Tetramethylammonium auride

Tetramethylammonium auride

Names
IUPAC name N,N,N-Trimethylmethanaminium auride
Identifiers
CAS Number	390801-81-7
3D model (JSmol)	Interactive image
InChI InChI=1S/C4H12N.Au/c1-5(2,3)4;/h1-4H3;/q+1;-1 Key: FNABMZORGWEURW-UHFFFAOYSA-N
SMILES C[N+](C)(C)C.[Au-]
Properties
Chemical formula	C4H12AuN
Molar mass	271.114 g·mol−1
Density	2.87
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Tetramethylammonium auride, (CH₃)₄NAu, is an ionic compound containing tetramethylammonium as cation and gold in a –1 oxidation state as anion. It is an example of a compound containing this rare ionic form of gold, and the first auride paired with a cation that is not a metal atom that has been synthesized. ^[1]

Production

Tetramethylammonium auride can be made from caesium auride dissolved in liquid ammonia reacting with tetramethylammonium chloride or an ion exchange resin. ^[1]

Properties

Tetramethylammonium auride decomposes over the period of a day at room temperature to form gold. However it is stable at −55°C. Crystals are transparent. ^[1]

The crystal structure is tetragonal with space group P4/nmm. Unit dell dimensions are a = 7.599, c = 5.433 Šwith volume V = 313.7 ų, Z = 2 formulas per unit cell. ^[1]

References

1. Dietzela, Pascal D. C.; Jansen, Martin (2001). "Synthesis and crystal structure determination of tetramethylammonium auride". Chemical Communications (21): 2208–2209. doi:10.1039/B105648B. PMID   12240114.

Further reading

• doi:10.1021/acs.inorgchem.2c00600 – Use of this compound to study the nature of tetramethylammonium–anion bonding