Identifiers | |
---|---|
3D model (JSmol) | |
ChemSpider | |
ECHA InfoCard | 100.151.587 |
EC Number |
|
PubChem CID | |
| |
| |
Properties | |
CsMnO4 | |
Molar mass | 251.8406 |
Appearance | purple crystals [1] |
Density | 3.6 [1] |
Melting point | 200-300 °C (decomposes) |
2.3 g·l−1 (19 °C) [2] | |
Structure | |
orthorhombic | |
Pnma (Nr. 62) | |
a = 1006 pm, b = 580.1 pm, c = 794.4 pm | |
Related compounds | |
Other anions | caesium perchlorate caesium periodate caesium pertechnetate |
Other cations | lithium permanganate sodium permanganate potassium permanganate rubidium permanganate ammonium permanganate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Caesium permanganate is the permanganate salt of caesium, with the chemical formula CsMnO4.
Caesium permanganate can be formed by the reaction of potassium permanganate and caesium nitrate:
Caesium permanganate is soluble in water with a solubility of 0.97 g/L at 1 °C, [2] 2.3 g/L at 19 °C, and 12.5 g/L at 59 °C. [3] Its crystal structure is orthorhombic, [4] the same as rubidium permanganate, ammonium permanganate and potassium permanganate.
Similar to potassium permanganate, the two-step decomposition of caesium permanganate leads to the formation of caesium manganate intermediates. It breaks down into manganese dioxide, caesium oxide and oxygen. [5] The decomposition temperature is between 200 and 300 °C. [6] Drift-away oxygen caused an 8% mass loss in the product. [6]
Total reaction:
Rubidium is the chemical element with the symbol Rb and atomic number 37. It is a very soft, whitish-grey solid in the alkali metal group, similar to potassium and caesium. Rubidium is the first alkali metal in the group to have a density higher than water. On Earth, natural rubidium comprises two isotopes: 72% is a stable isotope 85Rb, and 28% is slightly radioactive 87Rb, with a half-life of 48.8 billion years—more than three times as long as the estimated age of the universe.
An oxidizing agent is a substance in a redox chemical reaction that gains or "accepts"/"receives" an electron from a reducing agent. In other words, an oxidizer is any substance that oxidizes another substance. The oxidation state, which describes the degree of loss of electrons, of the oxidizer decreases while that of the reductant increases; this is expressed by saying that oxidizers "undergo reduction" and "are reduced" while reducers "undergo oxidation" and "are oxidized". Common oxidizing agents are oxygen, hydrogen peroxide, and the halogens.
Potassium permanganate is an inorganic compound with the chemical formula KMnO4. It is a purplish-black crystalline salt, that dissolves in water as K+ and MnO−
4, an intensely pink to purple solution.
Cuprates are a class of compounds that contain copper (Cu). They can be broadly categorized into two main types:
A permanganate is a chemical compound with the manganate(VII) ion, MnO−
4, the conjugate base of permanganic acid. Because the manganese atom has a +7 oxidation state, the permanganate(VII) ion is a strong oxidising agent. The ion is a transition metal ion with a tetrahedral structure. Permanganate solutions are purple in colour and are stable in neutral or slightly alkaline media. The exact chemical reaction depends on the carbon-containing reactants present and the oxidant used. For example, trichloroethane (C2H3Cl3) is oxidised by permanganate ions to form carbon dioxide (CO2), manganese dioxide (MnO2), hydrogen ions (H+), and chloride ions (Cl−).
Ozonide is the polyatomic anion O−3. Cyclic organic compounds formed by the addition of ozone to an alkene are also called ozonides.
Rubidium perchlorate, RbClO4, is the perchlorate of rubidium. It is an oxidizing agent, as are all perchlorates.
Potassium manganate is the inorganic compound with the formula K2MnO4. This green-colored salt is an intermediate in the industrial synthesis of potassium permanganate, a common chemical. Occasionally, potassium manganate and potassium permanganate are confused, but these compounds's properties are distinct.
Caesium chromate or cesium chromate is an inorganic compound with the formula Cs2CrO4. It is a yellow crystalline solid that is the caesium salt of chromic acid, and it crystallises in the orthorhombic system.
Potassium hypomanganate is the inorganic compound with the formula K3MnO4. Also known as potassium manganate(V), this bright blue solid is a rare example of a salt with the hypomanganate or manganate(V) anion, where the manganese atom is in the +5 oxidation state. It is an intermediate in the production of potassium permanganate and the industrially most important Mn(V) compound.
Sodium permanganate is the inorganic compound with the formula NaMnO4. It is closely related to the more commonly encountered potassium permanganate, but it is generally less desirable, because it is more expensive to produce. It is mainly available as the monohydrate. This salt absorbs water from the atmosphere and has a low melting point. Being about 15 times more soluble than KMnO4, sodium permanganate finds some applications where very high concentrations of MnO4− are sought.
Manganese tetrafluoride, MnF4, is the highest fluoride of manganese. It is a powerful oxidizing agent and is used as a means of purifying elemental fluorine.
Ammonium permanganate is the chemical compound NH4MnO4, or NH3·HMnO4. It is a water soluble, violet-brown or dark purple salt.
Barium permanganate is a chemical compound, with the formula Ba(MnO4)2. It forms violet to brown crystals that are sparingly soluble in water.
Perchloratoborate is an anion of the form [B(ClO4)4]−. It can form partly stable solid salts with heavy alkali metals. They are more stable than nitratoborate salts. K[B(ClO4)4] decomposes at 35 °C, Rb[B(ClO4)4] is stable to 50 °C, and Cs[B(ClO4)4] can exist up to 80 °C.
Caesium ozonide (CsO3) is an oxygen-rich compound of caesium. It is an ozonide, meaning it contains the ozonide anion (O3−). It can be formed by reacting ozone with caesium superoxide:
Caesium sesquioxide is a chemical compound with the formula Cs2O3 or Cs4O6. In terms of oxidation states, Caesium in this compound has a nominal charge of +1, and the oxygen is a mixed peroxide and superoxide for a structural formula of (Cs+)4(O−2)2(O2−2). Compared to the other caesium oxides, this phase is less well studied, but has been long present in the literature. It can be created by thermal decomposition of caesium superoxide at 290 °C.
Rubidium oxalate is the oxalate salt of rubidium, with the chemical formula of Rb2C2O4.
Rubidium permanganate is the permanganate salt of rubidium, with the chemical formula RbMnO
4.
{{citation}}
: CS1 maint: multiple names: authors list (link){{citation}}
: Check |url=
value (help)