Potassium hexafluoroantimonate

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Potassium hexafluoroantimonate
Kaliumhexafluoroantimonat.png
Names
IUPAC name
potassium;hexafluoroantimony(1-)
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.156.339 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 628-032-6
PubChem CID
  • InChI=1S/6FH.K.Sb/h6*1H;;/q;;;;;;+1;+5/p-6
    Key: LQKKGPUEJBHVHZ-UHFFFAOYSA-H
  • [K+].F[Sb-](F)(F)(F)(F)F
Properties
F6KSb
Molar mass 274.849 g·mol−1
Appearancepowder
Melting point 846
Boiling point 1505
Hazards
GHS labelling: [1]
GHS-pictogram-exclam.svg GHS-pictogram-pollu.svg
Warning
H302, H332, H411
P261, P264, P270, P271, P273, P301+P317, P304+P340, P317, P330, P391, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Potassium hexafluoroantimonate is an inorganic chemical compound with the chemical formula KSbF6. [2]

Contents

Synthesis

Potassium hexafluoroantimonate can be prepared by reacting potassium pyroantimonate K2H2Sb2O7 with hydrogen fluoride or by treating the product of the reaction of a mixture of solid antimony(III) oxide and potassium hydroxide with hydrogen peroxide solution (30%) with hydrochloric acid (48%). [3]

Also, the compound can be prepared by reacting antimony pentafluoride and potassium hexafluoromanganate. [4]

SbF5 + K2MnF6 → 4KSbF6 + 2MnF3 + F2

Uses

Potassium hexafluoroantimonate is used as a pharmaceutical intermediate. [5]

Chemical properties

Potassium hexafluoroaluminate can cause violent reactions with strong acids and oxidizing agents. [6]

Related Research Articles

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An inorganic nonaqueous solvent is a solvent other than water, that is not an organic compound. These solvents are used in chemical research and industry for reactions that cannot occur in aqueous solutions or require a special environment. Inorganic nonaqueous solvents can be classified into two groups, protic solvents and aprotic solvents. Early studies on inorganic nonaqueous solvents evaluated ammonia, hydrogen fluoride, sulfuric acid, as well as more specialized solvents, hydrazine, and selenium oxychloride.

Antimony pentafluoride is the inorganic compound with the formula SbF5. This colourless, viscous liquid is a strong Lewis acid and a component of the superacid fluoroantimonic acid, formed upon mixing liquid HF with liquid SbF5 in 1:1 ratio. It is notable for its strong Lewis acidity and the ability to react with almost all known compounds.

<span class="mw-page-title-main">Hydrogen fluoride</span> Chemical compound

Hydrogen fluoride (fluorane) is an inorganic compound with chemical formula HF. It is a very poisonous, colorless gas or liquid that dissolves in water to yield an aqueous solution termed hydrofluoric acid. It is the principal industrial source of fluorine, often in the form of hydrofluoric acid, and is an important feedstock in the preparation of many important compounds including pharmaceuticals and polymers, e.g. polytetrafluoroethylene (PTFE). HF is also widely used in the petrochemical industry as a component of superacids. Due to strong and extensive hydrogen bonding, it boils at near room temperature, much higher than other hydrogen halides.

<span class="mw-page-title-main">Arsenic pentoxide</span> Chemical compound

Arsenic pentoxide is the inorganic compound with the formula As2O5. This glassy, white, deliquescent solid is relatively unstable, consistent with the rarity of the As(V) oxidation state. More common, and far more important commercially, is arsenic(III) oxide (As2O3). All inorganic arsenic compounds are highly toxic and thus find only limited commercial applications.

<span class="mw-page-title-main">Hexafluorosilicic acid</span> Octahedric silicon compound

Hexafluorosilicic acid is an inorganic compound with the chemical formula H
2
SiF
6
. Aqueous solutions of hexafluorosilicic acid consist of salts of the cation and hexafluorosilicate anion. These salts and their aqueous solutions are colorless.

<span class="mw-page-title-main">Antimony pentoxide</span> Chemical compound

Antimony pentoxide (molecular formula: Sb2O5) is a chemical compound of antimony and oxygen. It contains antimony in the +5 oxidation state.

<span class="mw-page-title-main">Antimony trichloride</span> Chemical compound

Antimony trichloride is the chemical compound with the formula SbCl3. It is a soft colorless solid with a pungent odor and was known to alchemists as butter of antimony.

<span class="mw-page-title-main">Zirconium tetrafluoride</span> Chemical compound

Zirconium(IV) fluoride describes members of a family inorganic compounds with the formula (ZrF4(H2O)x. All are colorless, diamagnetic solids. Anhydrous Zirconium(IV) fluoride' is a component of ZBLAN fluoride glass.

Arsenic trifluoride is a chemical compound of arsenic and fluorine with the chemical formula AsF3. It is a colorless liquid which reacts readily with water.

<span class="mw-page-title-main">Bismuth(III) sulfide</span> Chemical compound

Bismuth(III) sulfide is a chemical compound of bismuth and sulfur. It occurs in nature as the mineral bismuthinite.

Dinitrogen difluoride is a chemical compound with the formula N2F2. It is a gas at room temperature, and was first identified in 1952 as the thermal decomposition product of the fluorine azide. It has the structure F−N=N−F and exists in both cis and trans isomers, as typical for diimides.

<span class="mw-page-title-main">Bismuth pentafluoride</span> Chemical compound

Bismuth pentafluoride is an inorganic compound with the formula BiF5. It is a white solid that is highly reactive. The compound is of interest to researchers but not of particular value.

<span class="mw-page-title-main">Hexafluoroarsenate</span> Chemical compound

The hexafluoroarsenate anion is a chemical species with formula AsF−6. Hexafluoroarsenate is relatively inert, being the conjugate base of the notional superacid hexafluoroarsenic acid.

Potassium hexafluorotitanate is an inorganic compound of potassium, fluorine, and titanium with the chemical formula K2TiF6.

The fluoroantimonates are a family of polyatomic weakly coordinating anions composed of antimony and fluorine, consisting of the fluorine adducts of antimony pentafluoride, [(SbF5)nF]. They occur in the internal chemistry of fluoroantimonic acid.

Sodium hexafluoroantimonate is an inorganic chemical compound with the chemical formula NaSbF6.

<span class="mw-page-title-main">Potassium hexafluoroarsenate</span> Chemical compound

Potassium hexafluoroarsenate is an inorganic chemical compound with the chemical formula KAsF6.

<span class="mw-page-title-main">Potassium hexafluoroaluminate</span> Chemical compound

Potassium hexafluoroaluminate is an inorganic chemical compound with the chemical formula K3AlF6. It naturally occures as the mineral cryolite.

References

  1. "Potassium hexafluoroantimonate". pubchem.ncbi.nlm.nih.gov.
  2. McCarthy, J. (6 December 2012). The Rare Earths in Modern Science and Technology: Volume 3. Springer Science & Business Media. p. 105. ISBN   978-1-4613-3406-4.
  3. Macintyre, Jane E. (23 July 1992). Dictionary of Inorganic Compounds. CRC Press. p. 3217. ISBN   978-0-412-30120-9 . Retrieved 15 June 2024.
  4. Ebnesajjad, Sina (11 May 2013). Introduction to Fluoropolymers: Materials, Technology and Applications. William Andrew. p. 10. ISBN   978-1-4557-7551-4 . Retrieved 15 June 2024.
  5. "Potassium hexafluoroantimonate(V) | CAS 16893-92-8 | SCBT - Santa Cruz Biotechnology". Santa Cruz Biotechnology . Retrieved 15 June 2024.
  6. "Potassium hexafluoroantimonate(V)". Sigma Aldrich . Retrieved 15 June 2024.