Phosphatoantimonate

Last updated

Phosphatoantimonates are compounds that contain anions that contain phosphorus and antimony in the +5 oxidation state, along with oxygen. Thus they are a compound of phosphate and antimonate, bound together by oxygen.

phosphatoantimonates have been investigated as catalysts, [1] and ion exchange materials. [2]

List

formulamwcrystal systemspace groupunit cell Åvolumedensitycommentreferences
SbOPO4monoclinicC2ca = 6.791 b = 8.033 c = 7.046 β = 115.90° Z=4 [3]
SbIIISbV3(PO4)6trigonalR3a = 16.880 c = 21.196 Z=125230mixed valence [4]
HSb(PO4)2·2H2Olayered; can be exfoliated; can exchange H+ with other ions; can reversibly dehydrate [5] [6]
H3Sb3P2O14•xH2Olayered [7]
H5Sb5P2O20•xH2O3D with channels [7]
Li5Sb5P2O20 [8]
(NH4)3Sb3P2O14•3H2O [9]
Na3SbO(PO4)2orthorhombicP212121a = 6.964 b = 9.284 c = 12.425 Z = 41D [10] [11]
Na3Sb3P2O14 [8]
Na5Sb5P2O20 [8]
Mg0.50SbFe(PO4)3hexagonalP3a = 8.3443 c = 22.3629 Z=6nasicon [12]
KSb2PO8monoclinicCca=12.306 b=7.086 c=15.037 β=95.82° Z=81304.54.498colourless; 3D [13] [14]
KSb2PO8−xNy [15]
KSbP2O8rhombohedralR3a = 4.7623 c = 25.409 Z = 32D [13] [16]
K2SbPO6orthorhombicPnmaa= 9.429 b= 5.891 c= 11.030 Z= 41D [13] [17]
4K2O · 4Sb2O5 · P2O5 · 8H2O

K8Sb8P2O29·8H2O

monovlinica = 23.952 b = 9.515 c = 8.193 β = 124.77°31P NMR shift −−6.77 ppm [18] [19]
K3Sb3P2O14rhombohedralR3ma = 7.147 c = 30.936 Z = 3reversible hydration; 2D [13] [20]
K3Sb3P2O14, 1.32H2OrhombohedralR3ma = 7.147 c = 30.936 Z=3 [21]
K3Sb3P2O14·5H2OhexagonalP3Z=6 [22]
K5Sb5P2O20orthorhombicPnnma= 23.443 b= 18.452 c= 7.149 z= 63D [13] [23]
K2SbAs0.5P0.5O6orthorhombic [24]
ScSbV3(PO4)6monoclinicP21/na=11.810 b=8.616 c=8.400 β=90.80°854.6 [4]
NaSbCr(PO4)3rhombohedralR3a = 8.329 c = 22.094 Z=61327nasicon [25]
Ca0.5AlSb(PO4)3a=8.56 c=21.874.128nasicon [26]
Mn0.50SbFe(PO4)3rhombohedralR3a=8.375 c=21.597nasicon [27] [28]
Mn0.5AlSb(PO4)3rhombohedralR3ca=8.270 c=21,7993.56nasicon [26]
Ca0.5CrSb(PO4)3a=8.61 c=22.084.321nasicon [26]
Mn0.5CrSb(PO4)3monoclinicP21/na=12.280 b=8.814 c=8.613 β=91.03°3.45 [26]
Sb1.50Fe0.50(PO4)3hexagonalR32a=8.305 c=22.035 [29]
(Sb0.50Fe0.50)P2O7orthorhombicPna21a=7.865 b=15.699 c=7.847pyrophosphate [29]
CaSb0.50Fe1.50(PO4)3rhombohedralR3ca=8.514 c=21.871nasicon [30]
Ca0.50SbFe(PO4)3rhombohedralR3a=8.257 c=22.276nasicon [27] [30]
Mn0.5FeSb(PO4)3rhombohedralR3ca=8.374 c=21.5933.68nasicon [26]
NaSbFe(PO4)3rhombohedralR3a = 8.361 c = 22.222 Z=61345nasicon [25]
Co[Sb(PO4)2]2·6H2O [5]
Ni0.50SbFe(PO4)3hexagonalP3a = 8.3384 c = 22.3456nasicon [12]
Rb3Sb3P2O14 [8]
Rb3Sb3P2O14•3H2OrhombohedralR3ma=7.1445 c=31.802 [9]
Rb5Sb5P2O20 [8]
Sr0.50SbFe(PO4)3rhombohedralR3a = 8.227 c = 22.767nasicon [27]
SrSb0.50Cr0.50(PO4)2monoclinicC2/ca= 16.5038 b= 5.1632 c= 8.0410 β = 115.85° Z=4617yavapaiite [31]
SrSb0.50Fe1.50(PO4)3rhombohedralR3ca = 8.339 c = 22.704nasicon [27]
Sr(SbV0.50FeIII0.50)(PO4)2monoclinicC2/ca = 16.5215 b = 5.1891 c = 8.0489 β = 115.70° Z=4yavapaiite [32]
Sr(Ga0.5Sb0.5)(PO4)2monoclinicC2/ca=16.455; b=5.158 c= 8.005 β=115.49° Z=4613 [33]
YSbV3(PO4)6R3a=17.019 c=21.2335326 [4]
Cd0.50SbFe(PO4)3rhombohedralR3a=8.313 c=21.996nasicon [27] [28]
SbV1.50InIII0.50(PO4)3monoclinicP21/na=11.801 b=8.623 c=8.372 β=90.93° [34]
SbV0.50InIII0.50P2O7orthorhombicPna21a=7.9389 b=16.0664 c=7.9777pyrophosphate [34]
InSbV3(PO4)6monoclinicP21/na=11.792 b=8.622 c=8.379 β=90.91°851.8 [4]
NaSbIn(PO4)3rhombohedralR3a=8.329 c = 23.031 Z=61383nasicon [25]
Cs3Sb3P2O14•3H2OrhombohedralR3ma=7.153 c=32.840 [9]
Cs4MgSb6P4O281858.39tetragonalI41/aa=16.5170 c=10.7355 Z=42928.84.22band gap 4.50 eV [35]
Cs4ZnSb6P4O28tetragonalI41/aa=16.4821 c=10.7453 Z=42919.14.32band gap 4.48 eV [35]
K0.8Ba1.6Sb4O9(PO4)2 (0 < x < 0.4)orthorhombicPnmaa = 20.998 b = 7.168 c = 9.569 [36]
Ba2Sb4O9(PO4)2orthorhombicPnmaa = 20.9237 b = 7.1836 c = 9.5189 Z = 4 [36]
BaSb0.50Cr0.50(PO4)2monoclinicC2/ma= 8.140 b= 5.175 c= 7.802 β = 94. 387° Z=2328yavapaiite [31]
BaSb2/3Mn1/3(PO4)2monoclinicC2/ma= b= c=7.8808 β=94.4° Z=2337 [37]
Ba(Sb0.50FeIII0.50)(PO4)2monoclinicC2/ma = 8.1568 b = 5.1996 c = 7.8290 β = 94.53° Z=2yavapaiite [32]
BaSb2/3Co1/3(PO4)2monoclinicC2/mc=7.8581 β=94.7° Z=2333 [37]
BaSb2/3Cu1/3(PO4)2monoclinicC2/mc=7.8795 β=95.3° Z=2331 [37]
BaSb2/3Zn1/3(PO4)2monoclinicC2/mc=7.8497 β=94.8° Z=2332 [37]
Ba(Ga0.5Sb0.5)(PO4)2monoclinicC2/ma= 8.106 b= 5.178 c= 7.806 β=94.79° Z=2327 [33]
Tl3Sb3P2O14•3H2OrhombohedralR3ma=7.135 c=31.447 [9]
PbSb0.50Cr0.50(PO4)2monoclinicC2/ca= 16.684 b= 5.156 c= 8.115 β = 115.35° Z=4631yavapaiite [31]
Pb(Sb0.50FeIII0.50)(PO4)2monoclinicC2/ca = 16.6925 b = 5.1832 c = 8.1215 β = 115.03°yavapaiite [32]
PbSb0.50Fe1.50(PO4)3rhombohedralR3ca = 8.313 c = 23.000 Z=61377nasicon [38]
Pb0.50SbFe(PO4)3rhombohedralR3a = 8.2397 c = 22.7801 Z=61339nasicon [38]
Pb(Ga0.5Sb0.5)(PO4)2monoclinicC2/ca=16.622 b=5.163 c=8.067 β=114.85°628 [33]
BiSbV3(PO4)6trigonalR3a=17.034 c=21.2605342.1 [4]
CaSb0.50Bi1.50(PO4)3monoclinicP21/ma = 4.9358 b = 6.9953 c = 4.7075 β = 96.2° [39]

Related Research Articles

<span class="mw-page-title-main">Phosphide</span>

In chemistry, a phosphide is a compound containing the P3− ion or its equivalent. Many different phosphides are known, with widely differing structures. Most commonly encountered on the binary phosphides, i.e. those materials consisting only of phosphorus and a less electronegative element. Numerous are polyphosphides, which are solids consisting of anionic chains or clusters of phosphorus. Phosphides are known with the majority of less electronegative elements with the exception of Hg, Pb, Sb, Bi, Te, and Po. Finally, some phosphides are molecular.

<span class="mw-page-title-main">Tricalcium phosphate</span> Chemical compound

Tricalcium phosphate (sometimes abbreviated TCP), more commonly known as Calcium phosphate, is a calcium salt of phosphoric acid with the chemical formula Ca3(PO4)2. It is also known as tribasic calcium phosphate and bone phosphate of lime (BPL). It is a white solid of low solubility. Most commercial samples of "tricalcium phosphate" are in fact hydroxyapatite.

<span class="mw-page-title-main">Iron(III) phosphate</span> Chemical compound

Iron(III) phosphate, also ferric phosphate, is the inorganic compound with the formula FePO4. Four polymorphs of anhydrous FePO4 are known. Additionally two polymorphs of the dihydrate FePO4·(H2O)2 are known. These materials have attracted much interest as potential cathode materials in batteries.

In chemistry, hypomanganate, also called manganate(V) or tetraoxidomanganate(3−), is a trivalent anion (negative ion) composed of manganese and oxygen, with formula MnO3−
4.

<span class="mw-page-title-main">Lithium iron phosphate battery</span> Type of rechargeable battery

The lithium iron phosphate battery or LFP battery is a type of lithium-ion battery using lithium iron phosphate as the cathode material, and a graphitic carbon electrode with a metallic backing as the anode. Because of their low cost, high safety, low toxicity, long cycle life and other factors, LFP batteries are finding a number of roles in vehicle use, utility-scale stationary applications, and backup power. LFP batteries are cobalt-free. As of September 2022, LFP type battery market share for EVs reached 31%, and of that, 68% was from Tesla and Chinese EV maker BYD production alone. Chinese manufacturers currently hold a near monopoly of LFP battery type production. With patents having started to expire in 2022 and the increased demand for cheaper EV batteries, LFP type production is expected to rise further and surpass lithium nickel manganese cobalt oxides (NMC) type batteries in 2028.

<span class="mw-page-title-main">Lithium iron phosphate</span> Chemical compound

Lithium iron phosphate or lithium ferro-phosphate (LFP) is an inorganic compound with the formula LiFePO
4. It is a gray, red-grey, brown or black solid that is insoluble in water. The material has attracted attention as a component of lithium iron phosphate batteries, a type of Li-ion battery. This battery chemistry is targeted for use in power tools, electric vehicles, solar energy installations and more recently large grid-scale energy storage.

<span class="mw-page-title-main">Copper(II) phosphate</span> Chemical compound

Copper(II) phosphate are inorganic compounds with the formula Cu3(PO4)2. They can be regarded as the cupric salts of phosphoric acid. Anhydrous copper(II) phosphate and a trihydrate are blue solids.

Langbeinites are a family of crystalline substances based on the structure of langbeinite with general formula M2M'2(SO4)3, where M is a large univalent cation, and M' is a small divalent cation. The sulfate group, SO2−4, can be substituted by other tetrahedral anions with a double negative charge such as tetrafluoroberyllate, selenate, chromate, molybdate, or tungstates. Although monofluorophosphates are predicted, they have not been described. By redistributing charges other anions with the same shape such as phosphate also form langbeinite structures. In these the M' atom must have a greater charge to balance the extra three negative charges.

<span class="mw-page-title-main">Cobalt(II) phosphate</span> Chemical compound

Cobalt phosphate is the inorganic compound with the formula Co3(PO4)2. It is a commercial inorganic pigment known as cobalt violet. Thin films of this material are water oxidation catalysts.

<span class="mw-page-title-main">NASICON</span> Class of solid materials

NASICON is an acronym for sodium (Na) super ionic conductor, which usually refers to a family of solids with the chemical formula Na1+xZr2SixP3−xO12, 0 < x < 3. In a broader sense, it is also used for similar compounds where Na, Zr and/or Si are replaced by isovalent elements. NASICON compounds have high ionic conductivities, on the order of 10−3 S/cm, which rival those of liquid electrolytes. They are caused by hopping of Na ions among interstitial sites of the NASICON crystal lattice.

Tetracalcium phosphate is the compound Ca4(PO4)2O, (4CaO·P2O5). It is the most basic of the calcium phosphates, and has a Ca/P ratio of 2, making it the most phosphorus poor phosphate. It is found as the mineral hilgenstockite, which is formed in industrial phosphate rich slag (called "Thomas slag"). This slag was used as a fertiliser due to the higher solubility of tetracalcium phosphate relative to apatite minerals. Tetracalcium phosphate is a component in some calcium phosphate cements that have medical applications.

<span class="mw-page-title-main">Iron(III) pyrophosphate</span> Chemical compound

Iron(III) pyrophosphate is an inorganic chemical compound with the formula Fe4(P2O7)3.

Nickel is one of the metals that can form Tutton's salts. The singly charged ion can be any of the full range of potassium, rubidium, cesium, ammonium (), or thallium. As a mineral the ammonium nickel salt, (NH4)2Ni(SO4)2 · 6 H2O, can be called nickelboussingaultite. With sodium, the double sulfate is nickelblödite Na2Ni(SO4)2 · 4 H2O from the blödite family. Nickel can be substituted by other divalent metals of similar sized to make mixtures that crystallise in the same form.

The fluoride phosphates or phosphate fluorides are inorganic double salts that contain both fluoride and phosphate anions. In mineralogy, Hey's Chemical Index of Minerals groups these as 22.1. The Nickel-Strunz grouping is 8.BN.

Borate phosphates are mixed anion compounds containing separate borate and phosphate anions. They are distinct from the borophosphates where the borate is linked to a phosphate via a common oxygen atom. The borate phosphates have a higher ratio of cations to number of borates and phosphates, as compared to the borophosphates.

Antimony phosphate, is a chemical compound of antimony and phosphate with formula SbPO4. Antimony is in the form Sb(III) with +3 oxidation state. Antimony atoms have a lone pair of electrons.

<span class="mw-page-title-main">Lithium aluminium germanium phosphate</span> Chemical compound

Lithium aluminium germanium phosphate, typically known with the acronyms LAGP or LAGPO, is an inorganic ceramic solid material whose general formula is Li
1+xAl
xGe
2-x(PO
4)
3. LAGP belongs to the NASICON family of solid conductors and has been applied as a solid electrolyte in all-solid-state lithium-ion batteries. Typical values of ionic conductivity in LAGP at room temperature are in the range of 10–5 - 10–4 S/cm, even if the actual value of conductivity is strongly affected by stoichiometry, microstructure, and synthesis conditions. Compared to lithium aluminium titanium phosphate (LATP), which is another phosphate-based lithium solid conductor, the absence of titanium in LAGP improves its stability towards lithium metal. In addition, phosphate-based solid electrolytes have superior stability against moisture and oxygen compared to sulfide-based electrolytes like Li
10GeP
2S
12 (LGPS) and can be handled safely in air, thus simplifying the manufacture process. Since the best performances are encountered when the stoichiometric value of x is 0.5, the acronym LAGP usually indicates the particular composition of Li
1.5Al
0.5Ge
1.5(PO
4)
3, which is also the typically used material in battery applications.

<span class="mw-page-title-main">Oxalate phosphate</span> Chemical compound containing oxalate and phosphate anions

The oxalate phosphates are chemical compounds containing oxalate and phosphate anions. They are also called oxalatophosphates or phosphate oxalates. Some oxalate-phosphate minerals found in bat guano deposits are known. Oxalate phosphates can form metal organic framework compounds.

The phosphate sulfates are mixed anion compounds containing both phosphate and sulfate ions. Related compounds include the arsenate sulfates, phosphate selenates, and arsenate selenates.

Hexagonal ferrites or hexaferrites are a family of ferrites with hexagonal crystal structure. The most common member is BaFe12O19, also called barium ferrite, BaM, etc. BaM is a strong room-temperature ferrimagnetic material with high anisotropy along the c axis. All the hexaferrite members are constructed by stacking a few building blocks in a certain order.

References

  1. ↑ Natarajan, Srinivasan; Thomas, John M. (February 1992). "The search for new solid acid catalysts: systems derived from phosphatoantimonates". Catalysis Today. 12 (4): 433–441. doi:10.1016/0920-5861(92)80060-Z.
  2. ↑ Guo, Yan-Ling; Sun, Hai-Yan; Zeng, Xi; Lv, Tian-Tian; Yao, Yue-Xin; Zhuang, Ting-Hui; Feng, Mei-Ling; Huang, Xiao-Ying (March 2023). "Efficient removal of Sr2+ ions by a one-dimensional potassium phosphatoantimonate". Chemical Engineering Journal. 460: 141697. doi:10.1016/j.cej.2023.141697.
  3. ↑ Piffard, Y.; Oyetola, S.; Verbaere, A.; Tournoux, M. (June 1986). "Synthesis, thermal stability, and crystal structure of antimony(V) phosphate SbOPO4". Journal of Solid State Chemistry. 63 (1): 81–85. doi:10.1016/0022-4596(86)90155-6.
  4. 1 2 3 4 5 Kasahara, Kenzo; Imoto, Hideo; Saito, Taro (August 1995). "Preparation and Crystal Structure of a New Form of Sb2(PO4)3 and M1/2SbV3/2(PO4)3 (M = Y, In, and Sc)". Journal of Solid State Chemistry. 118 (1): 104–111. doi:10.1006/jssc.1995.1317.
  5. 1 2 Hudson, Michael J.; Locke, William; Mitchell, Philip C. H. (1995). "Ion-exchange and protonic species in the antimony hydrogen phosphate HSb(PO 4 ) 2 ·2H 2 O". J. Mater. Chem. 5 (1): 159–163. doi:10.1039/JM9950500159. ISSN   0959-9428.
  6. ↑ Prasad, G.K.; Kumada, N.; Yamanaka, J.; Yonesaki, Y.; Takei, T.; Kinomura, N. (May 2006). "Lamellar nanocomposites based on exfoliated nanosheets and ionic polyacetylenes". Journal of Colloid and Interface Science. 297 (2): 654–659. Bibcode:2006JCIS..297..654P. doi:10.1016/j.jcis.2005.11.004. PMID   16364352.
  7. 1 2 Deniard-Courant, S (July 1988). "Relative humidity influence on the water content and on the protonic conductivity of the phosphatoantimonic acids HnSbnP2O3n+5, xH2O (n = 1, 3, 5)". Solid State Ionics. 27 (3): 189–194. doi:10.1016/0167-2738(88)90009-4.
  8. 1 2 3 4 5 Wang, E.; Greenblatt, M. (1991-07-01). "Ionic conductivities of ion-exchanged alkali metal phosphatoantimonate (A2Sb3P2O14, A = sodium, potassium, rubidium), A5Sb5P2O20 (A =lithium, sodium, potassium, rubidium), and partially substituted potassium phosphatoantimonato niobate or potassium phosphatoantimonato tantalate (K5Sb5-xMxP2O20, M = niobium, tantalum)". Chemistry of Materials. 3 (4): 703–709. doi:10.1021/cm00016a026. ISSN   0897-4756.
  9. 1 2 3 4 Walko, Priyanka S.; Paidi, Anil Kumar; Vidyasagar, Kanamaluru (2017-12-11). "Syntheses and Structural Characterization of A 3 Sb 3 P 2 O 14 ⋅3H 2 O ( A =Rb, Cs, Tl and NH 4 ) Phosphates; Facile Aqueous Ion Exchange Reactions of K 3 Sb 3 P 2 O 14 ⋅3H 2 O". ChemistrySelect. 2 (35): 11875–11879. doi:10.1002/slct.201702401. ISSN   2365-6549.
  10. ↑ Velchuri, Radha; Kadari, Ramaswamy; Ravi, Gundeboina; Munirathnam, Nagegownivari R.; Vithal, Muga (April 2015). "Effect of Cation/Anion Co-doping on the Photocatalytic Performance of Na 3 SbO(PO 4 ) 2". Zeitschrift für anorganische und allgemeine Chemie. 641 (5): 935–940. doi:10.1002/zaac.201400557. ISSN   0044-2313.
  11. ↑ Guyomard, D.; Pagnoux, C.; Letho, J.J.Zah; Verbaere, A.; Piffard, Y. (February 1991). "Preparation and crystal structure of Na3SbO(PO4)2". Journal of Solid State Chemistry. 90 (2): 367–372. doi:10.1016/0022-4596(91)90154-A.
  12. 1 2 Aatiq, Abderrahim; Marchoud, Asmaa; Bellefqih, Hajar; Tigha, My Rachid (September 2017). "Structural and Raman spectroscopic studies of the two M 0.50 SbFe(PO 4 ) 3 ( M = Mg, Ni) NASICON phases". Powder Diffraction. 32 (S1): S40–S51. Bibcode:2017PDiff..32S..40A. doi:10.1017/S0885715617000331. ISSN   0885-7156.
  13. 1 2 3 4 5 Husson, E.; Genet, F.; Lachgar, A.; Piffard, Y. (August 1988). "The vibrational spectra of some antimony phosphates". Journal of Solid State Chemistry. 75 (2): 305–312. Bibcode:1988JSSCh..75..305H. doi:10.1016/0022-4596(88)90171-5.
  14. ↑ Piffard, Y.; Lachgar, A.; Tournoux, M. (June 1985). "Crystal structure of KSb2PO8". Materials Research Bulletin. 20 (6): 715–721. doi:10.1016/0025-5408(85)90150-3.
  15. ↑ Ravi, G.; Sudhakar Reddy, Ch.; Sreenu, K.; Guje, Ravinder; Velchuri, Radha; Vithal, M. (April 2016). "Degradation of Methylene Blue and Rhodamine B Using a New Visible Light-Responsive Photocatalyst, KSb2PO8−x N y". Acta Metallurgica Sinica (English Letters). 29 (4): 335–343. doi:10.1007/s40195-016-0401-6. ISSN   1006-7191.
  16. ↑ Piffard, Y.; Oyetola, S.; Courant, S.; Lachgar, A. (November 1985). "Crystal structure of KSbP2O8". Journal of Solid State Chemistry. 60 (2): 209–213. doi:10.1016/0022-4596(85)90114-8.
  17. ↑ Lachgar, A.; Deniard-Courant, S.; Piffard, Y. (July 1986). "Preparation and crystal structure of K2SbPO6". Journal of Solid State Chemistry. 63 (3): 409–413. doi:10.1016/0022-4596(86)90198-2.
  18. ↑ An, Yonglin; Feng, Shouhua; Xu, Yihua; Xu, Ruren; Yue, Yong (November 1994). "Hydrothermal synthesis and characterization of a new potassium phosphatoantimonate". Journal of Materials Research. 9 (11): 2745–2746. Bibcode:1994JMatR...9.2745A. doi:10.1557/JMR.1994.2745. ISSN   0884-2914.
  19. ↑ An, Yonglin; Feng, Shouhua; Xu, Yihua; Xu, Ruren; Yue, Yong (1996-01-01). "Hydrothermal Synthesis and Characterization of a New Potassium Phosphatoantimonate, K 8 Sb 8 P 2 O 29 ·8H 2 O". Chemistry of Materials. 8 (2): 356–359. doi:10.1021/cm950182+. ISSN   0897-4756.
  20. ↑ Piffard, Y.; Lachgar, A.; Tournoux, M. (July 1985). "Structure cristalline du phosphatoantimonate K3Sb3P2O14". Journal of Solid State Chemistry (in French). 58 (2): 253–256. doi:10.1016/0022-4596(85)90242-7.
  21. ↑ Lachgar, A.; Deniard-Courant, S.; Piffard, Y. (April 1988). "Adsorption and structural studies of water in the layered compounds K3Sb3M2O14, xH2O (M = P, As)". Journal of Solid State Chemistry. 73 (2): 572–576. doi:10.1016/0022-4596(88)90147-8.
  22. ↑ An, Yonglin; Feng, Shouhua; Xu, Yihua; Xu, Ruren; Yue, Yong (1995). "Hydrothermal synthesis and characterization of K 3 Sb 3 A 2 O 14 ·5H 2 O (A  P,As)". J. Mater. Chem. 5 (5): 773–776. doi:10.1039/JM9950500773. ISSN   0959-9428.
  23. ↑ Piffard, Y.; Lachgar, A.; Tournoux, M. (October 1986). "A potassium phosphatoantimonate with a three dimensional framework : K5Sb5P2O20". Materials Research Bulletin. 21 (10): 1231–1238. doi:10.1016/0025-5408(86)90052-8.
  24. ↑ Botto, I.L.; Garcia, A.C. (December 1989). "Crystallographic data and vibrational spectrum of K2SbAsO6". Materials Research Bulletin. 24 (12): 1431–1439. doi:10.1016/0025-5408(89)90153-0.
  25. 1 2 3 Aatiq, Abderrahim; Tigha, My Rachid (September 2013). "Structural and spectroscopic study of NaSbR(PO 4 ) 3 (R = Cr, Fe, In) phases". Powder Diffraction. 28 (S2): S394–S408. Bibcode:2013PDiff..28S.394A. doi:10.1017/S0885715613000882. ISSN   0885-7156.
  26. 1 2 3 4 5 Anantharamulu, Navulla; Rao, K. Koteswara; Vithal, M.; Prasad, G. (June 2009). "Preparation, characterization, impedance and thermal expansion studies of Mn0.5MSb(PO4)3 (M=Al, Fe and Cr)". Journal of Alloys and Compounds. 479 (1–2): 684–691. doi:10.1016/j.jallcom.2009.01.038.
  27. 1 2 3 4 5 Aatiq, Abderrahim; Tigha, My Rachid; Benmokhtar, Said (February 2012). "Structure, infrared and Raman spectroscopic studies of new Sr0.50SbFe(PO4)3 and SrSb0.50Fe1.50(PO4)3 Nasicon phases". Journal of Materials Science. 47 (3): 1354–1364. Bibcode:2012JMatS..47.1354A. doi:10.1007/s10853-011-5910-0. ISSN   0022-2461.
  28. 1 2 Aatiq, Abderrahim; Hassine, Rabia; Tigha, My Rachid; Saadoune, Ismael (March 2005). "Structures of two newly synthesized A 0.50 SbFe(PO 4 ) 3 (A=Mn, Cd) Nasicon phases". Powder Diffraction. 20 (1): 33–39. doi:10.1154/1.1862252. ISSN   0885-7156.
  29. 1 2 Aatiq, Abderrahim; Bakri, Rachid (March 2007). "Crystal structures of newly synthesized Sb V 1.50 Fe III 0.50 (PO 4 ) 3 and (Sb V 0.50 Fe III 0.50 )P 2 O 7". Powder Diffraction. 22 (1): 47–54. doi:10.1154/1.2434788. ISSN   0885-7156.
  30. 1 2 Aatiq, Abderrahim; Tigha, My Rachid; Hassine, Rabia; Saadoune, Ismael (March 2006). "Crystallochemistry and structural studies of two newly CaSb 0.50 Fe 1.50 (PO 4 ) 3 and Ca 0.50 SbFe(PO 4 ) 3 Nasicon phases". Powder Diffraction. 21 (1): 45–51. doi:10.1154/1.2104535. ISSN   0885-7156.
  31. 1 2 3 Bellefqih, Hajar; Fakhreddine, Rachid; Tigha, Rachid; Aatiq, Abderrahim (2020). "Structure, Infrared and Raman spectroscopic studies of new AII(SbV0.50CrIII0.50)(PO4)2 (A = Ba, Sr, Pb) yavapaiite phases". Mediterranean Journal of Chemistry. 10 (8): 734–743. doi: 10.13171/mjc10802108201448hb . S2CID   225277143.
  32. 1 2 3 Aatiq, Abderrahim; Tigha, My Rachid; Fakhreddine, Rachid; Bregiroux, Damien; Wallez, Gilles (August 2016). "Structure, infrared and Raman spectroscopic studies of newly synthetic AII(SbV0.50FeIII0.50)(PO4)2 (ABa, Sr, Pb) phosphates with yavapaiite structure". Solid State Sciences. 58: 44–54. doi:10.1016/j.solidstatesciences.2016.05.009.
  33. 1 2 3 Fakhreddine, Rachid; Ouasri, Ali; Aatiq, Abderrahim (January 2024). "Synthesis, structural, morphology, spectroscopic and optical study of new metal orthophosphate MII(Ga0.5Sb0.5)(PO4)2 (MII= Sr, Pb, Ba) compounds". Journal of Solid State Chemistry. 329: 124439. doi:10.1016/j.jssc.2023.124439.
  34. 1 2 Aatiq, Abderrahim; Bakri, Rachid; Sakulich, Aaron Richard (September 2008). "Preparation and crystal structure of Sb V 1.50 In III 0.50 (PO 4 ) 3 and (Sb V 0.50 In III 0.50 )P 2 O 7". Powder Diffraction. 23 (3): 232–240. doi:10.1154/1.2955583. ISSN   0885-7156.
  35. 1 2 Zhang, Wei-Long; Guo, Zhen-Gang; Guan, Xiang-Feng; Chen, Chinghwa; He, Jiangang; Luo, Pei-Hui; Li, Xiao-Yan; Ding, Feng-Hua; Cheng, Wen-Dan (2019-05-27). "Unique 3D framework formed by adding M II O 4 groups into high Sb/P ratio phosphatoantimonates". Zeitschrift für Kristallographie - Crystalline Materials. 234 (5): 301–306. doi:10.1515/zkri-2018-2137 (inactive 2024-05-17). ISSN   2196-7105.{{cite journal}}: CS1 maint: DOI inactive as of May 2024 (link)
  36. 1 2 Pagnoux, C.; Mar, A.; Verbaere, A.; Piffard, Y. (February 1995). "Synthesis and Structure of K2xBa2-xSb4O9(PO4)2 (0 < x < 0.4)". Journal of Solid State Chemistry. 114 (2): 399–405. doi:10.1006/jssc.1995.1061.
  37. 1 2 3 4 Bellefqih, H.; Bilal, E.; Fakhreddine, R.; Mehdaoui, B.; Haneklaus, N.; Aatiq, A. (May 2024). "Structural, vibrational, and optical studies of newly synthesized Yavapaiite-type phases BaSb2/3X1/3(PO4)2 (X = Mn, Co, Cu, Zn)". Inorganic Chemistry Communications. 163: 112347. doi: 10.1016/j.inoche.2024.112347 .
  38. 1 2 "Structure and spectroscopic characterization of the two PbSb0.5Fe1.5(PO4)3 and Pb0.5SbFe(PO4)3 phosphates with Nasicon type-structure". J. Mater. Environ. Sci. 6 (12): 3483–3490. 2015.
  39. ↑ Aatiq, Abderrahim; Tigha, My Rachid (March 2014). "Structure of a new Ca II 1/3 Sb V 1/6 Bi III 1/2 PO 4 phosphate". Powder Diffraction. 29 (1): 14–19. Bibcode:2014PDiff..29...14A. doi:10.1017/S0885715613000717. ISSN   0885-7156.
This page is based on this Wikipedia article
Text is available under the CC BY-SA 4.0 license; additional terms may apply.
Images, videos and audio are available under their respective licenses.