Caesium permanganate

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Caesium permanganate
Caesiumpermanganat.png
Crystals CsMnO4.png
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.151.587 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 622-853-3
PubChem CID
  • InChI=1S/Cs.Mn.4O/q+1;;;;;-1
    Key: HAHSACJTONBJGG-UHFFFAOYSA-N
  • [Cs+].[O-][Mn](=O)(=O)=O
Properties
CsMnO4
Molar mass 251.8406
Appearancepurple crystals [1]
Density 3.6 [1]
Melting point 200-300 °C (decomposes)
2.3 g·l−1 (19 °C) [2]
Structure
orthorhombic
Pnma (Nr. 62)
a = 1006 pm, b = 580.1 pm, c = 794.4 pm
Related compounds
Other anions
caesium perchlorate
caesium periodate
caesium pertechnetate
Other cations
lithium permanganate
sodium permanganate
potassium permanganate
rubidium permanganate
ammonium permanganate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Caesium permanganate is the permanganate salt of caesium, with the chemical formula CsMnO4.

Contents

Preparation

Caesium permanganate can be formed by the reaction of potassium permanganate and caesium nitrate:

CsNO3 + KMnO4 → KNO3 + CsMnO4

Properties

Physical

Caesium permanganate is soluble in water with a solubility of 0.97 g/L at 1 °C, [2] 2.3 g/L at 19 °C, and 12.5 g/L at 59 °C. [3] Its crystal structure is orthorhombic, [4] the same as rubidium permanganate, ammonium permanganate and potassium permanganate.

Chemical

Similar to potassium permanganate, the two-step decomposition of caesium permanganate leads to the formation of caesium manganate intermediates. It breaks down into manganese dioxide, caesium oxide and oxygen. [5] The decomposition temperature is between 200 and 300 °C. [6] Drift-away oxygen caused an 8% mass loss in the product. [6]

10CsMnO4 → 3Cs2MnO4 + 7MnO2 + 2Cs2O + 6O2
2Cs2MnO4 → 2MnO2 + 2Cs2O + O2

Total reaction:

4CsMnO4 → 4MnO2 + 2Cs2O + 3O2

Related Research Articles

<span class="mw-page-title-main">Oxidizing agent</span> Chemical compound used to oxidize another substance in a chemical reaction

An oxidizing agent is a substance in a redox chemical reaction that gains or "accepts"/"receives" an electron from a reducing agent. In other words, an oxidizer is any substance that oxidizes another substance. The oxidation state, which describes the degree of loss of electrons, of the oxidizer decreases while that of the reductant increases; this is expressed by saying that oxidizers "undergo reduction" and "are reduced" while reducers "undergo oxidation" and "are oxidized". Common oxidizing agents are oxygen, hydrogen peroxide, and the halogens.

<span class="mw-page-title-main">Potassium permanganate</span> Chemical compound

Potassium permanganate is an inorganic compound with the chemical formula KMnO4. It is a purplish-black crystalline salt, that dissolves in water as K+ and MnO
4
, an intensely pink to purple solution.

Cuprates are a class of compounds that contain copper (Cu) atom(s) in an anion. They can be broadly categorized into two main types:

<span class="mw-page-title-main">Potassium ferrate</span> Chemical compound

Potassium ferrate is the chemical compound with the formula K2FeO4. This purple salt is paramagnetic, and is a rare example of an iron(VI) compound. In most of its compounds, iron has the oxidation state +2 or +3 (Fe2+ or Fe3+). Reflecting its high oxidation state, FeO2−4 is a powerful oxidizing agent resembling chromate (CrO2−4) or manganate (MnO2−4).

<span class="mw-page-title-main">Permanganate</span> Chemical compound

A permanganate is a chemical compound with the manganate(VII) ion, MnO
4
, the conjugate base of permanganic acid. Because the manganese atom has a +7 oxidation state, the permanganate(VII) ion is a strong oxidising agent. The ion is a transition metal ion with a tetrahedral structure. Permanganate solutions are purple in colour and are stable in neutral or slightly alkaline media. The exact chemical reaction depends on the carbon-containing reactants present and the oxidant used. For example, trichloroethane (C2H3Cl3) is oxidised by permanganate ions to form carbon dioxide (CO2), manganese dioxide (MnO2), hydrogen ions (H+), and chloride ions (Cl).

<span class="mw-page-title-main">Ozonide</span> Polyatomic ion (O3, charge –1), or cyclic compounds made from ozone and alkenes

Ozonide is the polyatomic anion O−3. Cyclic organic compounds formed by the addition of ozone to an alkene are also called ozonides.

<span class="mw-page-title-main">Rubidium perchlorate</span> Chemical compound

Rubidium perchlorate, RbClO4, is the perchlorate of rubidium. It is an oxidizing agent, as are all perchlorates.

<span class="mw-page-title-main">Potassium manganate</span> Chemical compound

Potassium manganate is the inorganic compound with the formula K2MnO4. This green-colored salt is an intermediate in the industrial synthesis of potassium permanganate, a common chemical. Occasionally, potassium manganate and potassium permanganate are confused, but each compound's properties are distinct.

<span class="mw-page-title-main">Caesium chromate</span> Chemical compound

Caesium chromate or cesium chromate is an inorganic compound with the formula Cs2CrO4. It is a yellow crystalline solid that is the caesium salt of chromic acid, and it crystallises in the orthorhombic system.

Potassium hypomanganate is the inorganic compound with the formula K3MnO4. Also known as potassium manganate(V), this bright blue solid is a rare example of a salt with the hypomanganate or manganate(V) anion, where the manganese atom is in the +5 oxidation state. It is an intermediate in the production of potassium permanganate and the industrially most important Mn(V) compound.

<span class="mw-page-title-main">Sodium permanganate</span> Chemical compound

Sodium permanganate is the inorganic compound with the formula NaMnO4. It is closely related to the more commonly encountered potassium permanganate, but it is generally less desirable, because it is more expensive to produce. It is mainly available as the monohydrate. This salt absorbs water from the atmosphere and has a low melting point. Being about 15 times more soluble than KMnO4, sodium permanganate finds some applications where very high concentrations of MnO4 are sought.

<span class="mw-page-title-main">Manganese(IV) fluoride</span> Chemical compound

Manganese tetrafluoride, MnF4, is the highest fluoride of manganese. It is a powerful oxidizing agent and is used as a means of purifying elemental fluorine.

<span class="mw-page-title-main">Ammonium permanganate</span> Chemical compound

Ammonium permanganate is the chemical compound NH4MnO4, or NH3·HMnO4. It is a water soluble, violet-brown or dark purple salt.

Barium permanganate is a chemical compound, with the formula Ba(MnO4)2. It forms violet to brown crystals that are sparingly soluble in water.

Perchloratoborate is an anion of the form [B(ClO4)4]. It can form partly stable solid salts with heavy alkali metals. They are more stable than nitratoborate salts. K[B(ClO4)4] decomposes at 35 °C, Rb[B(ClO4)4] is stable to 50 °C, and Cs[B(ClO4)4] can exist up to 80 °C.

<span class="mw-page-title-main">Caesium ozonide</span> Chemical compound

Caesium ozonide is an oxygen-rich chemical compound of caesium, with the chemical formula CsO3. It consists of caesium cations Cs+ and ozonide anions O−3. It can be formed by reacting ozone with caesium superoxide:

Caesium sesquioxide is a chemical compound with the formula Cs2O3 or more accurately Cs4O6. It is an oxide of caesium containing oxygen in different oxidation states. It consists of caesium cations Cs+, superoxide anions O−2 and peroxide anions O2−2. Caesium in this compound has an oxidation state of +1, while oxygen in superoxide has an oxidation state of −1/2 and oxygen in peroxide has an oxidation state of −1. This compound has a structural formula of (Cs+)4(O−2)2(O2−2). Compared to the other caesium oxides, this phase is less well studied, but has been long present in the literature. It can be created by thermal decomposition of caesium superoxide at 290 °C.

<span class="mw-page-title-main">Rubidium oxalate</span> Chemical compound

Rubidium oxalate is a chemical compound with the chemical formula Rb2C2O4. It is a rubidium salt of oxalic acid. It consists of rubidium cations Rb+ and oxalate anions C2O2−4. Rubidium oxalate forms a monohydrate Rb2C2O4·H2O.

<span class="mw-page-title-main">Rubidium permanganate</span> Chemical compound

Rubidium permanganate is the permanganate salt of rubidium, with the chemical formula RbMnO
4
.

References

  1. 1 2 R. Hoppe, D. Fischer, J. Schneider (1999), "Zur Kenntnis von Oxyden A[MO4]: Über LiMnO4, KMnO4, RbMnO4, CsMnO4 sowie RbIO4 und CsIO4. (– Was heißt eigentlich "Die Kristallstruktur von …"? –)", Zeitschrift für anorganische und allgemeine Chemie , vol. 625, no. 7, pp. 1521–3749, doi:10.1002/(SICI)1521-3749(199907)625:7<1135::AID-ZAAC1135>3.0.CO;2-L {{citation}}: CS1 maint: multiple names: authors list (link)
  2. 1 2 Aterton Seidell (1940), Solubilities of Organic Compounds, vol. 1, p. 1438
  3. Austin M. Patterson (1906), "Solubilities of Permanganates of the Alkali Metals", Journal of the American Chemical Society , vol. 28, no. 12, pp. 1734–1736, doi:10.1021/ja01978a009
  4. Groth, P. (Paul) (1877). Zeitschrift für Krystallographie und Mineralogie. New York Public Library. Leipzig : Wilhelm Engelmann.
  5. Beck, Michael W.; Brown, Michael E. (Jul 1983). "Thermal analysis of antimony/potassium permanganate pyrotechnic compositions". Thermochimica Acta. 65 (2–3): 197–212. doi:10.1016/0040-6031(83)80022-7.
  6. 1 2 Z. Gontarz, B. Pisarska (September 1990), "Thermal decomposition stages of potassium, rubidium and caesium permanganates", Journal of Thermal Analysis and Calorimetry , vol. 36, no. 6, pp. 2113–2117, doi:10.1007/BF01914135, S2CID   95763664