Iodide hydride

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Iodide hydrides are mixed anion compounds containing hydride and iodide anions. Many iodide hydrides are cluster compounds, containing a hydrogen atom in a core, surrounded by a layer of metal atoms, encased in a shell of iodide.

List

formulasystemspace groupunit cell Åvolumedensitycommentreference
(DippNacnac)Mg(μ-H)(μ-I)Mg(MesNacnac) [1]
KHI [2] [3]
[LZnI(η2-H)]2 (L=1,3-bis(2,6-diisopropylphenyl)inidazole-2-ylidine [4]
Sr2H3ItrigonalP3m1a = 4.260 c = 7.749 Z=1121.774.16transparent [5]
YIHC=31.033metallic [6]
YIH2P3m1a = 3.8579, c = 10.997light green [6]
Nb6I11HD10/2ha = 11.317; b = 15.471 ; c = 13.431 [7]
Nb6I11HIm3ma = 11.317; b = 15.471 ; c = 13.431black [7]
Nb6(H)I9StriclinicP1a = 10.340, b = 11.554, c = 10.181, α = 104.31°, β = 113.50°, γ = 105.48° Z=2 [8] [9]
HCsNb6I11 [10]
Ba2H3ItrigonalP3m1a= 4.519 c= 8.1184transparent [11]
Ba5H2I4O2orthorhombicCmcma =17.210, b = 14.525 c = 6.3903 Z=41597.445.11transparent [5]
LaI2HhexagonalP63/mmca=4.2158 c=15.508 [12] [13]
NdI2H [14]
Gd2ICH0.73P63mca=3.8128 C=14.844 Z=28.071 [15]
Eu2H3Idark red [16]
Eu5H2O2I4orthorhombicCmcma = 16.3697, b = 13.6954, c = 6.0436, Z = 4dark red [16]
Tb2ICH [15]
DyI2H [14]
[(η5-C5H5)W(NO)IH]2 [17]
(η5-C5H5)W(NO)I(H)(P(OPh)3)
Ir(η2-H2)(H)2I(PiPr3)2 [18] [19]
Ir(η2-H2)(H)2I(PiPr3)2•C10H8triclinicP1a=7.999 b=13.981 c=14.561 α=82.49° β=84.39° γ=71.70° Z=215K [19]

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Arsenide bromides or bromide arsenides are compounds containing anions composed of bromide (Br−) and arsenide (As3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the arsenide chlorides, arsenide iodides, phosphide bromides, and antimonide bromides.

Arsenide iodides or iodide arsenides are compounds containing anions composed of iodide (I−) and arsenide (As3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the arsenide chlorides, arsenide bromides, phosphide iodides, and antimonide iodides.

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Carbide bromides are mixed anion compounds containing bromide and carbide anions. Many carbide bromides are cluster compounds, containing on, two or more carbon atoms in a core, surrounded by a layer of metal atoms, encased in a shell of bromide ions. These ions may be shared between clusters to form chains, double chains or layers.

Carbide iodides are mixed anion compounds containing iodide and carbide anions. Many carbide iodides are cluster compounds, containing one, two or more carbon atoms in a core, surrounded by a layer of metal atoms, and encased in a shell of iodide ions. These ions may be shared between clusters to form chains, double chains or layers.

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Antimonide iodides or iodide antimonides are compounds containing anions composed of iodide (I−) and antimonide (Sb3−). They can be considered as mixed anion compounds. They are in the category of pnictide halides. Related compounds include the antimonide chlorides, antimonide bromides, phosphide iodides, and arsenide iodides.

<span class="mw-page-title-main">Disulfur diiodide</span> Chemical compound

Disulfur diiodide is an unstable inorganic chemical compound with the chemical formula S2I2. Its empirical formula is SI. It is a red-brown solid that decomposes above −30 °C to elemental sulfur and iodine.

References

  1. ↑ Jones, Cameron; Stasch, Andreas (2013), Harder, Sjoerd (ed.), "Stable Molecular Magnesium(I) Dimers: A Fundamentally Appealing Yet Synthetically Versatile Compound Class", Alkaline-Earth Metal Compounds, Topics in Organometallic Chemistry, Berlin, Heidelberg: Springer Berlin Heidelberg, vol. 45, pp. 73–101, doi:10.1007/978-3-642-36270-5_3, ISBN   978-3-642-36269-9 , retrieved 2023-11-15
  2. ↑ Mills, R (November 2001). "Minimum heat of formation of potassium iodo hydride". International Journal of Hydrogen Energy. 26 (11): 1199–1208. doi:10.1016/S0360-3199(01)00051-9.
  3. ↑ Mills, R (December 2000). "Synthesis and characterization of potassium iodo hydride". International Journal of Hydrogen Energy. 25 (12): 1185–1203. doi:10.1016/S0360-3199(00)00037-9.
  4. ↑ Lummis, Paul Ashley (2015). Earth-Abundant Transition Metal Hydride Complexes for Dehydrocoupling and Hydrosilylation Catalysis. University of Alberta.
  5. 1 2 Reckeweg, Olaf; DiSalvo, Francis J. (2011-01-01). "AlkalineEarthMetal-Hydride-Iodide Compounds: Syntheses andCrystal Structures of Sr 2 H 3 I and Ba 5 H 2 I 3.9(2) O 2". Zeitschrift für Naturforschung B. 66 (1): 21–26. doi: 10.1515/znb-2011-0104 . ISSN   1865-7117. S2CID   27301598.
  6. 1 2 Ryazanov, Mikhail; Simon, Arndt; Mattausch, Hansjürgen (August 2004). "YIH n : A New Family of Metal‐rich Hydride Halides". Zeitschrift für anorganische und allgemeine Chemie. 630 (10): 1401–1407. doi:10.1002/zaac.200400094. ISSN   0044-2313.
  7. 1 2 Simon, Arndt (December 1967). "Beiträge zur Chemie der Elemente Niob und Tantal. LXV. HNb6J11 Eine Verbindung mit der komplexen Gruppe [HNb6J8]". Zeitschrift für anorganische und allgemeine Chemie. 355 (5–6): 311–322. doi:10.1002/zaac.19673550511.
  8. ↑ Meyer, H. Juergen; Corbett, John D. (October 1992). "Theoretical study of the electronic properties of niobium iodide sulfide (Nb6I9S) and its hydride (Nb6(H)I9S)". Inorganic Chemistry. 31 (21): 4276–4280. doi:10.1021/ic00047a013. ISSN   0020-1669.
  9. ↑ Meyer, H. Juergen; Corbett, John D. (March 1991). "Synthesis and structure of the novel chain compound niobium iodide sulfide (Nb6I9S) and its hydride". Inorganic Chemistry. 30 (5): 963–967. doi:10.1021/ic00005a017. ISSN   0020-1669.
  10. ↑ Simon, Arndt (March 1985). "Empty, filled, and condensed metal clusters". Journal of Solid State Chemistry. 57 (1): 2–16. Bibcode:1985JSSCh..57....2S. doi:10.1016/S0022-4596(85)80055-4.
  11. ↑ Reckeweg, Olaf; DiSalvo, Francis J. (2011-11-01). "Filling up another Gap: Synthesis and Crystal Structure of Ba 2 H 3 I". Zeitschrift für Naturforschung B. 66 (11): 1087–1091. doi: 10.1515/znb-2011-1101 . ISSN   1865-7117. S2CID   40246199.
  12. ↑ Imoto, Hideo; Corbett, John D. (February 1981). "Lanthanum and neodymium diiodide hydride phases and their hydrogen dissociation pressures". Inorganic Chemistry. 20 (2): 630–633. doi:10.1021/ic50216a062. ISSN   0020-1669.
  13. ↑ Ryazanov, M; Simon, A; Mattausch, Hj; Kremer, R.K (July 2004). "The structural change of lanthanum diiodide upon hydrogenation". Journal of Alloys and Compounds. 374 (1–2): 142–145. doi:10.1016/j.jallcom.2003.11.072.
  14. 1 2 Bochkarev, M. N.; Logunov, A. A.; Burin, M. E. (October 2007). "Synthesis and some properties of neodymium(III) and dysprosium(III) iodide hydrides LnI2H". Russian Chemical Bulletin. 56 (10): 1953–1955. doi:10.1007/s11172-007-0303-x. ISSN   1066-5285. S2CID   93943595.
  15. 1 2 Ruck, M.; Simon, A. (November 1992). "Ln2XCHy: Kondensierte Cluster mit zwei verschiedenen interstitiellen Atomen". Zeitschrift für anorganische und allgemeine Chemie (in German). 617 (11): 7–18. doi:10.1002/zaac.19926170102. ISSN   0044-2313.
  16. 1 2 Rudolph, Daniel; Wylezich, Thomas; Netzsch, Philip; Blaschkowski, Björn; Höppe, Henning A.; Goldner, Philippe; Kunkel, Nathalie; Hoslauer, Jean-Louis; Schleid, Thomas (2023-10-07). "Synthesis and Crystal Structure of the Europium(II) Hydride Oxide Iodide Eu5H2O2I4 Showing Blue-Green Luminescence". International Journal of Molecular Sciences. 24 (19): 14969. doi: 10.3390/ijms241914969 . ISSN   1422-0067. PMC   10573458 . PMID   37834417.
  17. ↑ Oxley, Jimmie Carol (20 April 1978). Nitrosyl Hydrides and Cations of Group VI Transition Metals. California State University Northridge.
  18. ↑ Bau, Robert; Drabnis, Mary H. (June 1997). "Structures of transition metal hydrides determined by neutron diffraction". Inorganica Chimica Acta. 259 (1–2): 27–50. doi:10.1016/S0020-1693(97)89125-6.
  19. 1 2 Eckert, Juergen; Jensen, Craig M.; Koetzle, Thomas F.; Husebo, Trang Le; Nicol, Jacqueline; Wu, Ping (July 1995). "Inelastic Neutron Scattering Studies of IrIH2(H2)(PPri3)2 and Neutron Diffraction Structure Determination of IrIH2(H2)(PPri3)2•C10H8: Implications on the Mechanism of the Interconversion of Dihydrogen and Hydride Ligands". Journal of the American Chemical Society. 117 (27): 7271–7272. doi:10.1021/ja00132a038.
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