Caesium pertechnetate

Caesium pertechnetate

Names
Other names Cesium pertechnetate
Identifiers
CAS Number	13499-12-2  Y
3D model (JSmol)	Interactive image
InChI InChI=1S/Cs.4O.Tc/q+1;;;;-1; Key: LJXGSBFUWIGJNN-UHFFFAOYSA-N
SMILES [Cs+].[O-] [Tc](=O)(=O)=O
Properties
Chemical formula	CsO4Tc
Molar mass	295 g·mol−1
Appearance	white solid [1]
Melting point	590 °C [1]
Structure
Crystal structure	orthorhombic
Space group	Pnma (No. 62)
Lattice constant	a = 572.6 pm, b = 592.2 pm, c = 1436 pm
Related compounds
Other anions	caesium perchlorate caesium permanganate caesium perrhenate
Other cations	pertechnetic acid lithium pertechnetate sodium pertechnetate potassium pertechnetate rubidium pertechnetate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Caesium pertechnetate is the pertechnetate salt of caesium, with the chemical formula of CsTcO₄.

Preparation

Caesium pertechnetate can be prepared by reacting caesium carbonate and ammonium pertechnetate: ^[2]

Cs₂CO₃ + 2 NH₄TcO₄ → 2 CsTcO₄ + (NH₄)₂CO₃

Properties

Cesium pertechnetate is orthorhombic with space group Pnma (No. 62), and lattice parameters a = 572.6 pm, b = 592.2 pm and c = 1436 pm. ^[1] The Tc–O-bond length in pertechnetate is 164.0 pm, and the O–Tc–O bond angle is 112.9°. ^[2]

References

1. Klaus Schwochau (Nov 2008). Technetium: Chemistry and Radiopharmaceutical Applications. John Wiley & Sons. p. 129. ISBN   978-3527613373.
2. Jamie Weaver; Chuck Z. Soderquist; Nancy M. Washton; Andrew S. Lipton; Paul L. Gassman; Wayne W. Lukens; Albert A. Kruger; Nathalie A. Wall; John S. McCloy (Feb 2017). "Chemical Trends in Solid Alkali Pertechnetates". Inorganic Chemistry. 56 (5). Inorg. Chem.: 2533–2544. doi: 10.1021/acs.inorgchem.6b02694 . PMID   28221786.