Gold monoiodide

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Gold monoiodide
AuI structure.png
Names
IUPAC name
Iodogold
Systematic IUPAC name
Gold(I) iodide
Other names
Gold monoiodide
Aurous iodide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.584 OOjs UI icon edit-ltr-progressive.svg
PubChem CID
UNII
  • InChI=1S/Au.HI/h;1H/q+1;/p-1 Yes check.svgY
    Key: ATGIETUGWDAYPU-UHFFFAOYSA-M Yes check.svgY
  • [Au]I
Properties
AuI
Molar mass 323.871 g/mol
AppearanceYellowish to greenish-yellow powder
Density 8.25 g/cm3 [1]
91.0·10−6 cm3/mol
Structure
tetragonal, Pearson symbol tP8, Z = 4
P42/ncm (No. 138) [1]
a = 0.435, b = 0.435, c = 1.373 nm
Hazards
GHS labelling: [2]
GHS-pictogram-exclam.svg
Warning
H315, H319, H335
P302+P352, P305+P351+P338
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Gold monoiodide is the inorganic compound of gold and iodine with the formula AuI. It can be synthesized by dissolving gold powder in an aqueous solution of iodine and potassium iodide. [3] With Lewis bases, AuI reacts to give numerous complexes. [4]

Contents

Preparation

Gold monoiodide can be obtained by reacting a tetrachloridoauric acid solution with furthermore potassium iodide. It is also possible to produce it by reacting gold and iodine in a protective atmosphere at around 390 °C. [5]

Properties

Gold monoiodide is a yellow, crystalline powder that gradually decomposes upon contact with water, humidity or light. It has a tetragonal crystal structure with the space group P42/ncm (space group no. 138), a = 4.359 Å, c = 13.711 Å. [5]

Related Research Articles

<span class="mw-page-title-main">Iodine</span> Chemical element, symbol I and atomic number 53

Iodine is a chemical element; it has symbol I and atomic number 53. The heaviest of the stable halogens, it exists at standard conditions as a semi-lustrous, non-metallic solid that melts to form a deep violet liquid at 114 °C (237 °F), and boils to a violet gas at 184 °C (363 °F). The element was discovered by the French chemist Bernard Courtois in 1811 and was named two years later by Joseph Louis Gay-Lussac, after the Ancient Greek Ιώδης 'violet-coloured'.

<span class="mw-page-title-main">Lead(II) iodide</span> Chemical compound

Lead(II) iodide is a chemical compound with the formula PbI
2
. At room temperature, it is a bright yellow odorless crystalline solid, that becomes orange and red when heated. It was formerly called plumbous iodide.

<span class="mw-page-title-main">Gold(III) chloride</span> Chemical compound

Gold(III) chloride, traditionally called auric chloride, is an inorganic compound of gold and chlorine with the molecular formula Au2Cl6. The "III" in the name indicates that the gold has an oxidation state of +3, typical for many gold compounds. It has two forms, the monohydrate (AuCl3·H2O) and the anhydrous form, which are both hygroscopic and light-sensitive solids. This compound is a dimer of AuCl3. This compound has a few uses, such as an oxidizing agent and for catalyzing various organic reactions.

<span class="mw-page-title-main">Iodic acid</span> Chemical compound (HIO3)

Iodic acid is a white water-soluble solid with the chemical formula HIO3. Its robustness contrasts with the instability of chloric acid and bromic acid. Iodic acid features iodine in the oxidation state +5 and is one of the most stable oxo-acids of the halogens. When heated, samples dehydrate to give iodine pentoxide. On further heating, the iodine pentoxide further decomposes, giving a mix of iodine, oxygen and lower oxides of iodine.

<span class="mw-page-title-main">Sodium periodate</span> Chemical compound

Sodium periodate is an inorganic salt, composed of a sodium cation and the periodate anion. It may also be regarded as the sodium salt of periodic acid. Like many periodates, it can exist in two different forms: sodium metaperiodate (formula‍ NaIO4) and sodium orthoperiodate (normally Na2H3IO6, but sometimes the fully reacted salt Na5IO6). Both salts are useful oxidising agents.

<span class="mw-page-title-main">Copper(I) iodide</span> Chemical compound

Copper(I) iodide is the inorganic compound with the formula CuI. It is also known as cuprous iodide. It is useful in a variety of applications ranging from organic synthesis to cloud seeding.

<span class="mw-page-title-main">Aluminium iodide</span> Chemical compound

Aluminium iodide is a chemical compound containing aluminium and iodine. Invariably, the name refers to a compound of the composition AlI
3
, formed by the reaction of aluminium and iodine or the action of HI on Al metal. The hexahydrate is obtained from a reaction between metallic aluminum or aluminum hydroxide with hydrogen iodide or hydroiodic acid. Like the related chloride and bromide, AlI
3
is a strong Lewis acid and will absorb water from the atmosphere. It is employed as a reagent for the scission of certain kinds of C-O and N-O bonds. It cleaves aryl ethers and deoxygenates epoxides.

Osmium compounds are compounds containing the element osmium (Os). Osmium forms compounds with oxidation states ranging from −2 to +8. The most common oxidation states are +2, +3, +4, and +8. The +8 oxidation state is notable for being the highest attained by any chemical element aside from iridium's +9 and is encountered only in xenon, ruthenium, hassium, iridium, and plutonium. The oxidation states −1 and −2 represented by the two reactive compounds Na
2
[Os
4
(CO)
13
]
and Na
2
[Os(CO)
4
]
are used in the synthesis of osmium cluster compounds.

<span class="mw-page-title-main">Palladium(II) iodide</span> Chemical compound

Palladium(II) iodide is an inorganic compound of palladium and iodine. It is commercially available, though less common than palladium(II) chloride, the usual entry point to palladium chemistry. Three polymorphs are known.

<span class="mw-page-title-main">Iodosilane</span> Chemical compound

Iodosilane is a chemical compound of silicon, hydrogen, and iodine. It is a colorless monoclinic crystal of space group P21/c at −157 °C.

<span class="mw-page-title-main">Germanium(IV) iodide</span> Chemical compound

Germanium(IV) iodide is an inorganic compound with the chemical formula GeI4.

Gallium monoiodide is an inorganic gallium compound with the formula GaI or Ga4I4. It is a pale green solid and mixed valent gallium compound, which can contain gallium in the 0, +1, +2, and +3 oxidation states. It is used as a pathway for many gallium-based products. Unlike the gallium(I) halides first crystallographically characterized, gallium monoiodide has a more facile synthesis allowing a synthetic route to many low-valent gallium compounds.

<span class="mw-page-title-main">Indium(III) iodide</span> Chemical compound

Indium(III) iodide or indium triiodide is a chemical compound of indium and iodine with the formula InI3.

Phosphide iodides or iodide phosphides are compounds containing anions composed of iodide (I) and phosphide (P3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the phosphide chlorides, arsenide iodides antimonide iodides and phosphide bromides.

<span class="mw-page-title-main">Praseodymium(III) iodide</span> Chemical compound

Praseodymium(III) iodide is an inorganic salt, consisting of the rare-earth metal praseodymium and iodine, with the chemical formula PrI3. It forms green crystals. It is soluble in water.

<span class="mw-page-title-main">Europium compounds</span> Compounds with at least one europium atom

Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl3, Eu(NO3)3 and Eu(CH3COO)3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in aqueous solution. Many europium compounds fluoresce under ultraviolet light due to the excitation of electrons to higher energy levels. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod.

<span class="mw-page-title-main">Lanthanum(III) iodide</span> Chemical compound

Lanthanum(III) iodide is an inorganic compound containing lanthanum and iodine with the chemical formula LaI
3
.

<span class="mw-page-title-main">Lutetium(III) iodide</span> Chemical compound

Lutetium(III) iodide or lutetium iodide is an inorganic compound consisting of iodine and lutetium, with the chemical formula of LuI3.

<span class="mw-page-title-main">Gadolinium(III) iodide</span> Chemical compound

Gadolinium(III) iodide is an iodide of gadolinium, with the chemical formula of GdI3. It is a yellow, highly hygroscopic solid with a bismuth(III) iodide-type crystal structure. In air, it quickly absorbs moisture and forms hydrates. The corresponding oxide iodide is also readily formed at elevated temperature.

<span class="mw-page-title-main">Disulfur diiodide</span> Chemical compound

Disulfur diiodide is an unstable inorganic chemical compound with the chemical formula S2I2. Its empirical formula is SI. It is a red-brown solid that decomposes above −30 °C to elemental sulfur and iodine.

References

  1. 1 2 Jagodzinski H. (1959). "Die Kristallstruktur des AuJ". Z. Kristallogr. 112 (1–6): 80–87. Bibcode:1959ZK....112...80J. doi:10.1524/zkri.1959.112.1-6.80. S2CID   96721760.
  2. Sigma-Aldrich 398411 (13-12-2021)
  3. Wilfling, Marion; Klinkhammer, Karl W. (2010). "Gold(I)-Mediated Silicon-Silicon Bond Metathesis at Room Temperature". Angewandte Chemie International Edition. 49 (18): 3219–3223. doi:10.1002/anie.200905950. PMID   20349479.
  4. Tang, Zhongjia; Litvinchuk, A. P.; Lee, Hye-G.; Guloy, Arnold M. (1 September 1998). "Crystal Structure and Vibrational Spectra of a New Viologen Gold(I) Iodide". Inorganic Chemistry. 37 (19): 4752–4753. doi:10.1021/ic980141q. PMID   11670634.
  5. 1 2 Handbuch der präparativen anorganischen Chemie. 2 (3., umgearb. Aufl ed.). Stuttgart: Enke. 1978. ISBN   978-3-432-87813-3.