Arsenidogermanate

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Arsenidogermanates are chemical compounds that contain anions with arsenic bonded to germanium. They are in the category of tetrelarsenides, pnictidogermanates, or tetrelpnictides.

Germanium forms two arsenides: GeAs and GeAs2. [1]

List

nameformulaformula

weight

crystal

system

space

group

unit cellvolumedensitycommentsref
LiGe3As3orthorhombicPbama=10.0862 b=15.7612 c=3.7403 Z=4594.605.01 [2]
Li5GeAs3black [3]
NaGe6As6908.05monoclinicC2/ma = 22.063, b = 3.8032, c = 7.2020, β = 92.744°, Z = 2603.645.00needles [4]
Na10Ge2As6monoclinicP121/n1a=13.531 b=7.544 c=8.298 β = 90.2° Z=2847.0 [5]
K2GeAs2orthorhombicIbama = 13.292, b = 7.028, c = 6.548 Z = 4moisture sensitive needles [6]
KGe3As3481.53orthorhombicPnmaa=9.993, b=3.7664, c=18.607 Z=4700.344.568 [7]
K2Ge3As3520.73orthorhombicPnnma=14.1466 b=16.300 c=3.7489 Z=4864.474.001fibrous metallic [8]
K2NaGaAs2Ibama=6.733 b=14.809 c=6.574 Z=4655.53.250 [9]
KCdGeAs2triclinicP1a = 8.004, b = 8.402, c = 8.703, α = 71.019°, β = 75.257°, γ = 73.746°, Z=4band gap 0.8 eV; Ge2As6 units [10]
RbCdGeAs2triclinicP1a = 8.269, b = 8.452, c = 8.735, α = 71.163°, β = 75.601°, γ = 73.673°, Z=4Ge2As6 units [10]
Sr3Ge2As4red metallic; 1D As3GeGeAs3 units [11]
K5In5Ge5As14monoclinicC2/ma=40.00,b=3.925,c=10.299, β=99.97°, Z=815924.55air sensitive; layered [12]
K8In8Ge5As17monoclinicP21/ca=18.394,b=19.087,c=25.360, β=105.71°, Z=485714.45air sensitive; layered [12]
RbGe3As3528orthorhombicPnmaa=10.166 b=3.7595 c=19.028 Z=4727.24.823 [7]
Rb(Ge1.5In0.5)As2(As1.5Ge0.5)orthorhombicCmc21a = 3.799, b = 16.50, c = 12.24, Z = 47674.589 [13]
RbXGe2−XInXAs4 [13]
I8As21Ge254403cubicPm3na=10.5963 Z=11189.86.1431colourless [14]
Cs5GeAs3metallic; unstable in air; GeAs3 units [15]
BaGe2As2tetragonalP42mca=7,786 c=8.664 Z=4525.25.47metallic [16]
Ba4GeAs4dark metallic; GeAs4 units [17]
Re3Ge0.6As6.4 [18]
Re3GeAs61080.75cubicIm3ma = 8.73202 Z=4665.7510.78n-type semiconductor [18]
AuGeAsmonoclinicCca 7.2729, b 6.2953, c 6.3067, β 119.209° [19]
KXGe2−XTlXAs4 [13]

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References

  1. ↑ Stöhr, Herbert; Klemm, Wilhelm (1940-07-09). "Über Zweistoffsysteme mit Germanium. II. Germanium/Arsen, Germanium/Antimon, Germanium/Wismut". Zeitschrift für anorganische und allgemeine Chemie. 244 (2): 205–223. doi:10.1002/zaac.19402440211.
  2. ↑ Mark, Justin; Hanrahan, Michael P.; Woo, Katherine E.; Lee, Shannon; Rossini, Aaron J.; Kovnir, Kirill (2 May 2019). "Chemical and Electrochemical Lithiation of van der Waals Tetrel‐Arsenides". Chemistry – A European Journal. 25 (25): 6392–6401. doi:10.1002/chem.201900339. OSTI   1526289. PMID   30887569. S2CID   83463348.
  3. ↑ Juza, Robert; Schulz, Werner (February 1954). "Ternäre Phosphide und Arsenide des Lithiums mit Elementen der 3. und 4. Gruppe". Zeitschrift für anorganische und allgemeine Chemie (in German). 275 (1–3): 65–78. doi:10.1002/zaac.19542750107. ISSN   0044-2313.
  4. ↑ Khatun, Mansura; Mar, Arthur (2016-05-01). "NaGe6As6: Insertion of sodium into the layered semiconductor germanium arsenide GeAs". Zeitschrift für Naturforschung B. 71 (5): 375–380. doi:10.1515/znb-2015-0203. ISSN   1865-7117. S2CID   197298002.
  5. ↑ Eisenmann, B.; Klein, J.; Somer, M. (1991-02-01). Eisenmann, B.; Klein, J.; Somer, M. (eds.). "Crystal structure of decasodium di-μ-arsenido-bis(diarsenidogermanate), Na10Ge2As6". Zeitschrift für Kristallographie - Crystalline Materials. 197 (3–4): 265–266. Bibcode:1991ZK....197..265E. doi:10.1524/zkri.1991.197.3-4.265. ISSN   2194-4946.
  6. ↑ Eisenmann, Brigitte; Klein, Jürgen (September 1991). "SiS2-isostrukturelle Anionen [SiP22−], [GeAs22−] und [SnAs22−] in Alkaliverbindungen". Journal of the Less Common Metals (in German). 175 (1): 109–117. doi:10.1016/0022-5088(91)90355-8.
  7. 1 2 Khatun, Mansura; Stoyko, Stanislav S.; Mar, Arthur (June 2016). "Ternary arsenides ATt3As3 (A=K, Rb; Tt=Ge, Sn) with layered structures". Journal of Solid State Chemistry. 238: 229–235. Bibcode:2016JSSCh.238..229K. doi:10.1016/j.jssc.2016.03.035.
  8. ↑ Eulenstein, Armin R.; Bogdanovski, Dimitri; Reinhardt, Hendrik; Miß, Vanessa; Roling, Bernhard; Hampp, Norbert; Dronskowski, Richard; Dehnen, Stefanie (12 November 2019). "K2Ge3As3: Fiberlike Crystals of a Narrow-Band-Gap Zintl Phase with a One-Dimensional Substructure ∞1{(Ge3As3)2–}". Chemistry of Materials. 31 (21): 8839–8849. doi:10.1021/acs.chemmater.9b02827. S2CID   204116281.
  9. ↑ Somer, Mehmet; Peters, Karl; von Schnering, Hans Georg (July 1992). "K2NaGaP2, Cs2NaGaP2, K2NaGaAs2, K2NaInP2 und K2NaInAs2, Verbindungen mit den SiS2-isosteren Polyanionen ∞
    1    [MX4/2]3− (M=Ga, In; X=P, As)"    . Zeitschrift für anorganische und allgemeine Chemie (in German). 613 (7): 19–25. doi:10.1002/zaac.19926130103. ISSN   0044-2313.
  10. 1 2 Khatun, Mansura; Stoyko, Stanislav S.; Mar, Arthur (21 July 2014). "Quaternary Arsenides ACdGeAs2 (A = K, Rb) Built of Ethane-Like Ge2As6 Units". Inorganic Chemistry. 53 (14): 7756–7762. doi:10.1021/ic5011264. PMID   24983676.
  11. ↑ Eisenmann, Brigitte; Schäfer, Herbert (June 1980). "Zintl Phases with Complex Anions: Sr3Si2As4 and Sr3Ge2As4". Angewandte Chemie International Edition in English. 19 (6): 490–491. doi:10.1002/anie.198004901.
  12. 1 2 Shreeve-Keyer, Julie L; Haushalter, Robert C; Lee, Young-Sook; Li, Sichu; O'Connor, Charles J; Seo, Dong-Kyun; Whangbo, Myung-Hwan (May 1997). "New Layered Materials in the K–In–Ge–As System: K8In8Ge5As17 and K5In5Ge5As14". Journal of Solid State Chemistry. 130 (2): 234–249. Bibcode:1997JSSCh.130..234S. doi:10.1006/jssc.1996.7210.
  13. 1 2 3 Shreeve-Keyer, Julie L.; Haushalter, Robert C. (1996), Kajimura, Koji; Kuroda, Shin-ichi (eds.), "Synthesis and Structural Characterization of a Quaternary Zintl Phase Material from the Rb:Ge:In:As System: Rb(Ge1.5ln0.5)As2(As1.5Ge0.5)", Materials and Measurements in Molecular Electronics, Springer Proceedings in Physics, Tokyo: Springer Japan, vol. 81, pp. 139–150, doi:10.1007/978-4-431-68470-1_11, ISBN   978-4-431-68472-5 , retrieved 2021-12-08
  14. ↑ Ayouz, Katia; Kars, Mohammed; Rebbah, Allaoua; Rebbah, Houria (15 March 2009). "I8As21Ge25". Acta Crystallographica Section E. 65 (3): i15. doi:10.1107/S1600536809004991. PMC   2968696 . PMID   21582033.
  15. ↑ Eisenmann, Brigitte; Klein, Jürgen; Somer, Mehmet (January 1990). "Anions Isosteric with CO32− in Cs5SiP3, Cs5SiAs3, Cs5GeP3, and Cs5GeAs3". Angewandte Chemie International Edition in English. 29 (1): 87–88. doi:10.1002/anie.199000871.
  16. ↑ Eisenmann, Brigitte; Schäfer, Herbert (1981-04-01). "Zintlphasen mit binären Anionen: Zur Kenntnis von BaGe2P2 und BaGe2As2 / Zintl Phases with Binary Anions: BaGe2P2 and BaGe2As2". Zeitschrift für Naturforschung B. 36 (4): 415–419. doi: 10.1515/znb-1981-0403 . ISSN   1865-7117. S2CID   95993285.
  17. ↑ Eisenmann, Brigitte; Jordan, Hanna; Schäfer, Herbert (February 1981). "Ba4SiAs4, and Ba4GeAs4, Zintl Phases with Isolated SiAs48− and GeAs48− anions". Angewandte Chemie International Edition in English. 20 (2): 197–198. doi:10.1002/anie.198101972.
  18. 1 2 Soheilnia, Navid; Xu, Hong; Zhang, Huqin; Tritt, Terry M.; Swainson, Ian; Kleinke, Holger (1 August 2007). "Thermoelectric Properties of Re3Ge0.6As6.4 and Re3GeAs6 in Comparison to Mo3Sb5.4Te1.6". Chemistry of Materials. 19 (16): 4063–4068. doi:10.1021/cm0708517.
  19. ↑ Lee, Shannon J.; Won, Juyeon; Wang, Lin‐Lin; Jing, Dapeng; Harmer, Colin P.; Mark, Justin; Akopov, Georgiy; Kovnir, Kirill (6 May 2021). "New Noncentrosymmetric Tetrel Pnictides Composed of Square‐Planar Gold(I) with Peculiar Bonding". Chemistry – A European Journal. 27 (26): 7383–7390. doi:10.1002/chem.202005312. PMC   8251799 . PMID   33523500.
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