Dysprosium bismuthide

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Dysprosium bismuthide
NaCl polyhedra.png
Names
Other names
Dysprosium monobismuthide
Identifiers
3D model (JSmol)
  • InChI=1S/Bi.Dy.2H
    Key: KWPLIUAVNREDFA-UHFFFAOYSA-N
  • [Dy].[Bi]
Properties
BiDy
Molar mass 371.480 g·mol−1
Appearancepowder
Density 10.11 g/cm3 [1]
Melting point 2,050 °C (3,720 °F; 2,320 K) [1]
Related compounds
Other anions
Dysprosium nitride
Dysprosium phosphide
Dysprosium arsenide
Dysprosium antimonide
Other cations
Terbium phosphide
Holmium phosphide
Related compounds
Dy5Bi3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Dysprosium bismuthide is a binary inorganic compound of dysprosium and bismuth with the chemical formula DyBi. [2] [3]

Physical properties

The compound is rock-salt structured, crystallizing in the cubic Fm3m space group with unit cell dimension of a=6.249 Å. [1]

Related Research Articles

<span class="mw-page-title-main">Dysprosium</span> Chemical element with atomic number 66 (Dy)

Dysprosium is a chemical element; it has symbol Dy and atomic number 66. It is a rare-earth element in the lanthanide series with a metallic silver luster. Dysprosium is never found in nature as a free element, though, like other lanthanides, it is found in various minerals, such as xenotime. Naturally occurring dysprosium is composed of seven isotopes, the most abundant of which is 164Dy.

A period 6 element is one of the chemical elements in the sixth row (or period) of the periodic table of the chemical elements, including the lanthanides. The periodic table is laid out in rows to illustrate recurring (periodic) trends in the chemical behaviour of the elements as their atomic number increases: a new row is begun when chemical behaviour begins to repeat, meaning that elements with similar behaviour fall into the same vertical columns. The sixth period contains 32 elements, tied for the most with period 7, beginning with caesium and ending with radon. Lead is currently the last stable element; all subsequent elements are radioactive. For bismuth, however, its only primordial isotope, 209Bi, has a half-life of more than 1019 years, over a billion times longer than the current age of the universe. As a rule, period 6 elements fill their 6s shells first, then their 4f, 5d, and 6p shells, in that order; however, there are exceptions, such as gold.

<span class="mw-page-title-main">Pnictogen</span> Group 15 elements of the periodic table with valency 5

The pnictogens are the chemical elements in group 15 of the periodic table. This group is also known as the nitrogen group or nitrogen family. Group 15 consists of the elements nitrogen (N), phosphorus (P), arsenic (As), antimony (Sb), bismuth (Bi), and moscovium (Mc).

<span class="mw-page-title-main">Dysprosium(III) chloride</span> Chemical compound

Dysprosium(III) chloride (DyCl3), also known as dysprosium trichloride, is a compound of dysprosium and chlorine. It is a white to yellow solid which rapidly absorbs water on exposure to moist air to form a hexahydrate, DyCl3·6H2O. Simple rapid heating of the hydrate causes partial hydrolysis to an oxychloride, DyOCl.

<span class="mw-page-title-main">Terbium(III) bromide</span> Chemical compound

Terbium(III) bromide (TbBr3) is a crystalline chemical compound.

<span class="mw-page-title-main">Bismuth</span> Chemical element with atomic number 83 (Bi)

Bismuth is a chemical element; it has symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental bismuth occurs naturally, and its sulfide and oxide forms are important commercial ores. The free element is 86% as dense as lead. It is a brittle metal with a silvery-white color when freshly produced. Surface oxidation generally gives samples of the metal a somewhat rosy cast. Further oxidation under heat can give bismuth a vividly iridescent appearance due to thin-film interference. Bismuth is both the most diamagnetic element and one of the least thermally conductive metals known.

Chromium hydrides are compounds of chromium and hydrogen, and possibly other elements. Intermetallic compounds with not-quite-stoichometric quantities of hydrogen exist, as well as highly reactive molecules. When present at low concentrations, hydrogen and certain other elements alloyed with chromium act as softening agents that enables the movement of dislocations that otherwise not occur in the crystal lattices of chromium atoms.

<span class="mw-page-title-main">Dysprosium(III) hydroxide</span> Chemical compound

Dysprosium(III) hydroxide is an inorganic compound with the chemical formula Dy(OH)3.

Dysprosium(II) chloride (DyCl2), also known as dysprosium dichloride, is an ionic chemical compound of dysprosium and chlorine. This salt is a reduced compound, as the normal oxidation state of dysprosium in dysprosium compounds is +3.

<span class="mw-page-title-main">Neodymium bismuthide</span> Chemical compound

Neodymium bismuthide or Bismuth-Neodymium is a binary inorganic compound of neodymium and bismuth with the formula NdBi. It forms crystals.

<span class="mw-page-title-main">Dysprosium(III) bromide</span> Chemical compound

Dysprosium(III) bromide is an inorganic compound of bromine and dysprosium, with the chemical formula of DyBr3.

Holmium diantimonide is an inorganic compound with the chemical formula HoSb2. It is one of the antimonides of holmium. It can be obtained by reacting holmium and antimony at a certain temperature (1000~1500 °C) and pressure (30~65 kbar). X-ray diffraction shows its space group C222, unit cell parameters a=3.343 Å, b=5.790 Å, c=7.840 Å, Z=2.

Dysprosium(III) telluride is an inorganic compound, one of the tellurides of dysprosium, with the chemical formula Dy2Te3, where Dy is in the +3 oxidation state.

<span class="mw-page-title-main">Dysprosium nitride</span> Chemical compound

Dypsrosium nitride is a binary inorganic compound of dysprosium and nitride with the chemical formula DyN.

Under standard conditions, the elements dysprosium and tin combine to form a number of intermetallic compounds, the dysprosium stannides. Dysprosium stannides with simple empirical formulas include Dy5Sn3 and DySn2, but four other intermetallics have intermediate composition. None is believed to survive temperatures higher than 1,866 °C (3,391 °F), whereat Dy5Sn3 decomposes. Although dysprosium is a lanthanoid, its f orbitals likely participate in the metallic bonding: mixing dysprosium and tin releases an enthalpy quite different from mixing samarium and tin, with gadolinium and tin intermediate.

<span class="mw-page-title-main">Holmium bismuthide</span> Chemical compound

Holmium bismuthide is a binary inorganic compound of holmium and bismuth with the chemical formula HoBi.

<span class="mw-page-title-main">Dysprosium antimonide</span> Chemical compound

Dysprosium antimonide is a binary inorganic compound of dysprosium and antimony with the chemical formula DySb.

<span class="mw-page-title-main">Dysprosium monosulfide</span> Chemical compound

Dysprosium monosulfide is a binary inorganic compound of dysprosium and sulfur with the chemical formula DyS.

Dysprosium(III) sulfide is a binary inorganic compound of dysprosium and sulfur with the chemical formula Dy2S3.

References

  1. 1 2 3 Gschneidner, K. A.; Calderwood, F. W. (August 1989). "The Bi−Dy (Bismuth-Dysprosium) system". Bulletin of Alloy Phase Diagrams. 10 (4): 431–432. doi:10.1007/BF02882365.
  2. Borsese, A.; Borzone, G.; Ferro, R.; Delfino, S. (1 September 1977). "Heats of formation of dysprosium-bismuth alloys". Journal of the Less Common Metals . 55 (1): 115–120. doi:10.1016/0022-5088(77)90267-3. ISSN   0022-5088 . Retrieved 29 May 2024.
  3. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Cumulative Supplement to the Initial Inventory: User Guide and Indices. U.S. Environmental Protection Agency, Office of Toxic Substances. 1980. p. 128. Retrieved 29 May 2024.