 | |
| Identifiers | |
|---|---|
3D model (JSmol) | |
| |
| |
| Properties | |
| TaAs | |
| Molar mass | 255.869 g/mol |
| Density | 12.25 g/cm3 [1] |
| Melting point | Decomposes at 1400°C [2] |
| Structure | |
| Body-centered tetragonal | |
| I41md, No. 109 | |
| 4mm | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Tantalum arsenide is a compound of tantalum and arsenic with the formula TaAs. It is notable as being the first topological Weyl semimetal that was identified and characterized by ARPES. [3]
Tantalum arsenide crystallizes in a body-centered tetragonal cell with lattice parameters a = 3.44 Å and c = 11.65 Å. It belongs to the space group I41md.
TaAs has been prepared by decomposing TaAs2 at 900 °C. [1] A more recent preparation yielded large, single crystals of TaAs by chemical vapor transport with elemental precursors and iodine as the transport agent: [2]
In physics, the Kondo effect describes the scattering of conduction electrons in a metal due to magnetic impurities, resulting in a characteristic change i.e. a minimum in electrical resistivity with temperature. The cause of the effect was first explained by Jun Kondo, who applied third-order perturbation theory to the problem to account for scattering of s-orbital conduction electrons off d-orbital electrons localized at impurities. Kondo's calculation predicted that the scattering rate and the resulting part of the resistivity should increase logarithmically as the temperature approaches 0 K. Experiments in the 1960s by Myriam Sarachik at Bell Laboratories provided the first data that confirmed the Kondo effect. Extended to a lattice of magnetic impurities, the Kondo effect likely explains the formation of heavy fermions and Kondo insulators in intermetallic compounds, especially those involving rare earth elements such as cerium, praseodymium, and ytterbium, and actinide elements such as uranium. The Kondo effect has also been observed in quantum dot systems.
Cadmium arsenide (Cd3As2) is an inorganic semimetal in the II-V family. It exhibits the Nernst effect.
Tantalum carbides (TaC) form a family of binary chemical compounds of tantalum and carbon with the empirical formula TaCx, where x usually varies between 0.4 and 1. They are extremely hard, brittle, refractory ceramic materials with metallic electrical conductivity. They appear as brown-gray powders, which are usually processed by sintering.
In chemistry, an arsenide is a compound of arsenic with a less electronegative element or elements. Many metals form binary compounds containing arsenic, and these are called arsenides. They exist with many stoichiometries, and in this respect arsenides are similar to phosphides.
Boron arsenide is a chemical compound involving boron and arsenic, usually with a chemical formula BAs. Other boron arsenide compounds are known, such as the subarsenide B12As2. Chemical synthesis of cubic BAs is very challenging and its single crystal forms usually have defects.
Tantalum pentoxide, also known as tantalum(V) oxide, is the inorganic compound with the formula Ta
2O
5. It is a white solid that is insoluble in all solvents but is attacked by strong bases and hydrofluoric acid. Ta
2O
5 is an inert material with a high refractive index and low absorption, which makes it useful for coatings. It is also extensively used in the production of capacitors, due to its high dielectric constant.
Tungsten(IV) telluride (WTe2) is an inorganic semimetallic chemical compound. In October 2014, tungsten ditelluride was discovered to exhibit an extremely large magnetoresistance: 13 million percent resistance increase in a magnetic field of 60 Tesla at 0.5 Kelvin. The resistance is proportional to the square of the magnetic field and shows no saturation. This may be due to the material being the first example of a compensated semimetal, in which the number of mobile holes is the same as the number of electrons. Tungsten ditelluride has layered structure, similar to many other transition metal dichalcogenides, but its layers are so distorted that the honeycomb lattice many of them have in common is in WTe2 hard to recognize. The tungsten atoms instead form zigzag chains, which are thought to behave as one-dimensional conductors. Unlike electrons in other two dimensional semiconductors, the electrons in WTe2 can easily move between the layers.
Tantalum borides are compounds of tantalum and boron most remarkable for their extreme hardness.
A topological insulator is a material whose interior behaves as an electrical insulator while its surface behaves as an electrical conductor, meaning that electrons can only move along the surface of the material.
Bismuth selenide is a gray compound of bismuth and selenium also known as bismuth(III) selenide.
Molybdenum(IV) telluride, molybdenum ditelluride or just molybdenum telluride is a compound of molybdenum and tellurium with formula MoTe2, corresponding to a mass percentage of 27.32% molybdenum and 72.68% tellurium. It can crystallise in two dimensional sheets which can be thinned down to monolayers that are flexible and almost transparent. It is a semiconductor, and can fluoresce. It is part of a class of materials called transition metal dichalcogenides. As a semiconductor the band gap lies in the infrared region. This raises the potential use as a semiconductor in electronics or an infrared detector.
Weyl fermions are massless chiral fermions embodying the mathematical concept of a Weyl spinor. Weyl spinors in turn play an important role in quantum field theory and the Standard Model, where they are a building block for fermions in quantum field theory. Weyl spinors are a solution to the Dirac equation derived by Hermann Weyl, called the Weyl equation. For example, one-half of a charged Dirac fermion of a definite chirality is a Weyl fermion.
A Dirac cone is an electronic structure to describe electrons with photon-like relativistic effect in two-dimensional materials systems. Scientists believe that Dirac cones can provide a path to the next-generation computer chips, quantum computing, superconductors and desktop relativistic mechanics and technology.
The term Dirac matter refers to a class of condensed matter systems which can be effectively described by the Dirac equation. Even though the Dirac equation itself was formulated for fermions, the quasi-particles present within Dirac matter can be of any statistics. As a consequence, Dirac matter can be distinguished in fermionic, bosonic or anyonic Dirac matter. Prominent examples of Dirac matter are Graphene, topological insulators, Dirac semimetals, Weyl semimetals, various high-temperature superconductors with -wave pairing and liquid Helium-3. The effective theory of such systems is classified by a specific choice of the Dirac mass, the Dirac velocity, the Dirac matrices and the space-time curvature. The universal treatment of the class of Dirac matter in terms of an effective theory leads to a common features with respect to the density of states, the heat capacity and impurity scattering.
Nai Phuan Ong is an American experimental physicist, specializing in "condensed matter physics focusing on topological insulators, Dirac/Weyl semimetals, superconductors and quantum spin liquids."
The selenide iodides are chemical compounds that contain both selenide ions (Se2−) and iodide ions (I−) and one or metal atoms. They are in the class of mixed anion compounds or chalcogenide halides.
Zinc cadmium phosphide arsenide (Zn-Cd-P-As) is a quaternary system of group II (IUPAC group 12) and group V (IUPAC group 15) elements. Many of the inorganic compounds in the system are II-V semiconductor materials. The quaternary system of II3V2 compounds, (Zn1−xCdx)3(P1−yAsy)2, has been shown to allow solid solution continuously over the whole compositional range. This material system and its subsets have applications in electronics, optoelectronics, including photovoltaics, and thermoelectrics.
Tantalum diselenide is a compound made with tantalum and selenium atoms, with chemical formula TaSe2, which belongs to the family of transition metal dichalcogenides. In contrast to molybdenum disulfide (MoS2) or rhenium disulfide (ReS2, tantalum diselenide does not occur spontaneously in nature, but it can be synthesized. Depending on the growth parameters, different types of crystal structures can be stabilized.
Niobium phosphide is an inorganic compound of niobium and phosphorus with the chemical formula NbP.
Neodymium tantalate is an inorganic compound with the chemical formula NdTaO4. It is prepared by reacting neodymium oxide and tantalum pentoxide at 1200 °C. It reacts with a mixture of tantalum pentoxide and chlorine gas at high temperature to obtain Nd2Ta2O7Cl2. It is ammonolyzed at high temperature to obtain oxynitrides of Nd-Ta.