Arsenidostannate

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Arsenidostanates are chemical compounds that contain anions with arsenic bonded to tin. They are in the category of tetrelarsenides, pnictidostancates, or tetrelpnictides.

They are distinct from arsenide stannides such as palarstanide, (Pd8(Sn,As)3) where the cation charge exceeds that on the tin or arsenic. [1] Other minerals that contain arsenic and tin are erniggliite [2] and coiraite. [3]

nameformulaformula

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crystal

system

space

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unit cellvolumedensitycommentsref
Li1–xSn2+xAs2, 0.2 < x < 0.4trigonalR3ma=3.991-4.0244 c=25.592-25.632 Z=3353.6-358.9 [4]
Na2SnAs2I41/acda=14.166, c=21.191, Z = 32metallic grey [5]
NaSn2As2rhombohedralR3ma=4.000 c=27.562metallic; layers [6]
KSn3As3orthorhombicPnmaZ=4 band gap 0.50 eV [7]
RbSn3As3orthorhombicPnmaa=10.321, b=4.0917, c=19.570 [7]
Ca5Sn2As6orthorhombicPbama = 13.643, b = 11.830, c = 4.121 Z=2 [8]
α-Sr3Sn2As4orthorhombicCmcaa = 25.798, b = 12.888, c = 19.124, Z = 246358.8melt 1185K; band gap 0.9 eV [9]
β-Sr3Sn2As4monoclinicP21/ca = 7.705, b = 19.118, c = 7.688, β = 112.003°, Z = 41049.9dec>800K; band gap 0.9 eV [9]
Sr14Sn3As12trigonalR3Z=3 [10]
Ba3Sn4As6monoclinicP21/na=8.637, b=18.354, c=9.721, β=90.05°, Z=4 [11]
BaCu6Sn2As4−xtetragonalI4/mmma = 4.164, c = 24.088 [12]
Ba13Si6Sn8As224551.72tetragonalI42ma = 14.4857, c = 13.5506 Z=22843.45.316black; Si4As10 units; band gap 1.0 eV [13]
EuSn2As2trigonal [14]
Eu14Sn3As12trigonalR3Z=3 [10]
Eu11Zn4Sn2As123069.46monoclinicC2/ca = 7.5679, b = 13.0883, c = 31.305, β = 94.8444 Z=43089.76.599silver; band gap 0.04 eV; ferromagnetic below 15K; negative colossal magnetoresistance [15]

References

  1. ↑ "Palarstanide Mineral Data". webmineral.com. Retrieved 8 December 2021.
  2. ↑ "Erniggliite Mineral Data". webmineral.com. Retrieved 8 December 2021.
  3. ↑ "Coiraite Mineral Data". webmineral.com. Retrieved 8 December 2021.
  4. ↑ Lee, Kathleen; Kaseman, Derrick; Sen, Sabyasachi; Hung, Ivan; Gan, Zhehong; Gerke, Birgit; Pöttgen, Rainer; Feygenson, Mikhail; Neuefeind, Jörg; Lebedev, Oleg I.; Kovnir, Kirill (2015-03-18). "Intricate Short-Range Ordering and Strongly Anisotropic Transport Properties of Li 1– x Sn 2+ x As 2". Journal of the American Chemical Society. 137 (10): 3622–3630. doi:10.1021/jacs.5b00237. ISSN   0002-7863. OSTI   1334418. PMID   25702752.
  5. ↑ Asbrand, Matthias; Eisenmann, Brigitte (1993). "Na2[SnAs2], the first Zintl phase with a [SnAs2] framework based on adamantane analogous [Sn4As10] units". Zeitschrift für Naturforschung B. 48: 452–456. doi: 10.1515/znb-1993-0409 . ISSN   0932-0776. S2CID   95169843.
  6. ↑ Arguilla, Maxx Q.; Katoch, Jyoti; Krymowski, Kevin; Cultrara, Nicholas D.; Xu, Jinsong; Xi, Xiaoxiang; Hanks, Amanda; Jiang, Shishi; Ross, Richard D.; Koch, Roland J.; Ulstrup, Søren (2016-10-25). "NaSn 2 As 2 : An Exfoliatable Layered van der Waals Zintl Phase". ACS Nano. 10 (10): 9500–9508. arXiv: 1710.09059 . doi:10.1021/acsnano.6b04609. ISSN   1936-0851. PMID   27700035. S2CID   20747874.
  7. 1 2 Khatun, Mansura; Stoyko, Stanislav S.; Mar, Arthur (June 2016). "Ternary arsenides ATt3As3 (A=K, Rb; Tt=Ge, Sn) with layered structures". Journal of Solid State Chemistry. 238: 229–235. Bibcode:2016JSSCh.238..229K. doi:10.1016/j.jssc.2016.03.035.
  8. ↑ Eisenmann, Brigitte; Jordan, Hanna; Schäfer, Herbert (November 1985). "Ca5Sn2As6, das erste Inoarsenidostannat(IV)" . Zeitschrift für anorganische und allgemeine Chemie (in German). 530 (11): 74–78. doi:10.1002/zaac.19855301108. ISSN   0044-2313.
  9. 1 2 Liu, Xiao-Cun; Pan, Ming-Yan; Li, Xin; Xia, Sheng-Qing; Tao, Xu-Tang (2014). "Synthesis, polymorphism, and electronic structures of Sr 3 Sn 2 As 4" . Inorg. Chem. Front. 1 (9): 689–694. doi:10.1039/C4QI00106K. ISSN   2052-1553.
  10. 1 2 Liu, Xiao-Cun; Pan, Ming-Yan; Xia, Sheng-Qing; Tao, Xu-Tang (21 September 2015). "Sr 14 Sn 3 As 12 and Eu 14 Sn 3 As 12 : Enantiomorph-like Zintl Compounds". Inorganic Chemistry. 54 (18): 8875–8877. doi:10.1021/acs.inorgchem.5b01145. PMID   26361335.
  11. ↑ Lam, Robert; Mar, Arthur (May 2001). "The metallic Zintl phase Ba3Sn4As6" . Solid State Sciences. 3 (4): 503–512. Bibcode:2001SSSci...3..503L. doi:10.1016/S1293-2558(01)01155-4.
  12. ↑ Wu, Hanlin; Li, Sheng; Wang, Xiqu; Kwon, Sunah; Liu, Wenhao; Ofenstein, Gareth A.; Kim, Moon J.; Lv, Bing (February 2022). "New layered quaternary BaCu6Sn2As4−x and BaCu6Sn2P4−x phases: Crystal growth and physical properties" . Journal of Alloys and Compounds. 892: 162111. doi:10.1016/j.jallcom.2021.162111. S2CID   239061015.
  13. ↑ Liu, Xiao-Cun; Lin, Na; Wang, Jian; Pan, Ming-Yan; Zhao, Xian; Tao, Xu-Tang; Xia, Sheng-Qing (2013-10-21). "Ba 13 Si 6 Sn 8 As 22 : A Quaternary Zintl Phase Containing Adamantane-Like [Si 4 As 10 ] Clusters" . Inorganic Chemistry. 52 (20): 11836–11842. doi:10.1021/ic402023z. ISSN   0020-1669. PMID   24079277.
  14. ↑ Pakhira, Santanu; Tanatar, M. A.; Heitmann, Thomas; Vaknin, David; Johnston, D. C. (2021-11-19). "A -type antiferromagnetic order and magnetic phase diagram of the trigonal Eu spin- 7 2 triangular-lattice compound EuSn 2 As 2". Physical Review B. 104 (17): 174427. arXiv: 2106.10519 . Bibcode:2021PhRvB.104q4427P. doi:10.1103/PhysRevB.104.174427. ISSN   2469-9950. S2CID   235489681.
  15. ↑ Devlin, Kasey P.; Kazem, Nasrin; Zaikina, Julia V.; Cooley, Joya A.; Badger, Jackson R.; Fettinger, James C.; Taufour, Valentin; Kauzlarich, Susan M. (2018-10-23). "Eu 11 Zn 4 Sn 2 As 12 : A Ferromagnetic Zintl Semiconductor with a Layered Structure Featuring Extended Zn 4 As 6 Sheets and Ethane-like Sn 2 As 6 Units" . Chemistry of Materials. 30 (20): 7067–7076. doi:10.1021/acs.chemmater.8b02749. ISSN   0897-4756. S2CID   105572581.
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