Barium chloride fluoride

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Barium chloride fluoride
Barium chloride fluoride structure.png
Names
Other names
Barium chlorofluoride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.874 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 237-277-4
PubChem CID
  • InChI=1S/Ba.ClH.FH/h;2*1H/q+2;;/p-2
    Key: RBRFDGCVTRKUEW-UHFFFAOYSA-L
  • [F-].[Cl-].[Ba+2]
Properties
BaClF
Molar mass 191.78 g·mol−1
Appearancewhite crystals
Density g/cm3
Poorly soluble
Structure
Tetragonal
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Barium chloride fluoride is an inorganic chemical compound of barium, chlorine, and fluorine. [1] Its chemical formula is BaClF. [2] [3] The compound naturally occurs as Zhangpeishanite mineral of the Matlockite group. [4] One of the deposits where the mineral is mined is Bayan Obo in China. [5]

Contents

Synthesis

Barium fluoride can be prepared by precipitating barium chloride and ammonium fluoride in a solution.

Physical properties

Barium chloride fluoride forms white crystals. [6] The crystal structure of BaClF is a tetragonal distortion of that of fluoride type BaF
2
. [7]

The compound is poorly soluble in water. [8]

Related Research Articles

<span class="mw-page-title-main">Barium</span> Chemical element, symbol Ba and atomic number 56

Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element.

<span class="mw-page-title-main">Caesium</span> Chemical element, symbol Cs and atomic number 55

Caesium is a chemical element with the symbol Cs and atomic number 55. It is a soft, silvery-golden alkali metal with a melting point of 28.5 °C (83.3 °F), which makes it one of only five elemental metals that are liquid at or near room temperature. Caesium has physical and chemical properties similar to those of rubidium and potassium. It is pyrophoric and reacts with water even at −116 °C (−177 °F). It is the least electronegative element, with a value of 0.79 on the Pauling scale. It has only one stable isotope, caesium-133. Caesium is mined mostly from pollucite. Caesium-137, a fission product, is extracted from waste produced by nuclear reactors. It has the largest atomic radius of all elements whose radii have been measured or calculated, at about 260 picometers.

In chemistry, a salt is a chemical compound consisting of an ionic assembly of positively charged cations and negatively charged anions, which results in a compound with no net electric charge. A common example is table salt, with positively charged sodium ions and negatively charged chloride ions.

<span class="mw-page-title-main">Alkaline earth metal</span> Group of chemical elements

The alkaline earth metals are six chemical elements in group 2 of the periodic table. They are beryllium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), and radium (Ra). The elements have very similar properties: they are all shiny, silvery-white, somewhat reactive metals at standard temperature and pressure.

<span class="mw-page-title-main">Barium carbonate</span> Chemical compound

Barium carbonate is the inorganic compound with the formula BaCO3. Like most alkaline earth metal carbonates, it is a white salt that is poorly soluble in water. It occurs as the mineral known as witherite. In a commercial sense, it is one of the most important barium compounds.

<span class="mw-page-title-main">Barium chloride</span> Chemical compound

Barium chloride is an inorganic compound with the formula BaCl2. It is one of the most common water-soluble salts of barium. Like most other water-soluble barium salts, it is a white powder, highly toxic, and imparts a yellow-green coloration to a flame. It is also hygroscopic, converting to the dihydrate BaCl2·2H2O, which are colourless crystals with a bitter salty taste. It has limited use in the laboratory and industry.

<span class="mw-page-title-main">Lead(II) chloride</span> Chemical compound

Lead(II) chloride (PbCl2) is an inorganic compound which is a white solid under ambient conditions. It is poorly soluble in water. Lead(II) chloride is one of the most important lead-based reagents. It also occurs naturally in the form of the mineral cotunnite.

<span class="mw-page-title-main">Potassium fluoride</span> Ionic compound (KF)

Potassium fluoride is the chemical compound with the formula KF. After hydrogen fluoride, KF is the primary source of the fluoride ion for applications in manufacturing and in chemistry. It is an alkali halide salt and occurs naturally as the rare mineral carobbiite. Solutions of KF will etch glass due to the formation of soluble fluorosilicates, although HF is more effective.

Selenic acid is the inorganic compound with the formula H2SeO4. It is an oxoacid of selenium, and its structure is more accurately described as O2Se(OH)2. It is a colorless compound. Although it has few uses, one of its salts, sodium selenate is used in the production of glass and animal feeds.

<span class="mw-page-title-main">Cobalt(II) fluoride</span> Chemical compound

Cobalt(II) fluoride is a chemical compound with the formula (CoF2). It is a pink crystalline solid compound which is antiferromagnetic at low temperatures (TN=37.7 K) The formula is given for both the red tetragonal crystal, (CoF2), and the tetrahydrate red orthogonal crystal, (CoF2·4H2O). CoF2 is used in oxygen-sensitive fields, namely metal production. In low concentrations, it has public health uses. CoF2 is sparingly soluble in water. The compound can be dissolved in warm mineral acid, and will decompose in boiling water. Yet the hydrate is water-soluble, especially the di-hydrate CoF2·2H2O and tri-hydrate CoF2·3H2O forms of the compound. The hydrate will also decompose with heat.

<span class="mw-page-title-main">Akaganeite</span> Iron(III) oxide-hydroxide mineral

Akaganeite, also written as the deprecated Akaganéite, is a chloride-containing iron(III) oxide-hydroxide mineral, formed by the weathering of pyrrhotite (Fe1−xS).

<span class="mw-page-title-main">Barium iodide</span> Chemical compound

Barium iodide is an inorganic compound with the formula BaI2. The compound exists as an anhydrous and a hydrate (BaI2(H2O)2), both of which are white solids. When heated, hydrated barium iodide converts to the anhydrous salt. The hydrated form is freely soluble in water, ethanol, and acetone.

<span class="mw-page-title-main">Zinc fluoride</span> Chemical compound

Zinc fluoride is an inorganic chemical compound with the chemical formula ZnF2. It is encountered as the anhydrous form and also as the tetrahydrate, ZnF2·4H2O (rhombohedral crystal structure). It has a high melting point and has the rutile structure containing 6 coordinate zinc, which suggests appreciable ionic character in its chemical bonding. Unlike the other zinc halides, ZnCl2, ZnBr2 and ZnI2, it is not very soluble in water.

<span class="mw-page-title-main">Barium bromide</span> Chemical compound

Barium bromide is the chemical compound with the formula BaBr2. It is ionic in nature.

<span class="mw-page-title-main">Sodium fluorosilicate</span> Chemical compound

Sodium fluorosilicate is a compound with the chemical formula Na2[SiF6]. Unlike other sodium salts, it has a low solubility in water.

<span class="mw-page-title-main">Chromium(II) fluoride</span> Chemical compound

Chromium(II) fluoride is an inorganic compound with the formula CrF2. It exists as a blue-green iridescent solid. Chromium(II) fluoride is sparingly soluble in water, almost insoluble in alcohol, and is soluble in boiling hydrochloric acid, but is not attacked by hot distilled sulfuric acid or nitric acid. Like other chromous compounds, chromium(II) fluoride is oxidized to chromium(III) oxide in air.

Zhangpeishanite is a mineral named after Zhang Peishan, a Chinese mineralogist at the Institute of Geology of the Chinese Academy of Sciences, in recognition of his contributions to studying the mineralogy Bayan Obo deposit, where the mineral is mined. The Bayan Obo deposit is also known for being a world class deposit. The mineral got approved by the IMA in 2006 but was published two years after its approval. The mineral consists of barium chloride fluoride.

<span class="mw-page-title-main">Terbium compounds</span> Chemical compounds with at least one terbium atom

Terbium compounds are compounds formed by the lanthanide metal terbium (Tb). Terbium generally exhibits the +3 oxidation state in these compounds, such as in TbCl3, Tb(NO3)3 and Tb(CH3COO)3. Compounds with terbium in the +4 oxidation state are also known, such as TbO2 and BaTbF6. Terbium can also form compounds in the 0, +1 and +2 oxidation states.

Erbium compounds are compounds containing the element erbium (Er). These compounds are usually dominated by erbium in the +3 oxidation state, although the +2, +1 and 0 oxidation states have also been reported.

Radium compounds are compounds containing the element radium (Ra). Due to radium's radioactivity, not many compounds have been well characterized. Solid radium compounds are white as radium ions provide no specific coloring, but they gradually turn yellow and then dark over time due to self-radiolysis from radium's alpha decay. Insoluble radium compounds coprecipitate with all barium, most strontium, and most lead compounds.

References

  1. Hagemann, H.; D’Anna, V.; Lawson Daku, M.; Kubel, F. (7 March 2012). "Crystal Chemistry in the Barium Fluoride Chloride System". Crystal Growth & Design . 12 (3): 1124–1131. doi:10.1021/cg201588s. ISSN   1528-7483 . Retrieved 26 March 2023.
  2. "System of Registries | US EPA". United States Environmental Protection Agency . Retrieved 26 March 2023.
  3. "CAS 13718-55-3 Barium chloride fluoride - Alfa Chemistry". Alfa Chemistry. Retrieved 26 March 2023.
  4. 英彦, 島崎; 律郎, 宮脇; 一己, 横山; 聰, 松原; 主明, 楊 (2007). "中国内モンゴル白雲鄂博産の新鉱物,張培善石". 日本鉱物科学会年会講演要旨集. 2007: 198. doi:10.14824/jakoka.2007.0.198.0 . Retrieved 27 March 2023.
  5. "Zhangpeishanite". mindat.org. Retrieved 27 March 2023.
  6. Lide, David R. (19 June 2003). 1998 Freshman Achievement Award. CRC Press. pp. 4–49. ISBN   978-0-8493-0594-8 . Retrieved 26 March 2023.
  7. Marcus, Philippe; Maurice, Vincent (25 May 2006). Passivation of Metals and Semiconductors, and Properties of Thin Oxide Layers: A Selection of Papers from the 9th International Symposium, Paris, France, 27 June - 1 July 2005. Elsevier. p. 150. ISBN   978-0-08-046152-6 . Retrieved 26 March 2023.
  8. Comey, Arthur Messinger (1896). A Dictionary of chemical solubilities. Macmillan and Company. p. 47. Retrieved 26 March 2023.