Tellurite fluoride

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A tellurite fluoride is a mixed anion compound containing tellurite and fluoride ions. They have also been called oxyfluorotellurate(IV) where IV is the oxidation state of tellurium in tellurite.

Comparable compounds are sulfite fluorides or selenite fluorides.

List

nameformularatio

TeO3:F

 mw crystal
system		 space group unit cell Åvolumedensityopticalcommentreferences
Li7(TeO3)3FP63a =11.4178 c =4.8433band gap 4.75 eV
KTe3O6F3:1rhombohedralR3a=9.486, c=13.774, Z=6 [1]
ScTeO3F239.56orthorhombicPnmaa = 5.7740 b = 22.062 c = 5.500700.6colourless [2]
titanium(IV) tellurium(IV) trioxide difluorideTiTeO3F21:1361.50orthorhombicPnmaa = 7.392 b = 16.369 c=6.4886 Z=8785.1colourless [3]
divanadium(IV) ditellurium(IV) heptaoxide difluorideV2Te2O7F22:2507.38triclinicP1a = 4.882 b = 5.112 c = 7.243 α = 108.17° β = 91.64° γ = 92.63°171.4green-brown [3]
CrIIITeO3F1:1 [4]
FeTeO3F1:1250.45monoclinicP21/na = 5.0667 b = 5.0550 c = 12.397 β = 97.63° Z=4314.72green [4]
Co2TeO3F21:2331.46orthorhombicPnmaa=7.3810 b=10.1936 c=5.3013 Z=4398.865.520purple [5]
Co15F2(TeO3)1414:23380.35trigonalR3a =11.6649 c =27.317 Z=33219.15.231blue [6]
Cu7(TeO3)6F26:2triclinicP1a =4.9844 b =9.4724 c =9.958, α =82.318° β =76.275° γ =78.847° [7]
GaTeO3F1:1monoclinicP21/na = 5.0625 b = 4.9873 c = 12.166 β = 97.952 (13)° Z=4304.22colourless [4]
RbTe3O6F3:1
InTeO3F1:1309.42a = 7.939 b = 5.3867 c = 8.053 β = 91.06°344.35colourless [8] [2]
InTe2O5F2:1orthorhombicCmmma = 7.850, b = 27.637, c = 4.098, Z = 4889.1 [8]
In3TeO3F71:7orthorhombicCmmma  = 7.850(2) A, b  = 27.637(6) A, c  = 4.098 [8] [9]
In3(SO4)(TeO3)2F3(H2O)P212121a =8.3115 b =9.4341 c =14.807band gap 4.10 eV [10]
BaF2TeF2(OH)2Pmn21SHG ~3 × KDPfluorotellurite [11]
Ba2Ga3F3(Te6F2O16)a =8.8753 b =8.8753 c =11.655band gap 4.4 eV [12]
Ba(MoOF2)(TeO4)1:2478.87monoclinicP21/ca 5.4281 b 10.1306 c 12.3186 β 116.145° Z=4608.095.231colourless [13]
Ba(MoO2F)2(TeO3)22:2782.42orthorhombicAba2a=12.5605 b=11.0264 c=7.2858 Z=41009.15.150colourless [14]
Ba(WOF2)(TeO4)566.77monoclinicP21/ca 5.4483 b 10.0179 c 12.3134 β 115.422(6)° Z=4607.006.202green [13]
Pb2Al3F3(Te6F2O16)orthorhombicP4/mbma =8.7627 b =8.7627 c =11.235band gap 4.1 eV [12]
PbVTeO5F484.73orthorhombicPbcaa=9.8976 b=8.0685 c=13.0701043.86.169orange;

birefringence 0.142 at 590 nm

Pb2Ga3F3(Te6F2O16)orthorhombicP4/mbma =8.8439 b =8.8439 c =11.580band gap 4.2 eV [12]
Bi4TeO4F2(TeO3)2(SeO3)22:21670.64monoclinicP21/ca=7.0304 b=6.6782 c=17.355 β=106.155 Z=2782.667.089colourless [15]

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References

  1. ↑ Laval, J.P.; Guillet, L.; Frit, B. (April 2002). "KTe3O6F: a new layer TeO2 structure, stuffed with KF units". Solid State Sciences. 4 (4): 549–556. Bibcode:2002SSSci...4..549L. doi:10.1016/S1293-2558(02)01290-6.
  2. 1 2 Jennene Boukharrata, Nefla; Laval, Jean-Paul; Thomas, Philippe (2008-07-15). "Two new types of oxyfluorotellurates(IV): ScTeO 3 F and InTeO 3 F". Acta Crystallographica Section C Crystal Structure Communications. 64 (7): i57–i61. Bibcode:2008AcCrC..64I..57J. doi:10.1107/S0108270108017150. ISSN   0108-2701. PMID   18599966.
  3. 1 2 Laval, Jean Paul; Jennene Boukharrata, Nefla (2009-01-15). "New vanadium(IV) and titanium(IV) oxyfluorotellurates(IV): V 2 Te 2 O 7 F 2 and TiTeO 3 F 2". Acta Crystallographica Section C Crystal Structure Communications. 65 (1): i1–i6. Bibcode:2009AcCrC..65I...1L. doi:10.1107/S0108270108036755. ISSN   0108-2701. PMID   19129587.
  4. 1 2 3 Laval, Jean Paul; Jennene Boukharrata, Nefla; Thomas, Philippe (2008-02-15). "New oxyfluorotellurates(IV): M TeO 3 F ( M = Fe III , Ga III and Cr III )". Acta Crystallographica Section C Crystal Structure Communications. 64 (2): i12–i14. Bibcode:2008AcCrC..64I..12L. doi:10.1107/S0108270107062683. ISSN   0108-2701. PMID   18252985. S2CID   22908353.
  5. ↑ Hu, Shichao; Johnsson, Mats (2012). "Synthesis and crystal structure of two synthetic oxofluoride framework compounds – Co2TeO3F2 and Co2SeO3F2". Dalton Transactions. 41 (41): 12786–12789. doi:10.1039/c2dt31188g. ISSN   1477-9226. PMID   22968840.
  6. ↑ Lü, Minfeng; Jiang, Jianhua; Zhu, Bei; Zhao, Yuwei; Zhu, Tianyu; Yang, Haoming; Jin, Yong; Kabbour, Houria; Choi, Kwang-Yong; Harrison, William T. A. (2020). "Lone-pair self-containment in pyritohedron-shaped closed cavities: optimized hydrothermal synthesis, structure, magnetism and lattice thermal conductivity of Co 15 F 2 (TeO 3 ) 14". Dalton Transactions. 49 (7): 2234–2243. doi:10.1039/C9DT04176A. hdl: 2164/15901 . ISSN   1477-9226. PMID   32003383. S2CID   210983894.
  7. ↑ Hu, Shichao; Mace, Amber; Johnsson, Mats; Gnezdilov, Vladimir; Lemmens, Peter; Tapp, Joshua; Möller, Angela (2014-07-21). "Crystal Structure and Magnetic Properties of the S = 1 / 2 Quantum Spin System Cu 7 (TeO 3 ) 6 F 2 with Mixed Dimensionality". Inorganic Chemistry. 53 (14): 7661–7667. doi:10.1021/ic5009686. ISSN   0020-1669. PMID   24956023.
  8. 1 2 3 Jennene Boukharrata, N.; Laval, J.P. (February 2011). "Synthesis and structure determination of In3TeO3F7: An indium oxyfluorotellurate IV derived from W bronze structure with Te4+ in hexagonal tunnels". Journal of Alloys and Compounds. 509 (5): 1517–1522. doi:10.1016/j.jallcom.2010.10.139.
  9. ↑ Jennene Boukharrata, N.; Laval, J.P. (February 2011). "Synthesis and structure determination of In3TeO3F7: An indium oxyfluorotellurate IV derived from W bronze structure with Te4+ in hexagonal tunnels". Journal of Alloys and Compounds. 509 (5): 1517–1522. doi:10.1016/j.jallcom.2010.10.139.
  10. ↑ Gong, Ya-Ping; Ma, Yun-Xiang; Ying, Shao-Ming; Mao, Jiang-Gao; Kong, Fang (2019-08-19). "Two Indium Sulfate Tellurites: Centrosymmetric In 2 (SO 4 )(TeO 3 )(OH) 2 (H 2 O) and Non-centrosymmetric In 3 (SO 4 )(TeO 3 ) 2 F 3 (H 2 O)". Inorganic Chemistry. 58 (16): 11155–11163. doi:10.1021/acs.inorgchem.9b01730. ISSN   0020-1669. PMID   31365247. S2CID   199054944.
  11. ↑ Zhou, Jinjie; Wu, Hongping; Yu, Hongwei; Jiang, Shutong; Hu, Zhanggui; Wang, Jiyang; Wu, Yicheng; Halasyamani, P. Shiv (2020-03-11). "BaF 2 TeF 2 (OH) 2 : A UV Nonlinear Optical Fluorotellurite Material Designed by Band-Gap Engineering". Journal of the American Chemical Society. 142 (10): 4616–4620. doi:10.1021/jacs.0c00702. ISSN   0002-7863. PMID   32096982. S2CID   211525259.
  12. 1 2 3 Li, Peng-Fei; Kong, Fang; Mao, Jiang-Gao (June 2020). "MII2M3IIIF3(Te6F2O16) (MII = Pb, Ba; MIII = Al, Ga): New mixed anionic tellurites with isolated Te6 coplanar rings". Journal of Solid State Chemistry. 286: 121288. Bibcode:2020JSSCh.28621288L. doi:10.1016/j.jssc.2020.121288. S2CID   213626229.
  13. 1 2 Liang, Ming-Li; Ma, Yun-Xiang; Hu, Chun-Li; Kong, Fang; Mao, Jiang-Gao (2018). "A(VO 2 F)(SeO 3 ) (A = Sr, Ba) and Ba(MOF 2 )(TeO 4 ) (M = Mo, W): first examples of alkali-earth selenites/tellurites with a fluorinated d 0 -TM octahedron". Dalton Transactions. 47 (5): 1513–1519. doi:10.1039/C7DT04442A. ISSN   1477-9226. PMID   29313546.
  14. ↑ Liang, Ming-Li; Ma, Yun-Xiang; Hu, Chun-Li; Kong, Fang; Mao, Jiang-Gao (2020-11-24). "Ba(MoO 2 F) 2 (QO 3 ) 2 (Q = Se, Te): Partial Fluorination of MoO 6 Octahedra Enabling Two Polar Solids with Strong and Phase Matchable SHG Response". Chemistry of Materials. 32 (22): 9688–9695. doi:10.1021/acs.chemmater.0c03353. ISSN   0897-4756. S2CID   228831497.
  15. ↑ Gong, Ya-Ping; Hu, Chun-Li; Kong, Fang; Mao, Jiang-Gao (2019-03-07). "Exploration of New Birefringent Crystals in Bismuth d 0 Transition Metal Selenites". Chemistry – A European Journal. 25 (14): 3685–3694. doi:10.1002/chem.201806328. ISSN   0947-6539. PMID   30637825. S2CID   58575389.
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