Periodyl fluoride

Last updated
Periodyl fluoride
Names
Other names
Periodylfluoride
Identifiers
3D model (JSmol)
PubChem CID
  • InChI=1S/FIO3/c1-2(3,4)5
    Key: OXDIZDWCOMFELV-UHFFFAOYSA-N
  • O=I(=O)(=O)F
Properties
FIO3
Molar mass 193.900 g·mol−1
Appearancecolorless crystals
Related compounds
Related compounds
Iodosyl trifluoride
Perchloryl fluoride
Perbromyl fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Periodyl fluoride is an inorganic compound of iodine, fluorine, and oxygen with the chemical formula IO3F. [1] The compound has been initially synthesized around 1950. [2]

Contents

Synthesis

Synthesis of periodyl fluoride is by fluorination of KIO4 in liquid HF: [3]

KIO4 + HF → IO3F + KF + ½ O2

Physical properties

Periodyl fluoride forms colorless crystals. [4] Decomposes at 90 to 100 °C. [5]

Related Research Articles

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Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. Solutions of HF are colorless, acidic and highly corrosive. It is used to make most fluorine-containing compounds; examples include the commonly used pharmaceutical antidepressant medication fluoxetine (Prozac) and the material PTFE (Teflon). Elemental fluorine is produced from it. It is commonly used to etch glass and silicon wafers.

<span class="mw-page-title-main">Xenon hexafluoride</span> Chemical compound

Xenon hexafluoride is a noble gas compound with the formula XeF6. It is one of the three binary fluorides of xenon that have been studied experimentally, the other two being XeF2 and XeF4. All known are exergonic and stable at normal temperatures. XeF6 is the strongest fluorinating agent of the series. It is a colorless solid that readily sublimes into intensely yellow vapors.

<span class="mw-page-title-main">Thionyl fluoride</span> Chemical compound

Thionyl fluoride is the inorganic compound with the formula SOF
2
. This colourless gas is mainly of theoretical interest, but it is a product of the degradation of sulfur hexafluoride, an insulator in electrical equipment. The molecule adopts a distorted pyramidal structure, with Cs symmetry. The S-O and S-F distances are 1.42 and 1.58 Å, respectively. The O-S-F and F-S-F angles are 106.2 and 92.2°, respectively. Thionyl chloride and thionyl bromide have similar structures, although these compounds are liquid at room temperature. Mixed halides are also known, such as SOClF, thionyl chloride fluoride.

<span class="mw-page-title-main">Silver(II) fluoride</span> Chemical compound

Silver(II) fluoride is a chemical compound with the formula AgF2. It is a rare example of a silver(II) compound. Silver usually exists in its +1 oxidation state. It is used as a fluorinating agent.

Antimony pentafluoride is the inorganic compound with the formula SbF5. This colourless, viscous liquid is a strong Lewis acid and a component of the superacid fluoroantimonic acid, formed upon mixing liquid HF with liquid SbF5 in 1:1 ratio. It is notable for its strong Lewis acidity and the ability to react with almost all known compounds.

<span class="mw-page-title-main">Tantalum pentafluoride</span> Chemical compound

Tantalum(V) fluoride is the inorganic compound with the formula TaF5. It is one of the principal molecular compounds of tantalum. Characteristic of some other pentafluorides, the compound is volatile but exists as an oligomer in the solid state.

Vanadium(IV) fluoride (VF4) is an inorganic compound of vanadium and fluorine. It is paramagnetic yellow-brown solid that is very hygroscopic. Unlike the corresponding vanadium tetrachloride, the tetrafluoride is not volatile because it adopts a polymeric structure. It decomposes before melting.

<span class="mw-page-title-main">Tungsten(VI) oxytetrafluoride</span> Chemical compound

Tungsten(VI) oxytetrafluoride (WOF4) is an inorganic chemical compound.

<span class="mw-page-title-main">Chloryl fluoride</span> Chemical compound

Chloryl fluoride is the chemical compound with the formula ClO2F. It is commonly encountered as side-product in reactions of chlorine fluorides with oxygen sources. It is the acyl fluoride of chloric acid.

<span class="mw-page-title-main">Fluorine</span> Chemical element, symbol F and atomic number 9

Fluorine is a chemical element with the symbol F and atomic number 9. It is the lightest halogen and exists at standard conditions as a highly toxic, pale yellow diatomic gas. As the most electronegative reactive element, it is extremely reactive, as it reacts with all other elements except for the light inert gases.

<span class="mw-page-title-main">Tin(IV) fluoride</span> Chemical compound

Tin(IV) fluoride is a chemical compound of tin and fluorine with the chemical formula SnF4 and is a white solid with a melting point above 700 °C.

<span class="mw-page-title-main">Palladium(II) fluoride</span> Chemical compound

Palladium(II) fluoride, also known as palladium difluoride, is the chemical compound of palladium and fluorine with the formula PdF2.

<span class="mw-page-title-main">Difluoride</span> Index of chemical compounds with the same name

Difluorides are chemical compounds with two fluorine atoms per molecule.

Fluorine forms a great variety of chemical compounds, within which it always adopts an oxidation state of −1. With other atoms, fluorine forms either polar covalent bonds or ionic bonds. Most frequently, covalent bonds involving fluorine atoms are single bonds, although at least two examples of a higher order bond exist. Fluoride may act as a bridging ligand between two metals in some complex molecules. Molecules containing fluorine may also exhibit hydrogen bonding. Fluorine's chemistry includes inorganic compounds formed with hydrogen, metals, nonmetals, and even noble gases; as well as a diverse set of organic compounds. For many elements the highest known oxidation state can be achieved in a fluoride. For some elements this is achieved exclusively in a fluoride, for others exclusively in an oxide; and for still others the highest oxidation states of oxides and fluorides are always equal.

<span class="mw-page-title-main">Chromium(IV) fluoride</span> Chemical compound

Chromium(IV) fluoride is an inorganic compound with the chemical formula CrF4. It has a dark greenish-black color when solid. It rapidly hydrolysizes in presence of moisture in air or directly in water.

<span class="mw-page-title-main">Iodosyl trifluoride</span> Chemical compound

Iodosyl trifluoride is an inorganic compound of iodine, fluorine, and oxygen with the chemical formula IOF3.

Bromosyl trifluoride is an inorganic compound of bromine, fluorine, and oxygen with the chemical formula BrOF3.

Iodosyl pentafluoride is an inorganic compound of iodine, fluorine, and oxygen with the chemical formula IOF5.

<span class="mw-page-title-main">Iodyl fluoride</span> Chemical compound

Iodyl fluoride is an inorganic compound of iodine, fluorine, and oxygen with the chemical formula IO2F. The compound was initially synthesized in 1951.

Iodine trifluoride dioxide is an inorganic compound of iodine, fluorine, and oxygen with the chemical formula IO2F3. The compound was first obtained by Engelbrecht and Petersy in 1969.

References

  1. Advances in Inorganic Chemistry and Radiochemistry. Academic Press. 1 January 1963. p. 84. ISBN   978-0-08-057854-5 . Retrieved 24 May 2023.
  2. So, S. P.; Chau, F. T. (June 1973). "Urey-Bradley Force Field of Perhalyl Fluorides". Zeitschrift für Physikalische Chemie . 85 (1–4): 69–75. doi:10.1524/zpch.1973.85.1-4.069. S2CID   101872763 . Retrieved 24 May 2023.
  3. Wiberg, Egon; Wiberg, Nils (2001). Inorganic Chemistry. Academic Press. p. 468. ISBN   978-0-12-352651-9 . Retrieved 24 May 2023.
  4. Haynes, William M. (4 June 2014). CRC Handbook of Chemistry and Physics. CRC Press. p. 4-67. ISBN   978-1-4822-0868-9 . Retrieved 24 May 2023.
  5. Simons, J. H. (2 December 2012). Fluorine Chemistry V5. Elsevier. p. 91. ISBN   978-0-323-14724-8 . Retrieved 24 May 2023.