodides, phosphide bromides, and antimonide bromides.

Arsenide iodides or iodide arsenides are compounds containing anions composed of iodide (I) and arsenide (As3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the arsenide chlorides, arsenide bromides, phosphide iodides, and antimonide iodides.

References

  1. 1 2 3 4 "LTS Research Laboratories, Inc. Safety Data Sheet: Zinc Arsenide" (PDF). ltschem.com. Retrieved 2020-10-26.
  2. 1 2 Botha, J. R.; Scriven, G. J.; Engelbrecht, J. A. A.; Leitch, A. W. R. (1999). "Photoluminescence properties of metalorganic vapor phase epitaxial Zn3As2". Journal of Applied Physics. 86 (10): 5614–5618. doi:10.1063/1.371569.
  3. Okamoto, H. (1992). "The As-Zn (arsenic-zinc) system". Journal of Phase Equilibria. 13 (2): 155–161. doi:10.1007/BF02667479. S2CID   98798806.
  4. Trukhan, V. M.; Izotov, A. D.; Shoukavaya, T. V. (2014). "Compounds and solid solutions of the Zn-Cd-P-As system in semiconductor electronics". Inorganic Materials. 50 (9): 868–873. doi:10.1134/S0020168514090143. S2CID   94409384.