Calcium iodide

Last updated
Calcium iodide
Cadmium-iodide-3D-balls.png
Names
IUPAC name
calcium iodide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.238 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 233-276-8
PubChem CID
RTECS number
  • EV1300000
UNII
  • InChI=1S/Ca.2HI/h;2*1H/q+2;;/p-2 Yes check.svgY
    Key: UNMYWSMUMWPJLR-UHFFFAOYSA-L Yes check.svgY
  • InChI=1/Ca.2HI/h;2*1H/q+2;;/p-2
    Key: UNMYWSMUMWPJLR-NUQVWONBAC
  • I[Ca]I
  • [Ca+2].[I-].[I-]
Properties
CaI2
Molar mass 293.887 g/mol (anhydrous)
365.95 g/mol (tetrahydrate)
Appearancewhite solid
Density 3.956 g/cm3 (anhydrous) [1]
Melting point 779 °C (1,434 °F; 1,052 K) (anhydrous) [2]
Boiling point 1,100 °C (2,010 °F; 1,370 K) [2]
64.6 g/100 mL (0 °C)
66 g/100 mL (20 °C)
81 g/100 mL (100 °C)
Solubility soluble in acetone and alcohols
-109.0·10−6 cm3/mol
Structure
Rhombohedral, hP3
P-3m1, No. 164
octahedral
Hazards
NFPA 704 (fire diamond)
NFPA 704.svgHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 0: Will not burn. E.g. waterInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no code
2
0
1
Related compounds
Other anions
calcium fluoride
calcium chloride
calcium bromide
Other cations
beryllium iodide
magnesium iodide
strontium iodide
barium iodide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Calcium iodide (chemical formula CaI2) is the ionic compound of calcium and iodine. This colourless deliquescent solid is a salt that is highly soluble in water. Its properties are similar to those for related salts, such as calcium chloride. It is used in photography. [1] It is also used in cat food as a source of iodine.

Reactions

Henri Moissan first isolated pure calcium in 1898 by reducing calcium iodide with pure sodium metal: [3]

CaI2 + 2 Na → 2 NaI + Ca

Calcium iodide can be formed by treating calcium carbonate, calcium oxide, or calcium hydroxide with hydroiodic acid: [4]

CaCO3 + 2 HI → CaI2 + H2O + CO2

Calcium iodide slowly reacts with oxygen and carbon dioxide in the air, liberating iodine, which is responsible for the faint yellow color of impure samples. [5]

2 CaI2 + 2 CO2 + O2 → 2 CaCO3 + 2 I2

Related Research Articles

<span class="mw-page-title-main">Carbonate</span> Salt of carbonic acid

A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula CO2−3. The word carbonate may also refer to a carbonate ester, an organic compound containing the carbonate groupO=C(−O−)2.

<span class="mw-page-title-main">Calcium carbonate</span> Chemical compound

Calcium carbonate is a chemical compound with the chemical formula CaCO3. It is a common substance found in rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skeletons and pearls. Materials containing much calcium carbonate or resembling it are described as calcareous. Calcium carbonate is the active ingredient in agricultural lime and is produced when calcium ions in hard water react with carbonate ions to form limescale. It has medical use as a calcium supplement or as an antacid, but excessive consumption can be hazardous and cause hypercalcemia and digestive issues.

An iodide ion is the ion I. Compounds with iodine in formal oxidation state −1 are called iodides. In everyday life, iodide is most commonly encountered as a component of iodized salt, which many governments mandate. Worldwide, iodine deficiency affects two billion people and is the leading preventable cause of intellectual disability.

<span class="mw-page-title-main">Hydrogen iodide</span> Chemical compound

Hydrogen iodide (HI) is a diatomic molecule and hydrogen halide. Aqueous solutions of HI are known as hydroiodic acid or hydriodic acid, a strong acid. Hydrogen iodide and hydroiodic acid are, however, different in that the former is a gas under standard conditions, whereas the other is an aqueous solution of the gas. They are interconvertible. HI is used in organic and inorganic synthesis as one of the primary sources of iodine and as a reducing agent.

Cyanogen iodide or iodine cyanide (ICN) is a pseudohalogen composed of iodine and the cyanide group. It is a highly toxic inorganic compound. It occurs as white crystals that react slowly with water to form hydrogen cyanide.

<span class="mw-page-title-main">Sodium iodide</span> Chemical compound

Sodium iodide (chemical formula NaI) is an ionic compound formed from the chemical reaction of sodium metal and iodine. Under standard conditions, it is a white, water-soluble solid comprising a 1:1 mix of sodium cations (Na+) and iodide anions (I) in a crystal lattice. It is used mainly as a nutritional supplement and in organic chemistry. It is produced industrially as the salt formed when acidic iodides react with sodium hydroxide. It is a chaotropic salt.

<span class="mw-page-title-main">Copper(I) iodide</span> Chemical compound

Copper(I) iodide is the inorganic compound with the formula CuI. It is also known as cuprous iodide. It is useful in a variety of applications ranging from organic synthesis to cloud seeding.

<span class="mw-page-title-main">Zinc iodide</span> Chemical compound

Zinc iodide is the inorganic compound with the formula ZnI2. It exists both in anhydrous form and as a dihydrate. Both are white and readily absorb water from the atmosphere. It has no major application.

<span class="mw-page-title-main">Calcium acetate</span> Chemical compound

Calcium acetate is a chemical compound which is a calcium salt of acetic acid. It has the formula Ca(C2H3O2)2. Its standard name is calcium acetate, while calcium ethanoate is the systematic name. An older name is acetate of lime. The anhydrous form is very hygroscopic; therefore the monohydrate (Ca(CH3COO)2•H2O) is the common form.

<span class="mw-page-title-main">Thallium(I) iodide</span> Chemical compound

Thallium(I) iodide is a chemical compound with the formula TlI. It is unusual in being one of the few water-insoluble metal iodides, along with AgI, CuI, SnI2, SnI4, PbI2 and HgI2.

Terbium(III) iodide (TbI3) is an inorganic chemical compound.

<span class="mw-page-title-main">Magnesium iodide</span> Chemical compound

Magnesium iodide is an inorganic compound with the chemical formula MgI2. It forms various hydrates MgI2·xH2O. Magnesium iodide is a salt of magnesium and hydrogen iodide. These salts are typical ionic halides, being highly soluble in water.

<span class="mw-page-title-main">Strontium iodide</span> Chemical compound

Strontium iodide (SrI2) is a salt of strontium and iodine. It is an ionic, water-soluble, and deliquescent compound that can be used in medicine as a substitute for potassium iodide . It is also used as a scintillation gamma radiation detector, typically doped with europium, due to its optical clarity, relatively high density, high effective atomic number (Z=48), and high scintillation light yield. In recent years, europium-doped strontium iodide (SrI2:Eu2+) has emerged as a promising scintillation material for gamma-ray spectroscopy with extremely high light yield and proportional response, exceeding that of the widely used high performance commercial scintillator LaBr3:Ce3+. Large diameter SrI2 crystals can be grown reliably using vertical Bridgman technique and are being commercialized by several companies.

<span class="mw-page-title-main">Beryllium iodide</span> Chemical compound

Beryllium iodide is the inorganic compound with the formula BeI2. It is a hygroscopic white solid.

<span class="mw-page-title-main">Bismuth(III) iodide</span> Chemical compound

Bismuth(III) iodide is the inorganic compound with the formula BiI3. This gray-black salt is the product of the reaction of bismuth and iodine, which once was of interest in qualitative inorganic analysis.

<span class="mw-page-title-main">Total inorganic carbon</span> Sum of the inorganic carbon species

Total inorganic carbon is the sum of the inorganic carbon species.

Iron(III) iodide is an inorganic compound with the chemical formula FeI3. It is a thermodynamically unstable compound that is difficult to prepare. Nevertheless, iron(III) iodide has been synthesised in small quantities in the absence of air and water.

<span class="mw-page-title-main">Neodymium(II) iodide</span> Chemical compound

Neodymium(II) iodide or neodymium diiodide is an inorganic salt of iodine and neodymium the formula NdI2. Neodymium uses the +2 oxidation state in the compound.

Europium(III) iodide is an inorganic compound containing europium and iodine with the chemical formula EuI3.

References

  1. 1 2 Turner, Jr., Francis M., ed. (1920), The Condensed Chemical Dictionary (1st ed.), New York: Chemical Catalog Co., p. 127, retrieved 2007-12-08
  2. 1 2 R. J. Lewis (1993), Hawley's Condensed Chemical Dictionary 12th edition
  3. Mellor, Joseph William (1912), Modern Inorganic Chemistry, New York: Longmans, Green, and Co, p. 334, 6909989325689, retrieved 2007-12-08
  4. Gooch, Frank Austin; Walker, Claude Frederic (1905), Outlines of Inorganic Chemistry, New York: Macmillan, p. 340, retrieved 2007-12-08
  5. Jones, Harry Clary (1906), Principles of Inorganic Chemistry, New York: Macmillan, p. 365, retrieved 2007-12-08