Platinum(II) bis(acetylacetonate)

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Platinum(II) bis(acetylacetonate)
Pt(acac)2.svg
HAHHIJ.png
Pt(acac)2.jpg
Names
IUPAC name
Bis(acetylacetonato)platinum(II)
Systematic IUPAC name
Bis[(Z)-4-oxopent-2-en-2-olato-κ2O,O′]platinum(II)
Other names
Bis(2,4-pentanedionato)platinum; Platinum bis(acetylacetonate); Bis(acetylacetonato)platinum
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.035.642 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 239-223-5
PubChem CID
  • InChI=1S/2C5H8O2.Pt/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/b2*4-3-;
    Key: VEJOYRPGKZZTJW-FDGPNNRMSA-N
  • coordination form:CC(=C[C-](C)O1)O[Pt+2]12OC(=C[C-](C)O2)C
  • ionic form:O=C(C)/C=C(C)\[O-].O=C(C)/C=C(C)\[O-].[Pt+2]
Properties
C10H14O4Pt
Molar mass 393.302 g·mol−1
Appearanceyellow solid
Density 2.362 g/cm3
Melting point 239.4 C (dec.) [1]
insoluble
Hazards
GHS labelling:
GHS-pictogram-exclam.svg GHS-pictogram-silhouette.svg
Warning
H302, H312, H315, H319, H332, H335, H361
P201, P202, P261, P264, P270, P271, P280, P281, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P308+P313, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Platinum(II) bis(acetylacetonate) is the coordination compound with the formula Pt(O2C5H7)2, abbreviated Pt(acac)2. The homoleptic acetylacetonate complex of platinum(II), it is a yellow, benzene-soluble solid. According to X-ray crystallography, the Pt center is square planar. [2] The compound is a widely used precursor to platinum-based catalysts. [3]

Packing of Pt(acac)2 molecules within a crystal. HAHHIJpack.png
Packing of Pt(acac)2 molecules within a crystal.

The complex is prepared by the reaction of the platinum(II) aquo complex [Pt(H2O)4]2+ with acetylacetone. [4]

See also

References

  1. ↑ Flanagan, Scott; Hall, Eric; Bowie, Wade; Fuhs, James W.; Logan, Robbie; Maniei, Farzaneh; Hunt, Andrew (2005). "A design-of-experiments approach to modeling activity coefficients in solvent mixtures: a case study using platinum(ii) acetylacetonate in mixtures of acetone, cyclohexanol, 1,2,3,4-tetrahydronaphthalene and propylene carbonate". Green Chemistry. 7 (5): 333. doi:10.1039/b418130a. ISSN   1463-9262.
  2. ↑ Ha, Kwang (2011). "Crystal Structure of Bis(pentane-2,4-dionato)κ2O,O')platinum(II), Pt(C5H7O2)2". Zeitschrift für Kristallographie - New Crystal Structures. 226 (3). doi: 10.1524/ncrs.2011.0147 .
  3. ↑ Xiaoqing Huang; Zipeng Zhao; Liang Cao; Yu Chen; Enbo Zhu; Zhaoyang Lin; Mufan Li; Aiming Yan; Alex Zettl; Y. Morris Wang; Xiangfeng Duan; Tim Mueller; Yu Huang (2015). "High-Performance Transition Metal-Doped Pt3Ni Octahedra for Oxygen Reduction Reaction". Science. 348 (6240): 1230–1234. Bibcode:2015Sci...348.1230H. doi: 10.1126/science.aaa8765 . PMID   26068847.
  4. ↑ Okeya, Seichi; Kawaguchi, Shinichi (1980). "The bis(β-Diketonato)Platinum(II) Complexes". The Bis(β‐diketonato)Platinum(II)Complexes. Inorganic Syntheses. Vol. 20. pp. 65–67. doi:10.1002/9780470132517.ch20. ISBN   9780470132517.
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