Periodyl fluoride

Periodyl fluoride

Names
Other names Periodylfluoride
Identifiers
CAS Number	30708-86-2  Y
3D model (JSmol)	Interactive image
PubChem CID	44233512
InChI InChI=1S/FIO3/c1-2(3,4)5 Key: OXDIZDWCOMFELV-UHFFFAOYSA-N
SMILES O=I(=O)(=O)F
Properties
Chemical formula	FIO3
Molar mass	193.900 g·mol−1
Appearance	colorless crystals
Related compounds
Related compounds	Iodosyl trifluoride Perchloryl fluoride Perbromyl fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Periodyl fluoride is an inorganic compound of iodine, fluorine, and oxygen with the chemical formula IO₃F. ^[1] The compound has been initially synthesized around 1950. ^[2]

Synthesis

Synthesis of periodyl fluoride is by fluorination of KIO₄ in liquid HF: ^[3]

KIO₄ + 2 HF → IO₃F + KF + H₂O

Physical properties

Periodyl fluoride forms colorless crystals. ^[4] Decomposes at 90 to 100 °C. ^[5]

References

1. Advances in Inorganic Chemistry and Radiochemistry. Academic Press. 1 January 1963. p. 84. ISBN   978-0-08-057854-5 . Retrieved 24 May 2023.
2. So, S. P.; Chau, F. T. (June 1973). "Urey-Bradley Force Field of Perhalyl Fluorides" . Zeitschrift für Physikalische Chemie . 85 (1–4): 69–75. doi:10.1524/zpch.1973.85.1-4.069. S2CID   101872763 . Retrieved 24 May 2023.
3. Wiberg, Egon; Wiberg, Nils (2001). Inorganic Chemistry. Academic Press. p. 468. ISBN   978-0-12-352651-9 . Retrieved 24 May 2023.
4. Haynes, William M. (4 June 2014). CRC Handbook of Chemistry and Physics. CRC Press. p. 4-67. ISBN   978-1-4822-0868-9 . Retrieved 24 May 2023.
5. Simons, J. H. (2 December 2012). Fluorine Chemistry V5. Elsevier. p. 91. ISBN   978-0-323-14724-8 . Retrieved 24 May 2023.