Names | |
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IUPAC name Barium thiocyanate | |
Other names
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Identifiers | |
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3D model (JSmol) | |
ChemSpider | |
ECHA InfoCard | 100.016.587 |
EC Number |
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PubChem CID | |
UNII | |
CompTox Dashboard (EPA) | |
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Properties | |
Ba(SCN)2 | |
Molar mass | 253.49 g/mol |
Appearance | White crystals |
62.63 g/100 ml (25°C) | |
Solubility | Soluble in acetone, methanol, and ethanol |
Hazards | |
GHS labelling: | |
H301, H312, H315, H319, H332, H335 | |
P261, P280, P302+P352, P304+P340 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Barium thiocyanate is a colorless water-soluble salt that is very hygroscopic. It is highly toxic to ingestion and irritates the skin. It is also soluble in most alcohols and insoluble in simple alkanes.
Barium thiocyanate is used in dyeing textiles and is an ingredient in some photographic solutions. But because of its toxicity, it has limited uses. [3]
Barium thiocyanate is prepared by dissolving barium metal or barium nitrate in a solution of thiocyanic acid.[ citation needed ]
Barium is a chemical element; it has symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element.
Barium hydroxide is a chemical compound with the chemical formula Ba(OH)2. The monohydrate (x = 1), known as baryta or baryta-water, is one of the principal compounds of barium. This white granular monohydrate is the usual commercial form.
Barium sulfate (or sulphate) is the inorganic compound with the chemical formula BaSO4. It is a white crystalline solid that is odorless and insoluble in water. It occurs in nature as the mineral barite, which is the main commercial source of barium and materials prepared from it. Its opaque white appearance and its high density are exploited in its main applications.
Barium carbonate is the inorganic compound with the formula BaCO3. Like most alkaline earth metal carbonates, it is a white salt that is poorly soluble in water. It occurs as the mineral known as witherite. In a commercial sense, it is one of the most important barium compounds.
Thiocyanates are salts containing the thiocyanate anion [SCN]−. [SCN]− is the conjugate base of thiocyanic acid. Common salts include the colourless salts potassium thiocyanate and sodium thiocyanate. Mercury(II) thiocyanate was formerly used in pyrotechnics.
Barium chloride is an inorganic compound with the formula BaCl2. It is one of the most common water-soluble salts of barium. Like most other water-soluble barium salts, it is a white powder, highly toxic, and imparts a yellow-green coloration to a flame. It is also hygroscopic, converting to the dihydrate BaCl2·2H2O, which are colourless crystals with a bitter salty taste. It has limited use in the laboratory and industry.
Barium nitrate is the inorganic compound with the chemical formula Ba(NO3)2. It, like most barium salts, is colorless, toxic, and water-soluble. It burns with a green flame and is an oxidizer; the compound is commonly used in pyrotechnics.
A salt metathesis reaction is a chemical process involving the exchange of bonds between two reacting chemical species which results in the creation of products with similar or identical bonding affiliations. This reaction is represented by the general scheme:
Mercury(II) cyanide, also known as mercuric cyanide, is a poisonous compound of mercury and cyanide. It is an odorless, toxic white powder. It is highly soluble in polar solvents such as water, alcohol, and ammonia, slightly soluble in ether, and insoluble in benzene and other hydrophobic solvents.
Mercury(II) thiocyanate is an inorganic chemical compound, the coordination complex of Hg2+ and the thiocyanate anion. It is a white powder. It will produce a large, winding "snake" when ignited, an effect known as the Pharaoh's serpent.
Sodium thiocyanate (sometimes called sodium sulphocyanide) is the chemical compound with the formula NaSCN. This colorless deliquescent salt is one of the main sources of the thiocyanate anion. As such, it is used as a precursor for the synthesis of pharmaceuticals and other specialty chemicals. Thiocyanate salts are typically prepared by the reaction of cyanide with elemental sulfur:
Barium chlorate, Ba(ClO3)2, is the barium salt of chloric acid. It is a white crystalline solid, and like all soluble barium compounds, irritant and toxic. It is sometimes used in pyrotechnics to produce a green color. It also finds use in the production of chloric acid.
Cobalt(II) thiocyanate is an inorganic compound with the formula Co(SCN)2. The anhydrous compound is a coordination polymer with a layered structure. The trihydrate, Co(SCN)2(H2O)3, is a isothiocyanate complex used in the cobalt thiocyanate test (or Scott test) for detecting cocaine. The test has been responsible for widespread false positives and false convictions.
Barium bromide is the chemical compound with the formula BaBr2. It is ionic and hygroscopic in nature.
Methanesulfonic acid or methanesulphonic acid is an organosulfuric, colorless liquid with the molecular formula CH3SO3H and structure H3C−S(=O)2−OH. It is the simplest of the alkylsulfonic acids. Salts and esters of methanesulfonic acid are known as mesylates. It is hygroscopic in its concentrated form. Methanesulfonic acid can dissolve a wide range of metal salts, many of them in significantly higher concentrations than in hydrochloric acid (HCl) or sulfuric acid.
Lead(II) thiocyanate is a compound, more precisely a salt, with the formula Pb(SCN)2. It is a white crystalline solid, but will turn yellow upon exposure to light. It is slightly soluble in water and can be converted to a basic salt (Pb(CNS)2·Pb(OH)2 when boiled. Salt crystals may form upon cooling. Lead thiocyanate can cause lead poisoning if ingested and can adversely react with many substances. It has use in small explosives, matches, and dyeing.
Barium acetate (Ba(C2H3O2)2) is the salt of barium(II) and acetic acid. Barium acetate is toxic to humans, but it has use in chemistry and manufacturing.
Barium perchlorate is a powerful oxidizing agent, with the formula Ba(ClO4)2. It is used in the pyrotechnic industry.
Silver thiocyanate is the silver salt of thiocyanic acid with the formula AgSCN. Silver thiocyanate appears as a white crystalline powder. It is very commonly used in the synthesis of silver nanoparticles. Additionally, studies have found silver nanoparticles to be present in saliva present during the entire digestive process of silver nitrate. Silver thiocyanate is slightly soluble in water, with a solubility of 1.68 x 10−4 g/L. It is insoluble in ethanol, acetone, and acid.
Copper(I) thiocyanate is a coordination polymer with formula CuSCN. It is an air-stable, white solid used as a precursor for the preparation of other thiocyanate salts.