Barium thiocyanate

Last updated
Barium thiocyanate [1] [2]
Barium thiocyanate.svg
Names
IUPAC name
Barium thiocyanate
Other names
  • Barium sulfur cyanide
  • Barium(II) thiocyanate
  • Barium sulfocyanide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.016.587 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 218-245-9
PubChem CID
UNII
  • InChI=1S/2CHNS.Ba/c2*2-1-3;/h2*3H;/q;;+2/p-2
    Key: LKZCRGABYQYUFX-UHFFFAOYSA-L
  • C(#N)[S-].C(#N)[S-].[Ba+2]
Properties
Ba(SCN)2
Molar mass 253.49 g/mol
AppearanceWhite crystals
62.63 g/100 ml (25°C)
Solubility Soluble in acetone, methanol, and ethanol
Hazards
GHS labelling:
GHS-pictogram-exclam.svg
H301, H312, H315, H319, H332, H335
P261, P280, P302+P352, P304+P340
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Barium thiocyanate refers to salts of the formula Ba(SCN)2.xH2O. Both an anhydrous salt and a trihydrate are known. The anhydrous salt is hygroscopic. The trihydrate is soluble in most alcohols but insoluble in simple alkanes. Barium thiocyanate is used in dyeing textiles and in some photographic solutions. But because of its toxicity, it has limited uses. [3]

Preparation and structure

Barium thiocyanate is prepared by mixing barium hydroxide and ammonium thiocyanate in water. [4]

2 NH4SCN + Ba(OH)2 → Ba(SCN)2 + 2 NH3 + 2 H2O

According to X-ray crystallography, the anhydrous salt is a coordination polymer. The Ba2+ ions are each bonded to eight thiocyanate anions, with four Ba-S and four Ba-N bonds. The motif is reminiscent of the fluorite structure. [5] Strontium thiocyanate, calcium thiocyanate, and lead thiocyanate adopt the same structure.

Related Research Articles

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<span class="mw-page-title-main">Barium chloride</span> Chemical compound

Barium chloride is an inorganic compound with the formula BaCl2. It is one of the most common water-soluble salts of barium. Like most other water-soluble barium salts, it is a white powder, highly toxic, and imparts a yellow-green coloration to a flame. It is also hygroscopic, converting to the dihydrate BaCl2·2H2O, which are colourless crystals with a bitter salty taste. It has limited use in the laboratory and industry.

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<span class="mw-page-title-main">Aluminium fluoride</span> Chemical compound

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<span class="mw-page-title-main">Mercury(II) thiocyanate</span> Chemical compound

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<span class="mw-page-title-main">Cobalt(II) nitrate</span> Chemical compound

Cobalt nitrate is the inorganic compound with the formula Co(NO3)2.xH2O. It is cobalt(II)'s salt. The most common form is the hexahydrate Co(NO3)2·6H2O, which is a red-brown deliquescent salt that is soluble in water and other polar solvents.

<span class="mw-page-title-main">Potassium ferrioxalate</span> Chemical compound

Potassium ferrioxalate, also called potassium trisoxalatoferrate or potassium tris(oxalato)ferrate(III) is a chemical compound with the formula K3[Fe(C2O4)3]. It often occurs as the trihydrate K3[Fe(C2O4)3]·3H2O. Both are crystalline compounds, lime green in colour.

<span class="mw-page-title-main">Thiocyanogen</span> Chemical compound

Thiocyanogen, (SCN)2, is a pseudohalogen derived from the pseudohalide thiocyanate, [SCN], with behavior intermediate between dibromine and diiodine. This hexatomic compound exhibits C2 point group symmetry and has the connectivity NCS-SCN.

<span class="mw-page-title-main">Cobalt(II) thiocyanate</span> Chemical compound

Cobalt(II) thiocyanate is an inorganic compound with the formula Co(SCN)2. The anhydrous compound is a coordination polymer with a layered structure. The trihydrate, Co(SCN)2(H2O)3, is a isothiocyanate complex used in the cobalt thiocyanate test (or Scott test) for detecting cocaine. The test has been responsible for widespread false positives and false convictions.

<span class="mw-page-title-main">Barium bromide</span> Chemical compound

Barium bromide is the chemical compound with the formula BaBr2. It is ionic and hygroscopic in nature.

<span class="mw-page-title-main">Nickel(II) bromide</span> Chemical compound

Nickel(II) bromide is the name for the inorganic compounds with the chemical formula NiBr2(H2O)x. The value of x can be 0 for the anhydrous material, as well as 2, 3, or 6 for the three known hydrate forms. The anhydrous material is a yellow-brown solid which dissolves in water to give blue-green hexahydrate (see picture).

Lead(II) thiocyanate is a compound, more precisely a salt, with the formula Pb(SCN)2. It is a white crystalline solid, but will turn yellow upon exposure to light. It is slightly soluble in water and can be converted to a basic salt (Pb(CNS)2·Pb(OH)2 when boiled. Salt crystals may form upon cooling. Lead thiocyanate can cause lead poisoning if ingested and can adversely react with many substances. It has use in small explosives, matches, and dyeing.

<span class="mw-page-title-main">Silver thiocyanate</span> Chemical compound

Silver thiocyanate is the silver salt of thiocyanic acid with the formula AgSCN. Silver thiocyanate appears as a white crystalline powder. It is very commonly used in the synthesis of silver nanoparticles. Additionally, studies have found silver nanoparticles to be present in saliva present during the entire digestive process of silver nitrate. Silver thiocyanate is slightly soluble in water, with a solubility of 1.68 x 10−4 g/L. It is insoluble in ethanol, acetone, and acid.

<span class="mw-page-title-main">Copper(I) thiocyanate</span> Chemical compound

Copper(I) thiocyanate is a coordination polymer with formula CuSCN. It is an air-stable, white solid used as a precursor for the preparation of other thiocyanate salts.

Lithium thiocyanate is a chemical compound with the formula LiSCN. It is an extremely hygroscopic white solid that forms the monohydrate and the dihydrate. It is the least stable of the alkali metal thiocyanates due to the large electrostatic deforming field of the lithium cation.

Transition metal complexes of thiocyanate describes coordination complexes containing one or more thiocyanate (SCN-) ligands. The topic also includes transition metal complexes of isothiocyanate. These complexes have few applications but played significant role in the development of coordination chemistry.

<span class="mw-page-title-main">Strontium thiocyanate</span> Water-soluble salt

Strontium thiocyanate refers to the salt Sr(SCN)2. It is a colorless solid. According to X-ray crystallography, it is a coordination polymer. The Sr2+ ions are each coordinated to eight thiocyanate anions in a distorted square antiprismatic molecular geometry where each square face contains two adjacent S atoms and two adjacent N atoms. The motif is reminiscent of the fluorite structure. The same structure is observed for Ca(SCN)2, Ba(SCN)2, and Pb(SCN)2.

References

  1. "Barium thiocyanate | 336879-43-7". Sigma-Aldrich. 2012-09-14. Retrieved 2021-01-20.
  2. "BARIUM THIOCYANATE | 2092-17-3". Chemicalbook.com. 2020-07-03. Retrieved 2021-01-20.
  3. "Barium thiocyanate - CAMEO". Cameo.mfa.org. 2016-04-29. Retrieved 2021-01-20.
  4. Herstein, Karl M. (1950). "Barium Thiocyanate". Inorganic Syntheses. 3: 24–26.
  5. Cliffe, Matthew J. (2024). "Inorganic Metal Thiocyanates". Inorganic Chemistry. 63 (29): 13137–13156. doi:10.1021/acs.inorgchem.4c00920. PMC   11271006 . PMID   38980309.