Names | |
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IUPAC name tetraiodoplatinum | |
Other names Platinum tetraiodide, platinic iodide, platinum(4+) tetraiodide | |
Identifiers | |
3D model (JSmol) | |
ECHA InfoCard | 100.029.280 |
EC Number |
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PubChem CID | |
UNII | |
CompTox Dashboard (EPA) | |
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Properties | |
I4Pt | |
Molar mass | 702.702 g·mol−1 |
Appearance | brown crystals |
Density | 6.06 g/cm3 |
Melting point | 130 °C (266 °F; 403 K) |
decomposes in water | |
Related compounds | |
Related compounds | Iridium tetraiodide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Platinum(IV) iodide is a inorganic compound with the formula PtI4. [1] it is a dark brown diamagnetic solid and is one of several binary iodides of platinum.
Platinum(IV) iodide can be prepared from the effect of iodine on platinum: [2]
Iodide accelerates this process. [3]
It can also be obtained from the decomposition of hydrogen hexaiodoplatinate(IV) at 80 °C:
Platinum(IV) iodide forms dark brown crystals of several modifications: [4]
Platinum(IV) iodide decomposes in water. It is also soluble in ethanol, acetone, alkali, HI, KI, liquid NH3. [6]
It decomposes when heated:
When dissolved in hydroiodic acid, platinum(IV) iodide forms hydrogen hexaiodoplatinate(IV):
Hydrogen iodide (HI) is a diatomic molecule and hydrogen halide. Aqueous solutions of HI are known as hydroiodic acid or hydriodic acid, a strong acid. Hydrogen iodide and hydroiodic acid are, however, different in that the former is a gas under standard conditions, whereas the other is an aqueous solution of the gas. They are interconvertible. HI is used in organic and inorganic synthesis as one of the primary sources of iodine and as a reducing agent.
Tellurium tetraiodide (TeI4) is an inorganic chemical compound. It has a tetrameric structure which is different from the tetrameric solid forms of TeCl4 and TeBr4. In TeI4 the Te atoms are octahedrally coordinated and edges of the octahedra are shared.
Tin(IV) iodide, also known as stannic iodide, is the chemical compound with the formula SnI4. This tetrahedral molecule crystallizes as a bright orange solid that dissolves readily in nonpolar solvents such as benzene.
Berkelium forms a number of chemical compounds, where it normally exists in an oxidation state of +3 or +4, and behaves similarly to its lanthanide analogue, terbium. Like all actinides, berkelium easily dissolves in various aqueous inorganic acids, liberating gaseous hydrogen and converting into the trivalent oxidation state. This trivalent state is the most stable, especially in aqueous solutions, but tetravalent berkelium compounds are also known. The existence of divalent berkelium salts is uncertain and has only been reported in mixed lanthanum chloride-strontium chloride melts. Aqueous solutions of Bk3+ ions are green in most acids. The color of the Bk4+ ions is yellow in hydrochloric acid and orange-yellow in sulfuric acid. Berkelium does not react rapidly with oxygen at room temperature, possibly due to the formation of a protective oxide surface layer; however, it reacts with molten metals, hydrogen, halogens, chalcogens and pnictogens to form various binary compounds. Berkelium can also form several organometallic compounds.
Trimethylplatinum iodide is the organoplatinum complex with the formula [(CH3)3PtI]4. It is a white, air-stable solid that was one of the first σ-alkyl metal complexes reported. It arises from the reaction of potassium hexachloroplatinate with methylmagnesium iodide. The complex exists as a tetramer: a cubane-type cluster with four octahedral Pt(IV) centers linked by four iodides as triply bridging ligands. Due to its stability, it is often utilized as a precursor en route to the synthesis of other organoplatinum compound, such as hydrosilylation catalysts. It is also used as a precursor for forming platinum layers for electronics.
Samarium(III) iodide is an inorganic compound, a salt of samarium and hydroiodic acid with the chemical formula SmI
3.
Platinum-samarium is a binary inorganic compound of platinum and samarium with the chemical formula PtSm. This intermetallic compound forms crystals.
Polonium tetraiodide is a binary inorganic compound of polonium and iodine with the chemical formula PoI
4. The compound forms volatile black crystals.
Europium(III) iodide is an inorganic compound containing europium and iodine with the chemical formula EuI3.
Californium(II) iodide is a binary inorganic compound of californium and iodine with the formula CfI
2.
Platinum(II) iodide is a binary inorganic compound of platinum and iodine with the chemical formula PtI
2.
Iridium(IV) iodide is a binary chemical compound of iridium and iodide with the chemical formula IrI
4.
Niobium(IV) iodide is an iodide of niobium, with the chemical formula of NbI4.
Tantalum(IV) iodide is an inorganic compound with the chemical formula TaI4. It dissolves in water to give a green solution, but the color fades when left in the air and produces a white precipitate.
Protactinium tetrafluoride is a binary inorganic compound of protactinium metal and fluorine with the chemical formula PaF4.
Protactinium tetraiodide is a binary inorganic compound of protactinium metal and iodine with the chemical formula PaI4.
Lanthanum(III) sulfide is a binary inorganic chemical compound of lanthanum metal and sulfur with the chemical formula La2S3.
Potassium hexafluororhenate is an inorganic chemical compound with the chemical formula K2ReF6.
Potassium hexaiodorhenate is an inorganic chemical compound with the chemical formula K2ReI6.
Potassium tetraiodoplatinate is the inorganic compound with the formula K2PtI4·(H2O)2. It is the potassium salt of tetraiodoplatinate, a square planar complex of platinum(II). The compound crystallizes from water as the dihydrate, whereas the related chloride and bromide K2PtCl4 and K2PtBr4 are obtained only as the anhydrous salts.