Thulium acetylacetonate

Thulium acetylacetonate

Names
Other names Thulium(III) acetylacetonate
Identifiers
CAS Number	14589-44-7 anhydrous Y trihydrate: 21826-63-1  Y
3D model (JSmol)	Interactive image trihydrate: Interactive image
ChemSpider	48063949 trihydrate: 22199481
PubChem CID	57369571
CompTox Dashboard (EPA)	DTXSID00724537
InChI InChI=1S/3C5H8O2.Tm/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3 Key: ASFMKHGVRGERPB-UHFFFAOYSA-K trihydrate:InChI=1S/3C5H8O2.3H2O.Tm/c3*1-4(6)3-5(2)7;;;;/h3*3,6H,1-2H3;3*1H2;/q;;;;;;+3/p-3/b3*4-3-;;;; Key: UZKSYWPAPWYRSV-VBBOVLQFSA-K
SMILES CC(=CC(=O)C)[O-].CC(=CC(=O)C)[O-].CC(=CC(=O)C)[O-].[Tm+3] trihydrate:CC(=CC(=O)C)[O-].CC(=CC(=O)C)[O-].CC(=CC(=O)C)[O-].[Tm+3].O.O.O
Properties
Chemical formula	C15H21O6Tm
Molar mass	466.261 g·mol−1
Appearance	powder [1] white powder (trihydrate) [2]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Thulium acetylacetonate is a coordination compound with the formula Tm(C₅H₇O₂)₃. This anhydrous acetylacetonate complex is often discussed but unlikely to exist per se. The 8-coordinated dihydrate Tm(C₅H₇O₂)₃(H₂O)₂ is a more plausible formula based on the behavior of other lanthanide acetylacetonates. The dihydrate has been characterized by X-ray crystallography. ^{[3] [4]} Upon attempted dehydration by heating under vacuum, other hydrated lanthanide tris(acetylacetonate) complexes decompose to give oxo-clusters. ^[5]

Thulium acetylacetonate can be prepared by the reaction of thulium hydroxide and acetylacetone. ^[6] Its monohydrate is not volatile. ^[7] The acetonitrile solution of its dihydrate and the dichloromethane solution of 5-[(4-fluorobenzylidene)amino]-8-hydroxyquinoline (HL) react by heating to obtain the complex [Tm₄(acac)₆(L)₆(μ₃-OH)₂]. ^[8]

References

1. Pierson, H.O. (1999). Handbook of Chemical Vapor Deposition: Principles, Technology and Applications. Materials Science and Process Technology. Elsevier Science. p. 92. ISBN   978-0-8155-1743-6. Archived from the original on 2021-10-17. Retrieved 2021-09-16.
2. Perry, D.L. (2016). Handbook of Inorganic Compounds. CRC Press. p. 494. ISBN   978-1-4398-1462-8. Archived from the original on 2021-09-16. Retrieved 2021-09-16.
3. Cheng, Shen; Yuguo, Fan; Yutian, Wang; Pinzhe, Lu; Guofa, Liu (1983). Gaodeng Xuexiao Huaxue Xuebao (Chem.J.Chin.Univ.). 4: 769.{{cite journal}}: Missing or empty |title= (help)
4. Cambridge Crystallographic Data Center, number CCDC 1121251.
5. Tamang, Sem Raj; Singh, Arpita; Bedi, Deepika; Bazkiaei, Adineh Rezaei; Warner, Audrey A.; Glogau, Keeley; McDonald, Corey; Unruh, Daniel K.; Findlater, Michael (2020). "Polynuclear Lanthanide–Diketonato Clusters for the Catalytic Hydroboration of Carboxamides and Esters". Nat. Catal. 3 (2): 154–162. doi:10.1038/s41929-019-0405-5. S2CID   209897045.
6. Spencer, J.F. (1919). The Metals of the Rare Earths. Monographs on inorganic and physical chemistry. Longmans, Green. p. 153. Archived from the original on 2021-09-16. Retrieved 2021-09-16.
7. Friend, J.N. (1917). A Text-book of Inorganic Chemistry. Griffin. p. 438. Archived from the original on 2021-09-16. Retrieved 2021-09-16.
8. Hong-Ling Gao; Li Jiang; Shuang Liu; Hai-Yun Shen; Wen-Min Wang; Jian-Zhong Cui (2016). "Multiple magnetic relaxation processes, magnetocaloric effect and fluorescence properties of rhombus-shaped tetranuclear rare earth complexes" . Dalton Transactions. 45 (1): 253–264. doi:10.1039/C5DT03790E. ISSN   1477-9226. PMID   26600114 . Retrieved 2021-09-20.

External reading

• Gschneidner, K.A.; Bunzli, J.C.G.; Pecharsky, V.K. (2005). Handbook on the Physics and Chemistry of Rare Earths. ISSN. Elsevier Science. ISBN   978-0-08-046102-1. Archived from the original on 2021-09-16. Retrieved 2021-09-16.