Caesium iodide

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Caesium iodide
Kristall CsI(Tl).jpg
CsI crystal
Kristall-CsI(Tl) mit Skala.jpg
Scintillating CsI crystal
CsCl polyhedra.png
Crystal structure
Caesium-iodide-3D-ionic.png
Names
IUPAC name
Caesium iodide
Other names
Cesium iodide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.223 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 232-145-2
PubChem CID
RTECS number
  • FL0350000
UNII
  • InChI=1S/Cs.HI/h;1H/q+1;/p-1 Yes check.svgY
    Key: XQPRBTXUXXVTKB-UHFFFAOYSA-M Yes check.svgY
  • InChI=1/Cs.HI/h;1H/q+1;/p-1
    Key: XQPRBTXUXXVTKB-REWHXWOFAA
  • [Cs+].[I-]
Properties
CsI
Molar mass 259.809 g/mol [2]
Appearancewhite crystalline solid
Density 4.51 g/cm3 [2]
Melting point 632 °C (1,170 °F; 905 K) [2]
Boiling point 1,280 °C (2,340 °F; 1,550 K) [2]
848 g/L (25 °C) [2]
-82.6·10−6 cm3/mol [3]
1.9790 (0.3 µm)
1.7873 (0.59 µm)
1.7694 (0.75 µm)
1.7576 (1 µm)
1.7428 (5 µm)
1.7280 (20 µm) [4]
Structure
CsCl, cP2
Pm3m, No. 221 [5]
a = 0.4503 nm
0.0913 nm3
1
Cubic (Cs+)
Cubic (I)
Thermochemistry
52.8 J/mol·K [6]
Std molar
entropy
(S298)
123.1 J/mol·K [6]
−346.6 kJ/mol [6]
-340.6 kJ/mol [6]
Hazards
GHS labelling:
GHS-pictogram-exclam.svg GHS-pictogram-silhouette.svg GHS-pictogram-pollu.svg
Warning
H315, H317, H319, H335
P201, P202, P261, P264, P270, P271, P272, P273, P280, P281, P301+P312, P302+P352, P304+P340, P305+P351+P338, P308+P313, P312, P321, P330, P332+P313, P333+P313, P337+P313, P362, P363, P391, P403+P233, P405, P501
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
2386 mg/kg (oral, rat) [1]
Related compounds
Other anions
Caesium fluoride
Caesium chloride
Caesium bromide
Caesium astatide
Other cations
Lithium iodide
Sodium iodide
Potassium iodide
Rubidium iodide
Francium iodide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Caesium iodide or cesium iodide (chemical formula CsI) is the ionic compound of caesium and iodine. It is often used as the input phosphor of an X-ray image intensifier tube found in fluoroscopy equipment. Caesium iodide photocathodes are highly efficient at extreme ultraviolet wavelengths. [7]

Contents

Synthesis and structure

Monatomic caesium halide wires grown inside double-wall carbon nanotubes. CsX@DWNT.jpg
Monatomic caesium halide wires grown inside double-wall carbon nanotubes.

Bulk caesium iodide crystals have the cubic CsCl crystal structure, but the structure type of nanometer-thin CsI films depends on the substrate material – it is CsCl for mica and NaCl for LiF, NaBr and NaCl substrates. [9]

Caesium iodide atomic chains can be grown inside double-wall carbon nanotubes. In such chains I atoms appear brighter than Cs atoms in electron micrographs despite having a smaller mass. This difference was explained by the charge difference between Cs atoms (positive), inner nanotube walls (negative) and I atoms (negative). As a result, Cs atoms are attracted to the walls and vibrate more strongly than I atoms, which are pushed toward the nanotube axis. [8]

Properties

Solubility of Csl in water [10]
Т (°C) 0 10 20 25 30 40 50 60 70 80 90 100
S (wt%) 30.9 37.2 43.2 45.9 48.6 53.3 57.3 60.7 63.6 65.9 67.7 69.2

Applications

An important application of caesium iodide crystals, which are scintillators, is electromagnetic calorimetry in experimental particle physics. Pure CsI is a fast and dense scintillating material with relatively low light yield that increases significantly with cooling, [11] and a fairly small Molière radius is 3.5 cm. It exhibits two main emission components: one in the near ultraviolet region at the wavelength of 310 nm and one at 460 nm. The drawbacks of CsI are a high temperature gradient and a slight hygroscopicity.

Caesium iodide is used as a beamsplitter in Fourier transform infrared (FTIR) spectrometers. It has a wider transmission range than the more common potassium bromide beamsplitters, working range into the far infrared. However, optical-quality CsI crystals are very soft and hard to cleave or polish. They should also be coated (typically with germanium) and stored in a desiccator, to minimize interaction with atmospheric water vapors. [12]

In addition to image intensifier input phosphors, caesium iodide is often also used in medicine as the scintillating material in flat panel x-ray detectors. [13]

Related Research Articles

<span class="mw-page-title-main">Caesium</span> Chemical element with atomic number 55 (Cs)

Caesium is a chemical element; it has symbol Cs and atomic number 55. It is a soft, silvery-golden alkali metal with a melting point of 28.5 °C, which makes it one of only five elemental metals that are liquid at or near room temperature. Caesium has physical and chemical properties similar to those of rubidium and potassium. It is pyrophoric and reacts with water even at −116 °C (−177 °F). It is the least electronegative stable element, with a value of 0.79 on the Pauling scale. It has only one stable isotope, caesium-133. Caesium is mined mostly from pollucite. Caesium-137, a fission product, is extracted from waste produced by nuclear reactors. It has the largest atomic radius of all elements whose radii have been measured or calculated, at about 260 picometers.

<span class="mw-page-title-main">Photomultiplier tube</span> Fast, high sensitivity, low noise electronic photon detector

Photomultiplier tubes (photomultipliers or PMTs for short) are extremely sensitive detectors of light in the ultraviolet, visible, and near-infrared ranges of the electromagnetic spectrum. They are members of the class of vacuum tubes, more specifically vacuum phototubes. These detectors multiply the current produced by incident light by as much as 100 million times or 108 (i.e., 160 dB), in multiple dynode stages, enabling (for example) individual photons to be detected when the incident flux of light is low.

<span class="mw-page-title-main">Scintillation counter</span> Instrument for measuring ionizing radiation

A scintillation counter is an instrument for detecting and measuring ionizing radiation by using the excitation effect of incident radiation on a scintillating material, and detecting the resultant light pulses.

<span class="mw-page-title-main">Scintillator</span> Material which glows when excited by ionizing radiation

A scintillator is a material that exhibits scintillation, the property of luminescence, when excited by ionizing radiation. Luminescent materials, when struck by an incoming particle, absorb its energy and scintillate. Sometimes, the excited state is metastable, so the relaxation back down from the excited state to lower states is delayed. The process then corresponds to one of two phenomena: delayed fluorescence or phosphorescence. The correspondence depends on the type of transition and hence the wavelength of the emitted optical photon.

<span class="mw-page-title-main">Photocathode</span> Surface which converts light into electrons via the photoelectric effect

A photocathode is a surface engineered to convert light (photons) into electrons using the photoelectric effect. Photocathodes are important in accelerator physics where they are utilised in a photoinjector to generate high brightness electron beams. Electron beams generated with photocathodes are commonly used for free electron lasers and for ultrafast electron diffraction. Photocathodes are also commonly used as the negatively charged electrode in a light detection device such as a photomultiplier, phototube and image intensifier.

An image intensifier or image intensifier tube is a vacuum tube device for increasing the intensity of available light in an optical system to allow use under low-light conditions, such as at night, to facilitate visual imaging of low-light processes, such as fluorescence of materials in X-rays or gamma rays, or for conversion of non-visible light sources, such as near-infrared or short wave infrared to visible. They operate by converting photons of light into electrons, amplifying the electrons, and then converting the amplified electrons back into photons for viewing. They are used in devices such as night-vision goggles.

<span class="mw-page-title-main">Caesium fluoride</span> Chemical compound

Caesium fluoride is an inorganic compound with the formula CsF. A hygroscopic white salt, caesium fluoride is used in the synthesis of organic compounds as a source of the fluoride anion. The compound is noteworthy from the pedagogical perspective as caesium also has the highest electropositivity of all commonly available elements and fluorine has the highest electronegativity.

<span class="mw-page-title-main">Yttrium aluminium garnet</span> Synthetic crystalline material of the garnet group

Yttrium aluminium garnet (YAG, Y3Al5O12) is a synthetic crystalline material of the garnet group. It is a cubic yttrium aluminium oxide phase, with other examples being YAlO3 (YAP) in a hexagonal or an orthorhombic, perovskite-like form, and the monoclinic Y4Al2O9 (YAM).

<span class="mw-page-title-main">Gamma spectroscopy</span> Quantitative study of the energy spectra of gamma-ray sources

Gamma-ray spectroscopy is the qualitative study of the energy spectra of gamma-ray sources, such as in the nuclear industry, geochemical investigation, and astrophysics. Gamma-ray spectrometry, on the other hand, is the method used to acquire a quantitative spectrum measurement.

<span class="mw-page-title-main">Caesium chloride</span> Chemical compound

Caesium chloride or cesium chloride is the inorganic compound with the formula CsCl. This colorless salt is an important source of caesium ions in a variety of niche applications. Its crystal structure forms a major structural type where each caesium ion is coordinated by 8 chloride ions. Caesium chloride dissolves in water. CsCl changes to NaCl structure on heating. Caesium chloride occurs naturally as impurities in carnallite, sylvite and kainite. Less than 20 tonnes of CsCl is produced annually worldwide, mostly from a caesium-bearing mineral pollucite.

<span class="mw-page-title-main">Sodium iodide</span> Chemical compound

Sodium iodide (chemical formula NaI) is an ionic compound formed from the chemical reaction of sodium metal and iodine. Under standard conditions, it is a white, water-soluble solid comprising a 1:1 mix of sodium cations (Na+) and iodide anions (I) in a crystal lattice. It is used mainly as a nutritional supplement and in organic chemistry. It is produced industrially as the salt formed when acidic iodides react with sodium hydroxide. It is a chaotropic salt.

An X-ray image intensifier (XRII) is an image intensifier that converts X-rays into visible light at higher intensity than the more traditional fluorescent screens can. Such intensifiers are used in X-ray imaging systems to allow low-intensity X-rays to be converted to a conveniently bright visible light output. The device contains a low absorbency/scatter input window, typically aluminum, input fluorescent screen, photocathode, electron optics, output fluorescent screen and output window. These parts are all mounted in a high vacuum environment within glass or, more recently, metal/ceramic. By its intensifying effect, It allows the viewer to more easily see the structure of the object being imaged than fluorescent screens alone, whose images are dim. The XRII requires lower absorbed doses due to more efficient conversion of X-ray quanta to visible light. This device was originally introduced in 1948.

Caesium lithium borate or cesium lithium borate (CsLiB6O10), also known as CLBO, is a non-linear crystal for ultraviolet applications and generates the fourth and fifth harmonics of the Nd:YAG fundamental laser wavelength (1064 nm).

Digital radiography is a form of radiography that uses x-ray–sensitive plates to directly capture data during the patient examination, immediately transferring it to a computer system without the use of an intermediate cassette. Advantages include time efficiency through bypassing chemical processing and the ability to digitally transfer and enhance images. Also, less radiation can be used to produce an image of similar contrast to conventional radiography.

<span class="mw-page-title-main">Thallium(I) chloride</span> Chemical compound

Thallium(I) chloride, also known as thallous chloride, is a chemical compound with the formula TlCl. This colourless salt is an intermediate in the isolation of thallium from its ores. Typically, an acidic solution of thallium(I) sulfate is treated with hydrochloric acid to precipitate insoluble thallium(I) chloride. This solid crystallizes in the caesium chloride motif.

<span class="mw-page-title-main">Thallium(I) iodide</span> Chemical compound

Thallium(I) iodide is a chemical compound with the formula . It is unusual in being one of the few water-insoluble metal iodides, along with , , , , and .

<span class="mw-page-title-main">Caesium bromide</span> Chemical compound

Caesium bromide or cesium bromide is an ionic compound of caesium and bromine with the chemical formula CsBr. It is a white or transparent solid with melting point at 636 °C that readily dissolves in water. Its bulk crystals have the cubic CsCl structure, but the structure changes to the rocksalt type in nanometer-thin film grown on mica, LiF, KBr or NaCl substrates.

The thallium halides include monohalides, where thallium has oxidation state +1, trihalides in which thallium generally has oxidation state +3, and some intermediate halides containing thallium with mixed +1 and +3 oxidation states. These salts find use in specialized optical settings, such as focusing elements in research spectrophotometers. Compared to the more common zinc selenide-based optics, materials such as thallium bromoiodide enable transmission at longer wavelengths. In the infrared, this allows for measurements as low as 350 cm−1 (28 μm), whereas zinc selenide is opaque by 21.5 μm, and ZnSe optics are generally only usable to 650 cm−1 (15 μm).

In phosphors and scintillators, the activator is the element added as dopant to the crystal of the material to create desired type of nonhomogeneities.

<span class="mw-page-title-main">X-ray detector</span> Instrument that can measure properties of X-rays

X-ray detectors are devices used to measure the flux, spatial distribution, spectrum, and/or other properties of X-rays.

References

  1. 1 2 Cesium iodide. U.S. National Library of Medicine
  2. 1 2 3 4 5 Haynes, p. 4.57
  3. Haynes, p. 4.132
  4. Haynes, p. 10.240
  5. Huang, Tzuen-Luh; Ruoff, Arthur L. (1984). "Equation of state and high-pressure phase transition of CsI". Physical Review B. 29 (2): 1112. Bibcode:1984PhRvB..29.1112H. doi:10.1103/PhysRevB.29.1112.
  6. 1 2 3 4 Haynes, p. 5.10
  7. Kowalski, M. P.; Fritz, G. G.; Cruddace, R. G.; Unzicker, A. E.; Swanson, N. (1986). "Quantum efficiency of cesium iodide photocathodes at soft x-ray and extreme ultraviolet wavelengths". Applied Optics. 25 (14): 2440. Bibcode:1986ApOpt..25.2440K. doi:10.1364/AO.25.002440. PMID   18231513.
  8. 1 2 Senga, Ryosuke; Komsa, Hannu-Pekka; Liu, Zheng; Hirose-Takai, Kaori; Krasheninnikov, Arkady V.; Suenaga, Kazu (2014). "Atomic structure and dynamic behaviour of truly one-dimensional ionic chains inside carbon nanotubes". Nature Materials. 13 (11): 1050–4. Bibcode:2014NatMa..13.1050S. doi:10.1038/nmat4069. PMID   25218060.
  9. Schulz, L. G. (1951). "Polymorphism of cesium and thallium halides". Acta Crystallographica. 4 (6): 487–489. Bibcode:1951AcCry...4..487S. doi:10.1107/S0365110X51001641.
  10. Haynes, p. 5.191
  11. Mikhailik, V.; Kapustyanyk, V.; Tsybulskyi, V.; Rudyk, V.; Kraus, H. (2015). "Luminescence and scintillation properties of CsI: A potential cryogenic scintillator". Physica Status Solidi B. 252 (4): 804–810. arXiv: 1411.6246 . Bibcode:2015PSSBR.252..804M. doi:10.1002/pssb.201451464. S2CID   118668972.
  12. Sun, Da-Wen (2009). Infrared Spectroscopy for Food Quality Analysis and Control. Academic Press. pp. 158–. ISBN   978-0-08-092087-0.
  13. Lança, Luís; Silva, Augusto (2012). "Digital Radiography Detectors: A Technical Overview" (PDF). Digital Imaging Systems for Plain Radiography. Springer. doi:10.1007/978-1-4614-5067-2_2. hdl:10400.21/1932. ISBN   978-1-4614-5066-5. Archived from the original (PDF) on 2019-01-28. Retrieved 2017-08-28.

Cited sources