Aluminium lactate

Last updated
Aluminium lactate
Aluminum lactate.svg
Names
Other names
Aluminium trilactate, tris(2-hydroxypropanoato)aluminium
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.038.776 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 242-670-9
PubChem CID
  • InChI=1S/3C3H6O3.Al/c3*1-2(4)3(5)6;/h3*2,4H,1H3,(H,5,6);/q;;;+3/p-3
    Key: VXYADVIJALMOEQ-UHFFFAOYSA-K
  • CC(C(=O)O[Al](OC(=O)C(C)O)OC(=O)C(C)O)O
Properties
C9H15AlO9
Molar mass 294.192 g·mol−1
AppearanceWhite powder
Melting point 300 °C (572 °F; 573 K)
Soluble
Hazards
GHS labelling:
GHS-pictogram-exclam.svg
Warning
H315, H319, H335
P302, P305, P338, P351, P352
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Aluminium lactate is a chemical compound, a salt of aluminium and lactic acid with the formula Al(C3H5O3)3. [1] [2]

Contents

Synthesis

Aluminium lactate is obtained by precipitating a solution of the barium salt by aluminium sulfate. [3]

Physical properties

Aluminium lactate appears as a white powder which is soluble in water.

Use

Aluminium lactate is used as a mordant. [4]

It is suitable for use in both the cosmetic [5] and oral industries. [6] [7]

Aluminium lactate is also used as a precursor for sol–gel synthesis of alumina-based glasses. [8]

Related Research Articles

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Aluminium is a chemical element; it has symbol Al and atomic number 13. Aluminium has a density lower than that of other common metals; about one-third that of steel. It has a great affinity towards oxygen, forming a protective layer of oxide on the surface when exposed to air. Aluminium visually resembles silver, both in its color and in its great ability to reflect light. It is soft, nonmagnetic and ductile. It has one stable isotope: 27Al, which is highly abundant, making aluminium the twelfth-most common element in the universe. The radioactivity of 26Al is used in radiometric dating.

<span class="mw-page-title-main">Alum</span> Family of double sulfate salts of aluminium

An alum is a type of chemical compound, usually a hydrated double sulfate salt of aluminium with the general formula XAl(SO
4
)
2
·12 H
2
O
, such that X is a monovalent cation such as potassium or ammonium. By itself, "alum" often refers to potassium alum, with the formula KAl(SO
4
)
2
·12 H
2
O
. Other alums are named after the monovalent ion, such as sodium alum and ammonium alum.

<span class="mw-page-title-main">Aluminium oxide</span> Chemical compound with formula Al2O3

Aluminium oxide (or aluminium(III) oxide) is a chemical compound of aluminium and oxygen with the chemical formula Al2O3. It is the most commonly occurring of several aluminium oxides, and specifically identified as aluminium oxide. It is commonly called alumina and may also be called aloxide, aloxite, or alundum in various forms and applications. It occurs naturally in its crystalline polymorphic phase α-Al2O3 as the mineral corundum, varieties of which form the precious gemstones ruby and sapphire. Al2O3 is significant in its use to produce aluminium metal, as an abrasive owing to its hardness, and as a refractory material owing to its high melting point.

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<span class="mw-page-title-main">Aluminium hydroxide</span> Chemical compound

Aluminium hydroxide, Al(OH)3, is found in nature as the mineral gibbsite and its three much rarer polymorphs: bayerite, doyleite, and nordstrandite. Aluminium hydroxide is amphoteric, i.e., it has both basic and acidic properties. Closely related are aluminium oxide hydroxide, AlO(OH), and aluminium oxide or alumina, the latter of which is also amphoteric. These compounds together are the major components of the aluminium ore bauxite. Aluminium hydroxide also forms a gelatinous precipitate in water.

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<span class="mw-page-title-main">Hexafluorosilicic acid</span> Octahedric silicon compound

Hexafluorosilicic acid is an inorganic compound with the chemical formula H
2
SiF
6
. Aqueous solutions of hexafluorosilicic acid consist of salts of the cation and hexafluorosilicate anion. These salts and their aqueous solutions are colorless.

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Lithium aluminate, also called lithium aluminium oxide, is an inorganic chemical compound, an aluminate of lithium. In microelectronics, lithium aluminate is considered as a lattice matching substrate for gallium nitride. In nuclear technology, lithium aluminate is of interest as a solid tritium breeder material, for preparing tritium fuel for nuclear fusion. Lithium aluminate is a layered double hydroxide (LDH) with a crystal structure resembling that of hydrotalcite. Lithium aluminate solubility at high pH is much lower than that of aluminium oxides. In the conditioning of low- and intermediate level radioactive waste (LILW), lithium nitrate is sometimes used as additive to cement to minimise aluminium corrosion at high pH and subsequent hydrogen production. Indeed, upon addition of lithium nitrate to cement, a passive layer of LiH(AlO
2
)
2
· 5 H
2
O
is formed onto the surface of metallic aluminium waste immobilised in mortar. The lithium aluminate layer is insoluble in cement pore water and protects the underlying aluminium oxide covering the metallic aluminium from dissolution at high pH. It is also a pore filler. This hinders the aluminium oxidation by the protons of water and reduces the hydrogen evolution rate by a factor of 10.

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3
CO
2
)
3
. Under standard conditions it appears as a white, water-soluble solid that decomposes on heating at around 200 °C. The triacetate hydrolyses to a mixture of basic hydroxide / acetate salts, and multiple species co-exist in chemical equilibrium, particularly in aqueous solutions of the acetate ion; the name aluminium acetate is commonly used for this mixed system.

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References

  1. Vargel, Christian (12 May 2020). Corrosion of Aluminium. Elsevier. p. 748. ISBN   978-0-08-099927-2 . Retrieved 24 January 2022.
  2. "Aluminum L-lactate". American Elements . Retrieved 24 January 2022.
  3. Proceedings of the American Pharmaceutical Association at the Annual Meeting. American Pharmaceutical Association. 1887. p. 291. Retrieved 24 January 2022.
  4. "Aluminium Lactate - mordant for natural dyeing plant (cellulose) fibres". DT Craft and Design. 14 August 2021. Retrieved 24 January 2022.
  5. Hunt, Laura; Tankeu, Raissa; Thilk, Alexia; Coppenrath, Valerie (2014). "Ammonium Lactate–Containing Moisturizers: A Systematic Review". U.S. Pharmacist . 39 (11): 46–49. Retrieved 24 January 2022.
  6. "Aluminium Lactate by DPL-US - Personal Care & Cosmetics". ulprospector.com. Retrieved 24 January 2022.
  7. Lussi, Adrian (1 January 2006). Dental Erosion: From Diagnosis to Therapy. Karger Medical and Scientific Publishers. p. 182. ISBN   978-3-8055-8097-7 . Retrieved 24 January 2022.
  8. Zhang, Long; de Araujo, Carla C.; Eckert, Hellmut (May 2007). "Aluminum lactate – An attractive precursor for sol–gel synthesis of alumina-based glasses". Journal of Non-Crystalline Solids . 353 (13–15): 1255–1260. Bibcode:2007JNCS..353.1255Z. doi:10.1016/j.jnoncrysol.2006.10.065.