Barium thiocyanate

Last updated
Barium thiocyanate [1] [2]
Barium thiocyanate.svg
Names
IUPAC name
Barium thiocyanate
Other names
  • Barium sulfur cyanide
  • Barium(II) thiocyanate
  • Barium sulfocyanide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.016.587 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 218-245-9
PubChem CID
UNII
  • InChI=1S/2CHNS.Ba/c2*2-1-3;/h2*3H;/q;;+2/p-2
    Key: LKZCRGABYQYUFX-UHFFFAOYSA-L
  • C(#N)[S-].C(#N)[S-].[Ba+2]
Properties
Ba(SCN)2
Molar mass 253.49 g/mol
AppearanceWhite crystals
62.63 g/100 ml (25°C)
Solubility Soluble in acetone, methanol, and ethanol
Hazards
GHS labelling:
GHS-pictogram-exclam.svg
H301, H312, H315, H319, H332, H335
P261, P280, P302+P352, P304+P340
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Barium thiocyanate is a colorless water-soluble salt that is very hygroscopic. It is highly toxic to ingestion and irritates the skin. It is also soluble in most alcohols and insoluble in simple alkanes.

Contents

Uses

Barium thiocyanate is used in dyeing textiles and is an ingredient in some photographic solutions. But because of its toxicity, it has limited uses. [3]

Preparation

Barium thiocyanate is prepared by dissolving barium metal or barium nitrate in a solution of thiocyanic acid.

Related Research Articles

Barium Chemical element, symbol Ba and atomic number 56

Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element.

Gold cyanidation is a hydrometallurgical technique for extracting gold from low-grade ore by converting the gold to a water-soluble coordination complex. It is the most commonly used leaching process for gold extraction.

Barium hydroxide Chemical compound

Barium hydroxide is a chemical compound with the chemical formula Ba(OH)2. The monohydrate (x = 1), known as baryta or baryta-water, is one of the principal compounds of barium. This white granular monohydrate is the usual commercial form.

Barium sulfate Inorganic compound

Barium sulfate (or sulphate) is the inorganic compound with the chemical formula BaSO4. It is a white crystalline solid that is odorless and insoluble in water. It occurs as the mineral barite, which is the main commercial source of barium and materials prepared from it. The white opaque appearance and its high density are exploited in its main applications.

Barium carbonate Chemical compound

Barium carbonate is the inorganic compound with the formula BaCO3. Like most alkaline earth metal carbonates, it is a white salt that is poorly soluble in water. It occurs as the mineral known as witherite. In a commercial sense, it is one of the most important barium compounds.

Thiocyanate Ion

Thiocyanate is the anion [SCN]. It is the conjugate base of thiocyanic acid. Common derivatives include the colourless salts potassium thiocyanate and sodium thiocyanate. Mercury(II) thiocyanate was formerly used in pyrotechnics.

Barium chloride Chemical compound

Barium chloride is an inorganic compound with the formula BaCl2. It is one of the most common water-soluble salts of barium. Like most other water-soluble barium salts, it is white, highly toxic, and imparts a yellow-green coloration to a flame. It is also hygroscopic, converting first to the dihydrate BaCl2(H2O)2. It has limited use in the laboratory and industry.

Barium nitrate Chemical compound

Barium nitrate is the inorganic compound with the chemical formula Ba(NO3)2. It, like most barium salts, is colorless, toxic, and water-soluble. It burns with a green flame and is an oxidizer; the compound is commonly used in pyrotechnics.

Ammonium sulfate Chemical compound

Ammonium sulfate (American English and international scientific usage; ammonium sulphate in British English); (NH4)2SO4, is an inorganic salt with a number of commercial uses. The most common use is as a soil fertilizer. It contains 21% nitrogen and 24% sulfur.

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Mercury(II) cyanide Chemical compound

Mercury(II) cyanide, also known as mercuric cyanide, is a compound of mercury. It is an odorless, toxic white powder. It is highly soluble in polar solvents such as water, alcohol, and ammonia; slightly soluble in ether; and insoluble in benzene and other hydrophobic solvents.

Radium bromide Chemical compound

Radium bromide is the bromide salt of radium, with the formula RaBr2. It is produced during the process of separating radium from uranium ore. This inorganic compound was discovered by Pierre and Marie Curie in 1898, and the discovery sparked a huge interest in radiochemistry and radiotherapy. Since elemental radium oxidizes readily in air and water, radium salts are the preferred chemical form of radium to work with. Even though it is more stable than elemental radium, radium bromide is still extremely toxic, and can explode under certain conditions.

Barium chlorate Chemical compound

Barium chlorate, Ba(ClO3)2, is the barium salt of chloric acid. It is a white crystalline solid, and like all soluble barium compounds, irritant and toxic. It is sometimes used in pyrotechnics to produce a green color. It also finds use in the production of chloric acid.

Cobalt(II) thiocyanate Chemical compound

Cobalt(II) thiocyanate is an inorganic compound with the formula Co(SCN)2. It is a layered coordination complex and its trihydrate Co(SCN)2(H2O)3 is used in the cobalt thiocyanate test (or Scott test) for detecting cocaine. The test has been responsible for widespread false positives and false convictions.

Barium bromide Chemical compound

Barium bromide is the chemical compound with the formula BaBr2. Like barium chloride, it dissolves well in water and is toxic.

Lead(II) thiocyanate Chemical compound

Lead(II) thiocyanate is a compound, more precisely a salt, with the formula Pb(SCN)2. It is a white crystalline solid, but will turn yellow upon exposure to light. It is slightly soluble in water and can be converted to a basic salt (Pb(CNS)2·Pb(OH)2 when boiled. Salt crystals may form upon cooling. Lead thiocyanate can cause lead poisoning if ingested and can adversely react with many substances. It has use in small explosives, matches, and dyeing.

Barium acetate Chemical compound

Barium acetate (Ba(C2H3O2)2) is the salt of barium(II) and acetic acid. Barium acetate is toxic to humans, but has use in chemistry and manufacturing.

Barium perchlorate is a powerful oxidizing agent, with the formula Ba(ClO4)2. It is used in the pyrotechnic industry.

Copper(I) thiocyanate Chemical compound

Copper(I) thiocyanate is a coordination polymer with formula CuSCN. It is an air-stable, white solid used as a precursor for the preparation of other thiocyanate salts.

Potassium dicyanoaurate is an inorganic compound with formula K[Au(CN)2]. It is a colorless to white solid that is soluble in water and slightly soluble in alcohol. The salt itself is often not isolated, but solutions of the dicyanoaurate ion ([Au(CN)2]-) are generated on a large scale in the extraction of gold from its ores.

References

  1. "Barium thiocyanate | 336879-43-7". Sigma-Aldrich. 2012-09-14. Retrieved 2021-01-20.
  2. "BARIUM THIOCYANATE | 2092-17-3". Chemicalbook.com. 2020-07-03. Retrieved 2021-01-20.
  3. "Barium thiocyanate - CAMEO". Cameo.mfa.org. 2016-04-29. Retrieved 2021-01-20.