Iodide hydride

Last updated

Iodide hydrides are mixed anion compounds containing hydride and iodide anions. Many iodide hydrides are cluster compounds, containing a hydrogen atom in a core, surrounded by a layer of metal atoms, encased in a shell of iodide.

List

formulasystemspace groupunit cell Åvolumedensitycommentreference
(DippNacnac)Mg(μ-H)(μ-I)Mg(MesNacnac) [1]
KHI [2] [3]
[LZnI(η2-H)]2 (L=1,3-bis(2,6-diisopropylphenyl)inidazole-2-ylidine [4]
Sr2H3ItrigonalP3m1a = 4.260 c = 7.749 Z=1121.774.16transparent [5]
YIHC=31.033metallic [6]
YIH2P3m1a = 3.8579, c = 10.997light green [6]
Nb6I11HD10/2ha = 11.317; b = 15.471 ; c = 13.431 [7]
Nb6I11HIm3ma = 11.317; b = 15.471 ; c = 13.431black [7]
Nb6(H)I9StriclinicP1a = 10.340, b = 11.554, c = 10.181, α = 104.31°, β = 113.50°, γ = 105.48° Z=2 [8] [9]
HCsNb6I11 [10]
Ba2H3ItrigonalP3m1a= 4.519 c= 8.1184transparent [11]
Ba5H2I4O2orthorhombicCmcma =17.210, b = 14.525 c = 6.3903 Z=41597.445.11transparent [5]
LaI2HhexagonalP63/mmca=4.2158 c=15.508 [12] [13]
Cel2H0.90R3m [14]
Cel2D0.96R3m [14]
NdI2H [15]
GdI2H0.97R3mtransparent blue [16]
Gd2ICH0.73P63mca=3.8128 C=14.844 Z=28.071 [17]
Eu2H3Idark red [18]
Eu5H2O2I4orthorhombicCmcma = 16.3697, b = 13.6954, c = 6.0436, Z = 4dark red [18]
Tb2ICH [17]
DyI2H [15]
[(η5-C5H5)W(NO)IH]2 [19]
(η5-C5H5)W(NO)I(H)(P(OPh)3)
Ir(η2-H2)(H)2I(PiPr3)2 [20] [21]
Ir(η2-H2)(H)2I(PiPr3)2•C10H8triclinicP1a=7.999 b=13.981 c=14.561 α=82.49° β=84.39° γ=71.70° Z=215K [21]

Related Research Articles

<span class="mw-page-title-main">Indium(III) bromide</span> Chemical compound

Indium(III) bromide, (indium tribromide), InBr3, is a chemical compound of indium and bromine. It is a Lewis acid and has been used in organic synthesis.

There are three sets of Indium halides, the trihalides, the monohalides, and several intermediate halides. In the monohalides the oxidation state of indium is +1 and their proper names are indium(I) fluoride, indium(I) chloride, indium(I) bromide and indium(I) iodide.

The nitridoborates are chemical compounds of boron and nitrogen with metals. These compounds are typically produced at high temperature by reacting hexagonal boron nitride with metal nitrides or by metathesis reactions involving nitridoborates. A wide range of these compounds have been made involving lithium, alkaline earth metals and lanthanides, and their structures determined using crystallographic techniques such as X-ray crystallography. Structurally one of their interesting features is the presence of polyatomic anions of boron and nitrogen where the geometry and the B–N bond length have been interpreted in terms of π-bonding.

The inorganic imide is an inorganic chemical compound containing

<span class="mw-page-title-main">Europium(II) chloride</span> Chemical compound

Europium(II) chloride is an inorganic compound with a chemical formula EuCl2. When it is irradiated by ultraviolet light, it has bright blue fluorescence.

The telluride iodides are chemical compounds that contain both telluride ions (Te2−) and iodide ions (I−). They are in the class of mixed anion compounds or chalcogenide halides.

Nitride fluorides containing nitride and fluoride ions with the formula NF4-. They can be electronically equivalent to a pair of oxide ions O24-. Nitride fluorides were discovered in 1996 by Lavalle et al. They heated diammonium technetium hexafluoride to 300 °C to yield TcNF. Another preparation is to heat a fluoride compound with a nitride compound in a solid state reaction. The fluorimido ion is F-N2- and is found in a rhenium compound.

Sulfidostannates, or thiostannates are chemical compounds containing anions composed of tin linked with sulfur. They can be considered as stannates with sulfur substituting for oxygen. Related compounds include the thiosilicates, and thiogermanates, and by varying the chalcogen: selenostannates, and tellurostannates. Oxothiostannates have oxygen in addition to sulfur. Thiostannates can be classed as chalcogenidometalates, thiometallates, chalcogenidotetrelates, thiotetrelates, and chalcogenidostannates. Tin is almost always in the +4 oxidation state in thiostannates, although a couple of mixed sulfides in the +2 state are known,

A chloride nitride is a mixed anion compound containing both chloride (Cl−) and nitride ions (N3−). Another name is metallochloronitrides. They are a subclass of halide nitrides or pnictide halides.

Arsenide bromides or bromide arsenides are compounds containing anions composed of bromide (Br−) and arsenide (As3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the arsenide chlorides, arsenide iodides, phosphide bromides, and antimonide bromides.

Arsenide iodides or iodide arsenides are compounds containing anions composed of iodide (I−) and arsenide (As3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the arsenide chlorides, arsenide bromides, phosphide iodides, and antimonide iodides.

Antimonide bromides or bromide antimonides are compounds containing anions composed of bromide (Br−) and antimonide (Sb3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the antimonide chlorides, antimonide iodides, arsenide chlorides, arsenide bromides, arsenide iodides, phosphide chlorides, phosphide bromides, and phosphide iodides. The bromoantimonates have antimony in positive oxidation states.

An iodide nitride is a mixed anion compound containing both iodide (I−) and nitride ions (N3−). Another name is metalloiodonitrides. They are a subclass of halide nitrides or pnictide halides. Some different kinds include ionic alkali or alkaline earth salts, small clusters where metal atoms surround a nitrogen atom, layered group 4 element 2-dimensional structures, and transition metal nitrido complexes counter-balanced with iodide ions. There is also a family with rare earth elements and nitrogen and sulfur in a cluster.

Carbide chlorides are mixed anion compounds containing chloride anions and anions consisting entirely of carbon. In these compounds there is no bond between chlorine and carbon. But there is a bond between a metal and carbon. Many of these compounds are cluster compounds, in which metal atoms encase a carbon core, with chlorine atoms surrounding the cluster. The chlorine may be shared between clusters to form polymers or layers. Most carbide chloride compounds contain rare earth elements. Some are known from group 4 elements. The hexatungsten carbon cluster can be oxidised and reduced, and so have different numbers of chlorine atoms included.

Carbide bromides are mixed anion compounds containing bromide and carbide anions. Many carbide bromides are cluster compounds, containing on, two or more carbon atoms in a core, surrounded by a layer of metal atoms, encased in a shell of bromide ions. These ions may be shared between clusters to form chains, double chains or layers.

Carbide iodides are mixed anion compounds containing iodide and carbide anions. Many carbide iodides are cluster compounds, containing one, two or more carbon atoms in a core, surrounded by a layer of metal atoms, and encased in a shell of iodide ions. These ions may be shared between clusters to form chains, double chains or layers.

Germanide halides are compound that include the germanide (Ge4−) anion and a halide such as chloride (Cl−), bromide (Br−) or iodide (I−). They include germanide iodides, germanide bromides or germanide chlorides. They can be considered as mixed anion compounds. They are in the category of tetrelidehalides. Related compounds include the silicide iodides, and carbide iodides.

Antimonide iodides or iodide antimonides are compounds containing anions composed of iodide (I−) and antimonide (Sb3−). They can be considered as mixed anion compounds. They are in the category of pnictide halides. Related compounds include the antimonide chlorides, antimonide bromides, phosphide iodides, and arsenide iodides.

<span class="mw-page-title-main">Gadolinium diiodide</span> Chemical compound

Gadolinium diiodide is an inorganic compound, with the chemical formula of GdI2. It is an electride, with the ionic formula of Gd3+(I−)2e−, and therefore not a true gadolinium(II) compound. It is ferromagnetic at 276 K with a saturation magnetization of 7.3 B; it exhibits a large negative magnetoresistance (~70%) at 7 T near room temperature. It can be obtained by reacting gadolinium and gadolinium(III) iodide at a high temperature:

Hydride selenides are mixed anion compounds containing both hydride and selenide ions. They are in the category of heteroanionic chalcogenides, or mixed anion compounds. Related compounds include the oxyhydrides, hydride sulfides, and hydride tellurides.

References

  1. ↑ Jones, Cameron; Stasch, Andreas (2013), Harder, Sjoerd (ed.), "Stable Molecular Magnesium(I) Dimers: A Fundamentally Appealing Yet Synthetically Versatile Compound Class", Alkaline-Earth Metal Compounds, Topics in Organometallic Chemistry, vol. 45, Berlin, Heidelberg: Springer Berlin Heidelberg, pp. 73–101, doi:10.1007/978-3-642-36270-5_3, ISBN   978-3-642-36269-9 , retrieved 2023-11-15
  2. ↑ Mills, R (November 2001). "Minimum heat of formation of potassium iodo hydride". International Journal of Hydrogen Energy. 26 (11): 1199–1208. doi:10.1016/S0360-3199(01)00051-9.
  3. ↑ Mills, R (December 2000). "Synthesis and characterization of potassium iodo hydride". International Journal of Hydrogen Energy. 25 (12): 1185–1203. doi:10.1016/S0360-3199(00)00037-9.
  4. ↑ Lummis, Paul Ashley (2015). Earth-Abundant Transition Metal Hydride Complexes for Dehydrocoupling and Hydrosilylation Catalysis. University of Alberta.
  5. 1 2 Reckeweg, Olaf; DiSalvo, Francis J. (2011-01-01). "AlkalineEarthMetal-Hydride-Iodide Compounds: Syntheses andCrystal Structures of Sr 2 H 3 I and Ba 5 H 2 I 3.9(2) O 2". Zeitschrift für Naturforschung B. 66 (1): 21–26. doi: 10.1515/znb-2011-0104 . ISSN   1865-7117. S2CID   27301598.
  6. 1 2 Ryazanov, Mikhail; Simon, Arndt; Mattausch, Hansjürgen (August 2004). "YIH n : A New Family of Metal-rich Hydride Halides". Zeitschrift für anorganische und allgemeine Chemie. 630 (10): 1401–1407. doi:10.1002/zaac.200400094. ISSN   0044-2313.
  7. 1 2 Simon, Arndt (December 1967). "Beiträge zur Chemie der Elemente Niob und Tantal. LXV. HNb6J11 Eine Verbindung mit der komplexen Gruppe [HNb6J8]". Zeitschrift für anorganische und allgemeine Chemie. 355 (5–6): 311–322. doi:10.1002/zaac.19673550511.
  8. ↑ Meyer, H. Juergen; Corbett, John D. (October 1992). "Theoretical study of the electronic properties of niobium iodide sulfide (Nb6I9S) and its hydride (Nb6(H)I9S)". Inorganic Chemistry. 31 (21): 4276–4280. doi:10.1021/ic00047a013. ISSN   0020-1669.
  9. ↑ Meyer, H. Juergen; Corbett, John D. (March 1991). "Synthesis and structure of the novel chain compound niobium iodide sulfide (Nb6I9S) and its hydride". Inorganic Chemistry. 30 (5): 963–967. doi:10.1021/ic00005a017. ISSN   0020-1669.
  10. ↑ Simon, Arndt (March 1985). "Empty, filled, and condensed metal clusters". Journal of Solid State Chemistry. 57 (1): 2–16. Bibcode:1985JSSCh..57....2S. doi:10.1016/S0022-4596(85)80055-4.
  11. ↑ Reckeweg, Olaf; DiSalvo, Francis J. (2011-11-01). "Filling up another Gap: Synthesis and Crystal Structure of Ba 2 H 3 I". Zeitschrift für Naturforschung B. 66 (11): 1087–1091. doi: 10.1515/znb-2011-1101 . ISSN   1865-7117. S2CID   40246199.
  12. ↑ Imoto, Hideo; Corbett, John D. (February 1981). "Lanthanum and neodymium diiodide hydride phases and their hydrogen dissociation pressures". Inorganic Chemistry. 20 (2): 630–633. doi:10.1021/ic50216a062. ISSN   0020-1669.
  13. ↑ Ryazanov, M; Simon, A; Mattausch, Hj; Kremer, R.K (July 2004). "The structural change of lanthanum diiodide upon hydrogenation". Journal of Alloys and Compounds. 374 (1–2): 142–145. doi:10.1016/j.jallcom.2003.11.072.
  14. 1 2 Michaelis, C.; Mattausch, Hj.; Borromann, H.; Simon, A.; Cockroft, J. K. (1992-01). "LnHal 2 H n  Neue Phasen in den ternären Systemen Ln/Hal/H. I. Strukturen". Zeitschrift für anorganische und allgemeine Chemie. 607 (1): 29–33. doi:10.1002/zaac.19926070107. ISSN   0044-2313.{{cite journal}}: Check date values in: |date= (help)
  15. 1 2 Bochkarev, M. N.; Logunov, A. A.; Burin, M. E. (October 2007). "Synthesis and some properties of neodymium(III) and dysprosium(III) iodide hydrides LnI2H". Russian Chemical Bulletin. 56 (10): 1953–1955. doi:10.1007/s11172-007-0303-x. ISSN   1066-5285. S2CID   93943595.
  16. ↑ Michaelis, C.; Bauhofer, W.; Buchkremer‐Hermanns, H.; Kremer, R. K.; Simon, A.; Miller, G. J. (1992-12). "LnHal 2 H n — Neue Phasen in den ternären Systemen Ln/Hal/H (Ln = Lanthanoid, Hal = Br, I) III. Physikalische Eigenschaften". Zeitschrift für anorganische und allgemeine Chemie. 618 (12): 98–106. doi:10.1002/zaac.19926180118. ISSN   0044-2313.{{cite journal}}: Check date values in: |date= (help)
  17. 1 2 Ruck, M.; Simon, A. (November 1992). "Ln2XCHy: Kondensierte Cluster mit zwei verschiedenen interstitiellen Atomen". Zeitschrift für anorganische und allgemeine Chemie (in German). 617 (11): 7–18. doi:10.1002/zaac.19926170102. ISSN   0044-2313.
  18. 1 2 Rudolph, Daniel; Wylezich, Thomas; Netzsch, Philip; Blaschkowski, Björn; Höppe, Henning A.; Goldner, Philippe; Kunkel, Nathalie; Hoslauer, Jean-Louis; Schleid, Thomas (2023-10-07). "Synthesis and Crystal Structure of the Europium(II) Hydride Oxide Iodide Eu5H2O2I4 Showing Blue-Green Luminescence". International Journal of Molecular Sciences. 24 (19): 14969. doi: 10.3390/ijms241914969 . ISSN   1422-0067. PMC   10573458 . PMID   37834417.
  19. ↑ Oxley, Jimmie Carol (20 April 1978). Nitrosyl Hydrides and Cations of Group VI Transition Metals. California State University Northridge.
  20. ↑ Bau, Robert; Drabnis, Mary H. (June 1997). "Structures of transition metal hydrides determined by neutron diffraction". Inorganica Chimica Acta. 259 (1–2): 27–50. doi:10.1016/S0020-1693(97)89125-6.
  21. 1 2 Eckert, Juergen; Jensen, Craig M.; Koetzle, Thomas F.; Husebo, Trang Le; Nicol, Jacqueline; Wu, Ping (July 1995). "Inelastic Neutron Scattering Studies of IrIH2(H2)(PPri3)2 and Neutron Diffraction Structure Determination of IrIH2(H2)(PPri3)2•C10H8: Implications on the Mechanism of the Interconversion of Dihydrogen and Hydride Ligands". Journal of the American Chemical Society. 117 (27): 7271–7272. doi:10.1021/ja00132a038.
This page is based on this Wikipedia article
Text is available under the CC BY-SA 4.0 license; additional terms may apply.
Images, videos and audio are available under their respective licenses.