Names | |||
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Other names Aluminum phosphate Aluminium monophosphate Phosphoric acid, aluminium salt (1:1) | |||
Identifiers | |||
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3D model (JSmol) | |||
ChEMBL | |||
ChemSpider | |||
DrugBank | |||
ECHA InfoCard | 100.029.142 | ||
EC Number |
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PubChem CID | |||
RTECS number |
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UNII | |||
UN number | 1760 | ||
CompTox Dashboard (EPA) | |||
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Properties | |||
AlPO4 | |||
Molar mass | 121.9529 g/mol | ||
Appearance | White, crystalline powder | ||
Density | 2.566 g/cm3, solid | ||
Melting point | 1,800 °C (3,270 °F; 2,070 K) | ||
Boiling point | Decomposes | ||
1.89×10−9 g/100 ml [1] | |||
Solubility product (Ksp) | 9.84×10−21 [1] | ||
Solubility | Very slightly soluble in HCl and HNO3 | ||
Refractive index (nD) | 1.546 [2] | ||
Pharmacology | |||
A02AB03 ( WHO ) | |||
Hazards | |||
GHS labelling: | |||
Warning | |||
H314, H315, H319, H332, H335 | |||
P260, P261, P264, P271, P280, P301+P330+P331, P302+P352, P303+P361+P353, P304+P312, P304+P340, P305+P351+P338, P310, P312, P321, P332+P313, P337+P313, P362, P363, P403+P233, P405, P501 | |||
NFPA 704 (fire diamond) | |||
Lethal dose or concentration (LD, LC): | |||
LD50 (median dose) | 4640 mg/kg (rat, oral) > 4640 mg/kg (rabbit, dermal) | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Aluminium phosphate is a chemical compound. In nature it occurs as the mineral berlinite. [3] Many synthetic forms of aluminium phosphate are known. They have framework structures similar to zeolites and some are used as catalysts, ion-exchangers or molecular sieves. [4] Commercial aluminium phosphate gel is available.
AlPO4 is isoelectronic with Si2O4, silicon dioxide. Berlinite looks like quartz and has a structure that is similar to quartz with silicon replaced by Al and P. The AlO4 and PO4 tetrahedra alternate. Like quartz, AlPO4 exhibits chirality [5] and piezoelectric properties. [6] When heated, crystalline AlPO4 (berlinite) converts to tridymite and cristobalite forms, and this mirrors the behaviour of silicon dioxide. [7]
There are many types of aluminium phosphate molecular sieves, generically known as "ALPOs". The first ones were reported in 1982. [8] They all share the same chemical composition of AlPO4 and have framework structures with microporous cavities. The frameworks are made up of alternating AlO4 and PO4 tetrahedra. The denser cavity-less crystalline berlinite, shares the same alternating AlO4 and PO4 tetrahedra. [7] The aluminophosphate framework structures vary one from another in the orientation of the AlO4 tetrahedra and PO4 tetrahedra to form different-sized cavities, and in this respect they are similar to the aluminosilicate zeolites, which differ in having electrically charged frameworks. A typical preparation of an aluminophosphate involves the hydrothermal reaction of phosphoric acid and aluminium in the form of hydroxide, an aluminium salt such as aluminium nitrate salt or alkoxide under controlled pH in the presence of organic amines. [9] These organic molecules act as templates (now termed structure directing agents, SDAs) to direct the growth of the porous framework. [10]
Along with aluminium hydroxide, aluminium phosphate is one of the most common immunologic adjuvants (efficiency enhancers) in vaccinations. Aluminium adjuvant use is widespread due to its cheap price, long history of use, safety and efficiency with most antigens.
Similar to aluminium hydroxide, AlPO4 is used as an antacid. It neutralizes stomach acid (HCl) by forming AlCl3 with it. Up to 20% of aluminium from ingested antacid salts can be absorbed from the gastrointestinal tract – despite some unverified concerns about the neurological effects of aluminium, [11] aluminium phosphate and hydroxide salts are thought to be safe as antacids in normal use, even during pregnancy and breastfeeding. [12] [11]
Additional uses for AlPO4 in combination with or without other compounds are white colorants for pigments, corrosion inhibitors, cements and dental cements. Related compounds have also similar uses. For example, Al(H2PO4)3 is used in dental cements, metal coatings, glaze compositions and refractory binders; and Al(H2PO4)(HPO4) is used cement and refractory binders and adhesives. [13]
AlPO4·2H2O dihydrate is found as the minerals variscite and meta-variscite. [14] Aluminium phosphate dihydrate (variscite and meta-variscite) has a structure that can be regarded as an assembly of tetra- and octahedral units of phosphate anions, aluminium cations and water. Al3+ ions are 6-coordinate and PO43- ions are 4-coordinate. [3]
A synthetic hydrated form, AlPO4·1.5H2O is also known. [15]
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula SiO2, commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is abundant as it comprises several minerals and synthetic products. All forms are white or colorless, although impure samples can be colored.
Zeolite is a family of several microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula Mn+
1/n(AlO
2)−
(SiO
2)
x・yH
2O where Mn+
1/n is either a metal ion or H+. These positive ions can be exchanged for others in a contacting electrolyte solution. H+
exchanged zeolites are particularly useful as solid acid catalysts.
An oxyanion, or oxoanion, is an ion with the generic formula A
xOz−
y. Oxyanions are formed by a large majority of the chemical elements. The formulae of simple oxyanions are determined by the octet rule. The corresponding oxyacid of an oxyanion is the compound H
zA
xO
y. The structures of condensed oxyanions can be rationalized in terms of AOn polyhedral units with sharing of corners or edges between polyhedra. The oxyanions adenosine monophosphate (AMP), adenosine diphosphate (ADP) and adenosine triphosphate (ATP) are important in biology.
Calcium sulfate (or calcium sulphate) is the inorganic compound with the formula CaSO4 and related hydrates. In the form of γ-anhydrite (the anhydrous form), it is used as a desiccant. One particular hydrate is better known as plaster of Paris, and another occurs naturally as the mineral gypsum. It has many uses in industry. All forms are white solids that are poorly soluble in water. Calcium sulfate causes permanent hardness in water.
The term calcium phosphate refers to a family of materials and minerals containing calcium ions (Ca2+) together with inorganic phosphate anions. Some so-called calcium phosphates contain oxide and hydroxide as well. Calcium phosphates are white solids of nutritional value and are found in many living organisms, e.g., bone mineral and tooth enamel. In milk, it exists in a colloidal form in micelles bound to casein protein with magnesium, zinc, and citrate–collectively referred to as colloidal calcium phosphate (CCP). Various calcium phosphate minerals are used in the production of phosphoric acid and fertilizers. Overuse of certain forms of calcium phosphate can lead to nutrient-containing surface runoff and subsequent adverse effects upon receiving waters such as algal blooms and eutrophication (over-enrichment with nutrients and minerals).
Brazilianite, whose name derives from its country of origin, Brazil, is a typically yellow-green phosphate mineral, most commonly found in phosphate-rich pegmatites.
Sodium aluminate is an inorganic chemical that is used as an effective source of aluminium hydroxide for many industrial and technical applications. Pure sodium aluminate (anhydrous) is a white crystalline solid having a formula variously given as NaAlO2, NaAl(OH)4 (hydrated), Na2O·Al2O3, or Na2Al2O4. Commercial sodium aluminate is available as a solution or a solid.
Other related compounds, sometimes called sodium aluminate, prepared by reaction of Na2O and Al2O3 are Na5AlO4 which contains discrete AlO45− anions, Na7Al3O8 and Na17Al5O16 which contain complex polymeric anions, and NaAl11O17, once mistakenly believed to be β-alumina, a phase of aluminium oxide.
In chemistry, an aluminate is a compound containing an oxyanion of aluminium, such as sodium aluminate. In the naming of inorganic compounds, it is a suffix that indicates a polyatomic anion with a central aluminium atom.
Dicalcium phosphate is the calcium phosphate with the formula CaHPO4 and its dihydrate. The "di" prefix in the common name arises because the formation of the HPO42– anion involves the removal of two protons from phosphoric acid, H3PO4. It is also known as dibasic calcium phosphate or calcium monohydrogen phosphate. Dicalcium phosphate is used as a food additive, it is found in some toothpastes as a polishing agent and is a biomaterial.
Silicon compounds are compounds containing the element silicon (Si). As a carbon group element, silicon often forms compounds in the +4 oxidation state, though many unusual compounds have been discovered that differ from expectations based on its valence electrons, including the silicides and some silanes. Metal silicides, silicon halides, and similar inorganic compounds can be prepared by directly reacting elemental silicon or silicon dioxide with stable metals or with halogens. Silanes, compounds of silicon and hydrogen, are often used as strong reducing agents, and can be prepared from aluminum–silicon alloys and hydrochloric acid.
ZSM-5, Zeolite Socony Mobil–5 (framework type MFI from ZSM-5 (five)), is an aluminosilicate zeolite belonging to the pentasil family of zeolites. Its chemical formula is NanAlnSi96–nO192·16H2O (0<n<27). Patented by Mobil Oil Company in 1975, it is widely used in the petroleum industry as a heterogeneous catalyst for hydrocarbon isomerization reactions.
Berlinite (aluminium phosphate, chemical formula AlPO4 or Al(PO4)) is a rare high-temperature hydrothermal or metasomatic phosphate mineral. It has the same crystal structure as quartz with a low temperature polytype isostructural with α–quartz and a high temperature polytype isostructural with β–quartz. Berlinite can vary from colorless to greyish or pale pink and has translucent crystals.
In chemistry, germanate is a compound containing an oxyanion of germanium. In the naming of inorganic compounds it is a suffix that indicates a polyatomic anion with a central germanium atom, for example potassium hexafluorogermanate, K2GeF6.
This list gives an overview of the classification of non-silicate minerals and includes mostly International Mineralogical Association (IMA) recognized minerals and its groupings. This list complements the List of minerals recognized by the International Mineralogical Association series of articles and List of minerals. Rocks, ores, mineral mixtures, not IMA approved minerals, not named minerals are mostly excluded. Mostly major groups only, or groupings used by New Dana Classification and Mindat.
The pozzolanic activity is a measure for the degree of reaction over time or the reaction rate between a pozzolan and Ca2+ or calcium hydroxide (Ca(OH)2) in the presence of water. The rate of the pozzolanic reaction is dependent on the intrinsic characteristics of the pozzolan such as the specific surface area, the chemical composition and the active phase content.
Boron phosphate is an inorganic compound with the chemical formula BPO4. The simplest way of producing it is the reaction of phosphoric acid and boric acid. It is a white infusible solid that evaporates above 1450 °C.
Aluminium arsenate is an inorganic compound with the formula AlAsO4. It is most commonly found as an octahydrate. It is a colourless solid that is produced by the reaction between sodium arsenate and a soluble aluminium salt. Aluminium arsenate occurs naturally as the mineral mansfieldite. Anhydrous form is known as an extremely rare, fumarolic mineral alarsite A synthetic hydrate of aluminium arsenate is produced by hydrothermal method. with the formulation Al2O3·3As2O5·10H2O.
Tetracalcium phosphate is the compound Ca4(PO4)2O, (4CaO·P2O5). It is the most basic of the calcium phosphates, and has a Ca/P ratio of 2, making it the most phosphorus poor phosphate. It is found as the mineral hilgenstockite, which is formed in industrial phosphate rich slag (called "Thomas slag"). This slag was used as a fertiliser due to the higher solubility of tetracalcium phosphate relative to apatite minerals. Tetracalcium phosphate is a component in some calcium phosphate cements that have medical applications.
The phosphate sulfates are mixed anion compounds containing both phosphate and sulfate ions. Related compounds include the arsenate sulfates, phosphate selenates, and arsenate selenates.